C07C1/0445

Process to convert synthesis gas to olefins using a bifunctional chromium/zinc oxide-SAPO-34 catalyst

A process for preparing C.sub.2 to C.sub.3 olefins includes introducing a feed stream having a volumetric ratio of hydrogen to carbon monoxide from greater than 0.5:1 to less than 5:1 into a reactor, and contacting the feed stream with a bifunctional catalyst. The bifunctional catalyst includes a Cr/Zn oxide methanol synthesis component having a Cr to Zn molar ratio from greater than 1.0:1 to less than 2.15:1, and a SAPO-34 silicoaluminophosphate microporous crystalline material. The reactor operates at a temperature ranging from 350 C. to 450 C., and a pressure ranging from 10 bar (1.0 MPa) to 60 bar (6.0 MPa). The process has a cumulative productivity of C.sub.2 to C.sub.3 olefins greater than 15 kg C.sub.2 to C.sub.3 olefins/kg catalyst.

Process to convert synthesis gas to olefins using a bifunctional chromium/zinc oxide-SAPO-34 catalyst

A process for preparing C.sub.2 to C.sub.3 olefins includes introducing a feed stream having a volumetric ratio of hydrogen to carbon monoxide from greater than 0.5:1 to less than 5:1 into a reactor, and contacting the feed stream with a bifunctional catalyst. The bifunctional catalyst includes a Cr/Zn oxide methanol synthesis component having a Cr to Zn molar ratio from greater than 1.0:1 to less than 2.15:1, and a SAPO-34 silicoaluminophosphate microporous crystalline material. The reactor operates at a temperature ranging from 350 C. to 450 C., and a pressure ranging from 10 bar (1.0 MPa) to 60 bar (6.0 MPa). The process has a cumulative productivity of C.sub.2 to C.sub.3 olefins greater than 15 kg C.sub.2 to C.sub.3 olefins/kg catalyst.

COMPOSITE CATALYST AND PREPARATION METHOD THEREFOR

Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.

COMPOSITE CATALYST AND PREPARATION METHOD THEREFOR

Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.

Composite catalyst and preparation method therefor

Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.

Composite catalyst and preparation method therefor

Disclosed is a composite catalyst, comprising carbon in a continuous phase and Raney alloy particles in a dispersed phase. The Raney alloy particles are dispersed evenly or unevenly in the carbon in a continuous phase, and the carbon in a continuous phase is obtained by carbonizing at least one carbonizable organic substance. The catalyst has good particle strength, high catalytic activity, and good selectivity.

COBALT CATALYST COMPRISING A SUPPORT CONTAINING A MIXED OXIDE PHASE INCLUDING COBALT AND/OR NICKEL PRODUCED USING A HYDROCARBON COMPOUND

The invention relates to a catalyst containing an active cobalt phase, deposited on a support comprising alumina, silica or silica-alumina, said support also containing a mixed oxide phase containing cobalt and/or nickel, said catalyst having been prepared by introducing at least one hydrocarbon organic compound of formula C.sub.xH.sub.y. The invention also relates to the use thereof in the field of Fischer-Tropsch synthesis processes.

METHODS FOR PREPARATION AND USE OF LIQUID SYNTHESIS CATALYSTS
20200038846 · 2020-02-06 ·

Described herein are catalysts relating to liquid synthesis, methods of their preparation, and methods of their use. In an embodiment according to the present disclosure, a method of producing a catalyst for liquid synthesis comprises: providing a silica oxide support; pretreating the silica oxide support to remove air and moisture; impregnating the pretreated silica oxide support with cobalt from a cobalt source using a cobalt impregnation method; and calcinating the impregnated silica oxide support in an oven with a temperature ramping profile, wherein the calcinating comprises feeding air into the oven.

METHODS FOR PREPARATION AND USE OF LIQUID SYNTHESIS CATALYSTS
20200038846 · 2020-02-06 ·

Described herein are catalysts relating to liquid synthesis, methods of their preparation, and methods of their use. In an embodiment according to the present disclosure, a method of producing a catalyst for liquid synthesis comprises: providing a silica oxide support; pretreating the silica oxide support to remove air and moisture; impregnating the pretreated silica oxide support with cobalt from a cobalt source using a cobalt impregnation method; and calcinating the impregnated silica oxide support in an oven with a temperature ramping profile, wherein the calcinating comprises feeding air into the oven.

PROCESS TO CONVERT SYNTHESIS GAS TO OLEFINS USING A BIFUNCTIONAL CHROMIUM/ZINC OXIDE-SAPO-34 CATALYST

A process for preparing C.sub.2 to C.sub.3 olefins includes introducing a feed stream having a volumetric ratio of hydrogen to carbon monoxide from greater than 0.5:1 to less than 5:1 into a reactor, and contacting the feed stream with a bifunctional catalyst. The bifunctional catalyst includes a Cr/Zn oxide methanol synthesis component having a Cr to Zn molar ratio from greater than 1.0:1 to less than 2.15:1, and a SAPO-34 silicoaluminophosphate microporous crystalline material. The reactor operates at a temperature ranging from 350 C. to 450 C., and a pressure ranging from 10 bar (1.0 MPa) to 60 bar (6.0 MPa). The process has a cumulative productivity of C.sub.2 to C.sub.3 olefins greater than 15 kg C.sub.2 to C.sub.3 olefins/kg catalyst.