A coated article is provided with at least one infrared (IR) reflecting layer. The IR reflecting layer may be of silver or the like. In certain example embodiments, a titanium oxide layer is provided over the IR reflecting layer, and it has been found that this surprisingly results in an IR reflecting layer with a lower specific resistivity (SR) thereby permitting thermal properties of the coated article to be improved.

A substrate is coated on one face with a thin-films stack having reflection properties in the infrared and/or in solar radiation including at least one metallic functional layer, based on silver or on a metal alloy containing silver, and at least two antireflection coatings. The coatings each include at least one dielectric layer. The functional layer is positioned between the two antireflection coatings. The stack also includes a terminal layer which is the layer of the stack which is furthest from the face. The terminal layer is a metallic layer consisting of zinc and tin, made of Sn.sub.xZn.sub.y with a ratio of 0.1≦x/y≦2.4 and having a physical thickness of between 0.5 nm and 5.0 nm excluding these values, or even between 0.6 nm and 2.7 nm excluding these values.

A material includes a glass sheet coated on at least part of one of its faces with a stack of thin layers, the stack being coated on at least part of its surface with an enamel layer including zinc and less than 5% by weight of bismuth oxide, the stack further including, in contact with the enamel layer, a layer, called contact layer, which is based on an oxide, the physical thickness of the contact layer being at least 5 nm.

The present invention relates to a transparent substrate comprising a multiple layer coating stack and the use of same in the manufacture of a double glazing unit, wherein the multiple layer coating stack comprises, n functional metal layer, m; and n plus 1 (n+1) dielectric layer, d, wherein the dielectric layers are positioned before and after each functional metal layer, and wherein n is the total number of functional metal layer in the stack counted from the substrate and is greater than or equal to 3; and wherein each dielectric layer comprises one or more layers, characterized in that the geometrical layer thickness of each functional metal layer in the coating stack Gm, is greater than the geometrical layer thickness of each functional metal layer appearing before it in the multiple layer coating stack, that is, Gmi+1>Gm.sub.i wherein i is the position of the functional metal layer in the coating stack counted from the substrate, and wherein for each dielectric layer d located before and after each functional metal layer m, the optical layer thickness of each dielectric layer (opln) is greater than or equal to the optical layer thickness of the dielectric layer (opln−1) positioned before it in the coating stack with the proviso that: twice the optical layer thickness of the first dielectric layer (opl.sub.1) in the coating stack, is less than the optical layer thickness of the second dielectric layer (opl.sub.2) in the coating stack, that is, (2×opl.sub.1)<opl.sub.2; and twice the optical layer thickness of the last dielectric layer (opl.sub.n+1) in the coating stack, is greater than the thickness of the optical layer thickness of the penultimate dielectric layer (opl.sub.n), that is, (opl.sub.n)<(opl.sub.n+1)×2.

Provided is a radiative cooling device that provides coloration of the radiative surface while maximally avoiding reduction in its radiative cooling performance due to absorption of solar light. An infrared radiative layer for radiating infrared light from a radiative surface and a light reflective layer disposed on the side opposite to the presence side of the radiative surface of the infrared radiative layer are provided in a mutually stacked state. The light reflective layer is arranged such that a first metal layer made of silver or silver alloy and having a thickness equal to or greater than 10 nm and equal to or less than 100 nm, a transparent dielectric layer and a second metal layer reflecting light transmitted through the first metal layer and the transparent dielectric layer are stacked in this order on the side closer to the infrared radiative layer. The transparent dielectric layer has a thickness that causes a resonance wavelength of the light reflective layer to be a wavelength included in wavelengths equal to or greater than 400 nm and equal to or less than 800 nm.

Absorbing layers of a low-emissivity (low-E) coating are designed to cause the coating to have a reduced film side reflectance which is advantageous for aesthetic purposes. In certain embodiments, the absorbing layers are metallic or substantially metallic (e.g., NiCr or NiCrN.sub.x) and are positioned in order to reduce or prevent oxidation of the absorbing layers during optional heat treatment (e.g., thermal tempering, heat bending, and/or heat strengthening). Coated articles according to certain example embodiments of this invention may be used in the context of insulating glass (IG) window units, other types of windows, etc.

There is provided a multilayer coating comprising a plurality of layers comprising a) one or more layers of an elemental transition metal; b) one or more layers of an elemental metalloid; and c) two or more layers of an oxide; characterized in that the transition metal and metalloid layers are between the oxide layers and the plurality of layers does not need to contain an additional transparent conductive film (TCF). The multilayer coatings show high transparency in the visible light range combined with heat shielding without the need of transparent conductive oxide which have been previously used to achieve these properties. The multilayers can be produced with conventional physical vapor deposition methods on glass and polymer substrates. The coatings may therefore be used for applications on windows, plastic sheets and window shields. The invention relates also to the process for making the multilayer coatings, articles comprising them and their use in building and other applications.

The invention relates to a technique of manufacturing a coated substrate (102) such as glass (104) carrying a conductive layer (112) such as a metal layer to be tempered after deposition. A system (100) for manufacturing the coated substrate (102) may comprise a sputtering configuration (120) adapted for depositing the conductive layer (112) on the substrate (104). A pulse laser (132) is adapted for irradiating the conductive layer (112) with laser pulses (136). The pulse laser (132) is adapted for laser pulses (136) with a pulse duration below one microsecond.

Infrared reflecting substrate includes, on a transparent film base, an infrared reflecting layer mainly made of silver and a light absorptive metal layer in this order. The light absorptive metal layer has a thickness of 15 nm or less, and a transparent protective layer has a thickness of 10 nm to 120 nm. The distance between the light absorptive metal layer and the transparent protective layer is 25 nm or less.

A substrate is coated on one face with a thin-films stack having reflection properties in the infrared and/or in solar radiation including a single metallic functional layer, based on silver or on a metal alloy containing silver, and two antireflection coatings. The coatings each include at least one dielectric layer. The functional layer is positioned between the two antireflection coatings. At least one of the antireflection coatings includes an intermediate layer including zinc oxide Zn.sub.1O.sub.1+x with 0.05<x<0.3 and having a physical thickness of between 0.5 nm and 20 nm, or between 2.5 nm and 10 nm.