An article includes a ceramic-based substrate and a barrier layer on the ceramic-based substrate. The barrier layer includes a matrix, diffusive particles, and gettering particles. The gettering particles include at least one of non-gas-evolving particles and porous particles. An article and a method are also disclosed.

A method of providing a self-healing coating includes providing substrate, applying a layer of an aluminum-containing MAX phase material and another material to the substrate. The method includes exposing the layer to a temperature greater than 2000° F. to form alpha aluminum.

A method of providing a self-healing coating includes providing substrate, applying a layer of an aluminum-containing MAX phase material and another material to the substrate. The method includes exposing the layer to a temperature greater than 2000° F. to form alpha aluminum.

The present invention concerns a method for obtaining a finished or semi-finished zirconia-based article (1), the article having a metallic external appearance and non-zero surface electrical conductivity, characterized in that the method includes the steps consisting in: taking at least one zirconia article, pre-shaped in its finished or semi-finished form; placing said article inside a chamber (10) in which a gaseous mixture is arranged, this gaseous mixture including at least a first hydrogen and carbon based gas compound in a first concentration (C1) and a second hydrogen and nitrogen based gas compound in a second concentration (C2); heating the gaseous mixture until the molecules of the first and second compounds dissociate and keeping said article in the reactive atmosphere thereby created to obtain diffusion of the carbon and nitrogen atoms in the external surface (2) of said article and to form stoichiometric carbonitride (ZrC.sub.x—N.sub.y) at the surface, and prior to the step of heating the process gases contained in the chamber, a reduction step consisting in placing said article inside a chamber into which dihydrogen is injected and in heating the dihydrogen allowing diffusion towards the surface and release of the oxygen contained in said zirconia article.

The present invention concerns a method for obtaining a finished or semi-finished zirconia-based article (1), the article having a metallic external appearance and non-zero surface electrical conductivity, characterized in that the method includes the steps consisting in: taking at least one zirconia article, pre-shaped in its finished or semi-finished form; placing said article inside a chamber (10) in which a gaseous mixture is arranged, this gaseous mixture including at least a first hydrogen and carbon based gas compound in a first concentration (C1) and a second hydrogen and nitrogen based gas compound in a second concentration (C2); heating the gaseous mixture until the molecules of the first and second compounds dissociate and keeping said article in the reactive atmosphere thereby created to obtain diffusion of the carbon and nitrogen atoms in the external surface (2) of said article and to form stoichiometric carbonitride (ZrC.sub.x—N.sub.y) at the surface, and prior to the step of heating the process gases contained in the chamber, a reduction step consisting in placing said article inside a chamber into which dihydrogen is injected and in heating the dihydrogen allowing diffusion towards the surface and release of the oxygen contained in said zirconia article.

The present invention relates to carbon material having, on the base material, a coating layer that includes TaC, and a method for producing the carbon material. For example, the carbon material may include a base material and a coating layer on the surface of the base material. The coating layer may include TaC, which may have a maximum diffraction peak value on the (111) surface, where diffraction peak values may be generated by diffractions of X-rays in XRD analysis.

The present invention relates to carbon material having, on the base material, a coating layer that includes TaC, and a method for producing the carbon material. For example, the carbon material may include a base material and a coating layer on the surface of the base material. The coating layer may include TaC, which may have a maximum diffraction peak value on the (111) surface, where diffraction peak values may be generated by diffractions of X-rays in XRD analysis.

Cutting elements include a carbonate diamond-bonded body that is sintered under HPHT conditions in the presence of a carbonate material, where the body includes a matrix phase of intercrystalline bonded diamond with interstitial regions including the carbonate material, where the diamond-bonded body is sintered without a substrate. A matrix casting is formed and mechanically coupled to the body after the body is sintered, and a portion of the body surface is exposed along a surface of the matrix casting. The exposed body surface is thereafter intentionally treated to induce a compressive residual surface stress that is greater than a remaining portion of the body. The compressive residual surface stress is less than about 500 MPa, and from about 100 to 500 MPa, and a remaining region the body may have a residual stress of less than about 300 MPa, and less than about 100 MPa.

A part made from a composite material having a ceramic matrix and including a protection device, the protection including a coating layer having a gradual composition. The gradual-composition coating layer includes at least one silicon phase and one aluminium phase, the proportions of which change according to the height in the layer, with a first height in the gradual-composition coating layer corresponding to a silicon-free composition, and a second height corresponding to an aluminium-free composition. A method for producing such a protection, and to a device for carrying out the method, are disclosed.

A part made from a composite material having a ceramic matrix and including a protection device, the protection including a coating layer having a gradual composition. The gradual-composition coating layer includes at least one silicon phase and one aluminium phase, the proportions of which change according to the height in the layer, with a first height in the gradual-composition coating layer corresponding to a silicon-free composition, and a second height corresponding to an aluminium-free composition. A method for producing such a protection, and to a device for carrying out the method, are disclosed.