Methods, processes, systems, devices and apparatus are provided for additive manufacture resulting in the 3D printing of ceramic materials and components with a thickness greater than three millimeters (3 mm). A sulfur-free 3D printable formulation comprises a liquid inorganic polymer resin using Stereolithograpy (SLA) printers and Digital Light Processing (DLP) curing of the polymer resin via the chemical bonding of the materials rather than sintering. Thus, the process has shorter manufacturing intervals, significantly lower energy use and produces larger scale ceramic components having less linear shrinkage, less mass loss and high ceramic yield with no corrosive sulfur compounds present in the ceramic component.

The present invention relates to an alpha alumina having a high purity, a high density and a low surface area and particularly, to a method to produce such an alpha alumina as well as to the use of the alpha alumina in sapphire production or the production of composite and ceramic bodies.

Methods of forming composite materials, composite materials, and articles. The composite materials may include electromagnetic shielding materials. The methods may include providing a mixture of ultra-high temperature ceramic particles and a liquid preceramic precursor, curing the mixture to form a solid mixture, forming particles of the solid mixture, and pressing the particles into a mold.

A method of making an electrical structure having a foam housing is set forth. The foam housing includes an interior surface forming a conductive cavity adapted to carry energized waveforms therethrough. An electrical component of the electrical structure is integrally formed with the interior surface as the foam housing of the structure is assembled. The method includes the steps of depositing a plating material into a mold, pouring a foam polymer into the mold and removing the plated foam structure from the mold without etching the section from the mold. The method further includes steps of forming a metallic form into a planar structure, filling the open pores of the foam with a material such as photo-resist, machining a cavity from the foam, electroplating the cavity in the foam then removing the photo-resist material.

Systems, methods, components, and materials are disclosed for stereolithographic fabrication of three-dimensional, dense objects. A resin including at least one component of a binder system and dispersed particles can be exposed to an activation light source. The activation light source can cure the at least one component of the binder system to form a green object, which can include the at least one component of the binder system and the particles. A dense object can be formed from the green object by removing the at least one component of the binder system in an extraction process and thermally processing particles to coalesce into the dense object.

The disclosed method includes selecting a suspension ceramic or metal photocurable composition (CPC or MPC); preparing a sacrificial organic material (SOM) forming a photocurable layer destroyed by heating; for manufacturing pieces, on the working tray, forming successive layers of SOM cured by irradiation, the one or more CPC or MPC-based pieces being manufactured by machining a recess in a layer of cured SOM; depositing the CPC or MPC within the recesses; curing the CPC or MPC to obtain a hard horizontal surface level with the adjacent layer of cured SOM, when forming each recess, it is delimited by previously defined patterns, the depth(s) selected in order to ensure the continuity of the one or more pieces to be manufactured; and obtaining one or more green pieces inserted in the SOM, which are subjected to debinding by heating in order to destroy the SOM in which they are trapped.

An additive manufacturing apparatus has a platform, one or more supports positioned above the platform, an actuator coupled to at least one of the platform and the one or more supports and configured to create relative motion therebetween such that the one or more supports scan across the platform, a first dispenser system configured dispense a plurality of successive layers of powder onto a build area supported by the platform, a second dispenser system configured to dispense a binder material onto the build area, and an energy source configured to emit radiation toward the platform so as to solidify the binder material. The first dispenser system includes a first powder dispenser that is attached to and moves with a first support from the one or more supports and is configured to selectively dispense a first powder onto the build area.

The present invention relates to preceramic polymer grafted nanoparticles and as well as methods of making and using same. Advantages of such preceramic polymer grafted nanoparticles include, reduced out gassing, desired morphology control and desirable, distinct rheological properties that are not found in simple mixtures. As a result, Applicants' preceramic polymer grafted nanoparticles can be used to provide significantly improved, items including but not limited to hypersonic vehicles, jets, rockets, mirrors, signal apertures, furnaces, glow plugs, brakes, and armor.

A cellular material includes a continuous solid phase including an ordered ceramic material, the solid phase having a solid core including the ordered ceramic material. A composition for forming a cellular material includes: a first UV curable pre-ceramic monomer; a second UV curable pre-ceramic monomer; and a photoinitiator. A method of forming at least one ceramic waveguide includes: securing a volume of a composition including a UV curable pre-ceramic monomer; exposing the composition to a light source to form at least one polymer waveguide including a pre-ceramic material; and converting the pre-ceramic material of the polymer waveguide to a ceramic material to form a ceramic waveguide.

A method for producing a solid composition according to the present disclosure is a method for producing a solid composition that is used for forming a functional ceramic having a first crystal phase. The method for producing a solid composition includes: producing an oxide composed of a second crystal phase different from the first crystal phase; and mixing the oxide and an oxo acid compound.