Embodiments described herein provide a compound that may be used in a variety of applications such as corrosion inhibition, additives for metalworking, mining reagents, epoxy curatives, emulsifiers, fuel or lubricant additives, surfactant manufacture, acid scavengers and asphalt additives. The compound has the following structure:

##STR00001## where R.sub.1 is a methoxy group, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are independently a hydrogen atom or an alkyl group, and R.sub.6 is an aminomethyl group.

Embodiments described herein provide a compound that may be used in a variety of applications such as corrosion inhibition, additives for metalworking, mining reagents, epoxy curatives, emulsifiers, fuel or lubricant additives, surfactant manufacture, acid scavengers and asphalt additives. The compound has the following structure:

##STR00001## where R.sub.1 is a methoxy group, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are independently a hydrogen atom or an alkyl group, and R.sub.6 is an aminomethyl group.

Amines and amine derivatives that improve the buffering range, and/or reduce the chelation and other negative interactions of the buffer and the system to be buffered. The reaction of amines or polyamines with various molecules to form polyamines with differing pKa's will extend the buffering range, derivatives that result in polyamines that have the same pKa yields a greater buffering capacity. Derivatives that result in zwitterionic buffers improve yield by allowing a greater range of stability.

Amines and amine derivatives that improve the buffering range, and/or reduce the chelation and other negative interactions of the buffer and the system to be buffered. The reaction of amines or polyamines with various molecules to form polyamines with differing pKa's will extend the buffering range, derivatives that result in polyamines that have the same pKa yields a greater buffering capacity. Derivatives that result in zwitterionic buffers improve yield by allowing a greater range of stability.

This invention relates to polyetheramines based on 1,3-dialcohols, in particular to an etheramine mixture comprising at least 90% by weight, based on the total weight of the etheramine mixture, of an amine of Formula (I) and/or (II),

##STR00001##

wherein R.sub.1-R.sub.12 are independently selected from H, alkyl, cycloalkyl, aryl, alkylaryl, or arylalkyl, wherein at least one of R.sub.1-R.sub.6 and at least one of R.sub.7-R.sub.12 is different from H, wherein A.sub.1-A.sub.9 are independently selected from linear or branched alkylenes having 2 to 18 carbon atoms, wherein Z.sub.1-Z.sub.4 are independently selected OH, CH.sub.2CH.sub.2CH.sub.2NH.sub.2, NH.sub.2, NHR′ or NR′R″, wherein the degree of amination is <50%, wherein R′ and R″ are independently selected from alkylenes having 2-6 carbon atoms, and wherein the sum of x+y is in the range of from 2 to 200, wherein x≧1 and y≧1; and x.sub.1+y.sub.1 is in the range of from 2 to 200.

This invention relates to polyetheramines based on 1,3-dialcohols, in particular to an etheramine mixture comprising at least 90% by weight, based on the total weight of the etheramine mixture, of an amine of Formula (I) and/or (II),

##STR00001##

wherein R.sub.1-R.sub.12 are independently selected from H, alkyl, cycloalkyl, aryl, alkylaryl, or arylalkyl, wherein at least one of R.sub.1-R.sub.6 and at least one of R.sub.7-R.sub.12 is different from H, wherein A.sub.1-A.sub.9 are independently selected from linear or branched alkylenes having 2 to 18 carbon atoms, wherein Z.sub.1-Z.sub.4 are independently selected OH, CH.sub.2CH.sub.2CH.sub.2NH.sub.2, NH.sub.2, NHR′ or NR′R″, wherein the degree of amination is <50%, wherein R′ and R″ are independently selected from alkylenes having 2-6 carbon atoms, and wherein the sum of x+y is in the range of from 2 to 200, wherein x≧1 and y≧1; and x.sub.1+y.sub.1 is in the range of from 2 to 200.

A process for removing hydrogen sulfide and carbon dioxide from a fluid stream comprises a) an absorption step in which the fluid stream is contacted with an absorbent comprising an aqueous solution (i) of an amine of the general formula (I)

##STR00001##

in which R.sub.1, R.sub.2 and R.sub.3 are each independently selected from C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.4 is independently selected from hydrogen, C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.5 is independently selected from hydrogen, C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; X is OH or NH(CR.sub.1R.sub.2R.sub.3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and optionally (ii) at least one tertiary amine, where the molar ratio of (i) to (ii) is greater than 0.05; wherein at least 90% of the hydrogen sulfide is removed from the fluid stream and selectivity for hydrogen sulfide over carbon dioxide is not greater than 8, wherein a CO.sub.2- and H.sub.2S-laden absorbent is obtained; b) a regeneration step in which at least a substream of the CO.sub.2- and H.sub.2S-laden absorbent is regenerated and a regenerated absorbent is obtained; and c) a recycling step in which at least a substream of the regenerated absorbent is recycled into the absorption step a). The process allows a high level of hydrogen sulfide removal with a simultaneously high coabsorption of carbon dioxide.

A process for removing hydrogen sulfide and carbon dioxide from a fluid stream comprises a) an absorption step in which the fluid stream is contacted with an absorbent comprising an aqueous solution (i) of an amine of the general formula (I)

##STR00001##

in which R.sub.1, R.sub.2 and R.sub.3 are each independently selected from C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.4 is independently selected from hydrogen, C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; each R.sub.5 is independently selected from hydrogen, C.sub.1-4-alkyl and C.sub.1-4-hydroxyalkyl; X is OH or NH(CR.sub.1R.sub.2R.sub.3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and optionally (ii) at least one tertiary amine, where the molar ratio of (i) to (ii) is greater than 0.05; wherein at least 90% of the hydrogen sulfide is removed from the fluid stream and selectivity for hydrogen sulfide over carbon dioxide is not greater than 8, wherein a CO.sub.2- and H.sub.2S-laden absorbent is obtained; b) a regeneration step in which at least a substream of the CO.sub.2- and H.sub.2S-laden absorbent is regenerated and a regenerated absorbent is obtained; and c) a recycling step in which at least a substream of the regenerated absorbent is recycled into the absorption step a). The process allows a high level of hydrogen sulfide removal with a simultaneously high coabsorption of carbon dioxide.

An absorbent for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, wherein the absorbent contains an aqueous solution, comprising: a) an amine or a mixture of amines of the general formula (I) wherein R.sup.1 is C.sub.1-C.sub.5-alkyl; R.sup.2 is C.sub.1-C.sub.5-alkyl; R.sup.3 is selected from hydrogen and C.sub.1-C.sub.5-alkyl; x is an integer from 2 to 10; and b) an ether or a mixture of ethers of the general formula (II): R.sup.4—[O—CH.sub.2—CH.sub.2].sub.y—OH; wherein R.sup.4 is C.sub.1-C.sub.5-alkyl; and y is an integer from 2 to 10; wherein R.sup.1 and R.sup.4 are identical; wherein the mass ratio of b) to a) is from 0.08 to 0.5. The absorbent is suitable for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and is easily obtainable. ##STR00001##

An absorbent for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, wherein the absorbent contains an aqueous solution, comprising: a) an amine or a mixture of amines of the general formula (I) wherein R.sup.1 is C.sub.1-C.sub.5-alkyl; R.sup.2 is C.sub.1-C.sub.5-alkyl; R.sup.3 is selected from hydrogen and C.sub.1-C.sub.5-alkyl; x is an integer from 2 to 10; and b) an ether or a mixture of ethers of the general formula (II): R.sup.4—[O—CH.sub.2—CH.sub.2].sub.y—OH; wherein R.sup.4 is C.sub.1-C.sub.5-alkyl; and y is an integer from 2 to 10; wherein R.sup.1 and R.sup.4 are identical; wherein the mass ratio of b) to a) is from 0.08 to 0.5. The absorbent is suitable for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and is easily obtainable. ##STR00001##