Patent classifications
C07C29/154
METHODS OF PRODUCING A SYNGAS COMPOSITION
A method of producing a syngas composition includes hydrolyzing a metal halide salt to form a hydrohalic acid and a hydroxide salt of the metal in the metal halide salt. The metal includes an alkaline earth metal or an alkali metal. The method includes reacting the hydrohalic acid with a metal carbonate salt, wherein the metal carbonate salt is a carbonate salt of the alkaline earth metal or alkali metal, to form CO.sub.2 and the metal halide salt. At least some of the metal halide salt formed from the reacting of the hydrohalic acid with the metal carbonate salt is recycled as at least some of the metal halide salt in the hydrolyzing of the metal halide salt to form the hydrohalic acid and the hydroxide salt. The method also includes electrolytically converting the CO.sub.2 and the water into the syngas composition including carbon monoxide and hydrogen.
CARBON DIOXIDE REDUCTION CATALYST AND CARBON DIOXIDE REDUCTION METHOD
The present invention provides a carbon dioxide reduction catalyst that is used in reduction reactions of carbon dioxide and that has high methanol selectivity. A carbon dioxide reduction catalyst according to the present invention is used in producing methanol by reduction reactions of carbon dioxide, and contains Au and Cu as catalyst components and ZnO as a carrier. It is preferable that the catalyst components contain 7-25 mol % of Au as a catalyst component. This makes it possible to obtain high methanol selectivity—for example, selectivity of not less than 80%. The carbon dioxide reduction catalyst makes it possible to obtain high methanol selectivity even under the conditions of not more than 240° C. and not more than 50 bar.
CARBON DIOXIDE REDUCTION CATALYST AND CARBON DIOXIDE REDUCTION METHOD
The present invention provides a carbon dioxide reduction catalyst that is used in reduction reactions of carbon dioxide and that has high methanol selectivity. A carbon dioxide reduction catalyst according to the present invention is used in producing methanol by reduction reactions of carbon dioxide, and contains Au and Cu as catalyst components and ZnO as a carrier. It is preferable that the catalyst components contain 7-25 mol % of Au as a catalyst component. This makes it possible to obtain high methanol selectivity—for example, selectivity of not less than 80%. The carbon dioxide reduction catalyst makes it possible to obtain high methanol selectivity even under the conditions of not more than 240° C. and not more than 50 bar.
CARBON DIOXIDE REDUCTION CATALYST AND CARBON DIOXIDE REDUCTION METHOD
The present invention provides a carbon dioxide reduction catalyst that is used in reduction reactions of carbon dioxide and that has high methanol selectivity. A carbon dioxide reduction catalyst according to the present invention is used in producing methanol by reduction reactions of carbon dioxide, and contains Au and Cu as catalyst components and ZnO as a carrier. It is preferable that the catalyst components contain 7-25 mol % of Au as a catalyst component. This makes it possible to obtain high methanol selectivity—for example, selectivity of not less than 80%. The carbon dioxide reduction catalyst makes it possible to obtain high methanol selectivity even under the conditions of not more than 240° C. and not more than 50 bar.
Continuous Capture of Carbon Dioxide From Exhaust Gas and Conversion Thereof to Useful Chemistries
A method including collecting exhaust gas comprising carbon dioxide (CO.sub.2) at a wellsite to provide a collected exhaust gas, separating CO.sub.2 from the collected exhaust gas to provide a separated CO.sub.2, and forming an alcohol product utilizing at least a portion of the separated CO.sub.2. The alcohol product can include methanol, ethanol, a precursor thereof, or a combination thereof.
Continuous Capture of Carbon Dioxide From Exhaust Gas and Conversion Thereof to Useful Chemistries
A method including collecting exhaust gas comprising carbon dioxide (CO.sub.2) at a wellsite to provide a collected exhaust gas, separating CO.sub.2 from the collected exhaust gas to provide a separated CO.sub.2, and forming an alcohol product utilizing at least a portion of the separated CO.sub.2. The alcohol product can include methanol, ethanol, a precursor thereof, or a combination thereof.
PROCESS FOR PRODUCING A MULTIFUNCTIONAL PRODUCT AND THE DEVICE FOR APPLYING SAID PROCESS
A process by which the raw material, a gas comprising mainly hydrogen, carbon monoxide and carbon dioxide, is introduced into a first reactor together with a catalyst, in which one or more reactions take place that produce methanol or dimethyl ether or both, which are then introduced into a second reactor adding oxygen and a catalyst and producing formaldehyde and a minority of dimethyl ether, and where there may be an excess of water, such water being extracted from the process and the remaining products being introduced into the third reactor with, optionally, an additive, and such raw material is exposed to catalysts and under an atmosphere at medium temperature and pressure, in order to produce three or four groups of chemical reactions that, after extracting most of the water that is generated as a residue during the process, produces as a result a liquid multifunctional product that can be used as a solvent, a foaming agent or an oxygenated fuel; said product, normally a fluid, comprises polyoxymethylene dimethyl ethers with molecular formula CH3O(CH2O)nCH3 wherein n has a value between 1 and 7.
PROCESS FOR PRODUCING A MULTIFUNCTIONAL PRODUCT AND THE DEVICE FOR APPLYING SAID PROCESS
A process by which the raw material, a gas comprising mainly hydrogen, carbon monoxide and carbon dioxide, is introduced into a first reactor together with a catalyst, in which one or more reactions take place that produce methanol or dimethyl ether or both, which are then introduced into a second reactor adding oxygen and a catalyst and producing formaldehyde and a minority of dimethyl ether, and where there may be an excess of water, such water being extracted from the process and the remaining products being introduced into the third reactor with, optionally, an additive, and such raw material is exposed to catalysts and under an atmosphere at medium temperature and pressure, in order to produce three or four groups of chemical reactions that, after extracting most of the water that is generated as a residue during the process, produces as a result a liquid multifunctional product that can be used as a solvent, a foaming agent or an oxygenated fuel; said product, normally a fluid, comprises polyoxymethylene dimethyl ethers with molecular formula CH3O(CH2O)nCH3 wherein n has a value between 1 and 7.
PROCESS FOR PRODUCING A MULTIFUNCTIONAL PRODUCT AND THE DEVICE FOR APPLYING SAID PROCESS
A process by which the raw material, a gas comprising mainly hydrogen, carbon monoxide and carbon dioxide, is introduced into a first reactor together with a catalyst, in which one or more reactions take place that produce methanol or dimethyl ether or both, which are then introduced into a second reactor adding oxygen and a catalyst and producing formaldehyde and a minority of dimethyl ether, and where there may be an excess of water, such water being extracted from the process and the remaining products being introduced into the third reactor with, optionally, an additive, and such raw material is exposed to catalysts and under an atmosphere at medium temperature and pressure, in order to produce three or four groups of chemical reactions that, after extracting most of the water that is generated as a residue during the process, produces as a result a liquid multifunctional product that can be used as a solvent, a foaming agent or an oxygenated fuel; said product, normally a fluid, comprises polyoxymethylene dimethyl ethers with molecular formula CH3O(CH2O)nCH3 wherein n has a value between 1 and 7.
METHODS, SYSTEMS, AND CATALYSTS FOR THE DIRECT CONVERSION OF SYNGAS TO HIGH-OCTANE HYDROCARBONS
The present disclosure relates to a method that includes converting a gas stream that contains hydrogen (H.sub.2) and carbon monoxide (CO) to a second mixture that contains a hydrocarbon, for example, a hydrocarbon having between 3 and 15 carbon atoms, where the converting is performed using a first catalyst configured to convert H.sub.2 and CO to methanol, a second catalyst configured to convert methanol to dimethyl ether (DME), and a third catalyst configured to convert DME to the hydrocarbon.