Patent classifications
C07C217/08
Absorbent and process for selectively removing hydrogen sulfide
An absorbent for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide, wherein the absorbent contains an aqueous solution, comprising: a) an amine or a mixture of amines of the general formula (I) wherein R.sup.1 is C.sub.1-C.sub.5-alkyl; R.sup.2 is C.sub.1-C.sub.5-alkyl; R.sup.3 is selected from hydrogen and C.sub.1-C.sub.5-alkyl; x is an integer from 2 to 10; and b) an ether or a mixture of ethers of the general formula (II): R.sup.4—[O—CH.sub.2—CH.sub.2].sub.y—OH; wherein R.sup.4 is C.sub.1-C.sub.5-alkyl; and y is an integer from 2 to 10; wherein R.sup.1 and R.sup.4 are identical; wherein the mass ratio of b) to a) is from 0.08 to 0.5. The absorbent is suitable for the selective removal of hydrogen sulfide from a fluid stream comprising carbon dioxide and hydrogen sulfide. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and is easily obtainable. ##STR00001##
Electrolyte salt and electrolyte for electricity storage device, and electricity storage device
Provided is an electrolyte salt comprising a quaternary ammonium cation indicated by formula (1) and a trimethylsilyl alkanesulfonate anion indicated by formula (2). ##STR00001##
(In the formula, R.sup.1-R.sup.4 each independently indicate a C1-4 alkyl group or an alkoxyalkyl group indicated by —(CH.sub.2).sub.n—OR. Any two among R.sup.1-R.sup.4 can mutually bond and form a ring together with a nitrogen atom to which same have bonded. The remaining two can mutually bond and form a spiro ring having a nitrogen atom as the spiro atom therefor. R indicates a methyl group or an ethyl group. n indicates 1 or 2 and m indicates 2 or 3.)
Electrolyte salt and electrolyte for electricity storage device, and electricity storage device
Provided is an electrolyte salt comprising a quaternary ammonium cation indicated by formula (1) and a trimethylsilyl alkanesulfonate anion indicated by formula (2). ##STR00001##
(In the formula, R.sup.1-R.sup.4 each independently indicate a C1-4 alkyl group or an alkoxyalkyl group indicated by —(CH.sub.2).sub.n—OR. Any two among R.sup.1-R.sup.4 can mutually bond and form a ring together with a nitrogen atom to which same have bonded. The remaining two can mutually bond and form a spiro ring having a nitrogen atom as the spiro atom therefor. R indicates a methyl group or an ethyl group. n indicates 1 or 2 and m indicates 2 or 3.)
ANIONIC-CATIONIC-NONIONIC SURFACTANT, PRODUCTION AND USE THEREOF
An anionic-cationic-nonionic surfactant as substantially represented by the formula (I) exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present anionic-cationic-nonionic surfactant, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.
##STR00001##
In the formula (I), each group is as defined in the specification.
ANIONIC-CATIONIC-NONIONIC SURFACTANT, PRODUCTION AND USE THEREOF
An anionic-cationic-nonionic surfactant as substantially represented by the formula (I) exhibits significantly improved interfacial activity and stability as compared with the prior art. With the present anionic-cationic-nonionic surfactant, a flooding fluid composition for tertiary oil recovery with improved oil displacement efficiency and oil washing capability as compared with the prior art could be produced.
##STR00001##
In the formula (I), each group is as defined in the specification.
LIPIDS FOR DELIVERY OF CHARGED MATERIAL, FORMULATIONS THEREOF AND METHOD FOR MAKING SAME
Disclosed herein is a lipid having a net charge at physiological pH, and being covalently attached to a lipid moiety. The lipid moiety comprises a hydrocarbon structure having two or more linked hydrocarbon chains, optionally having cis or trans C═C, at least one of said chains being covalently attached to the head group optionally via the linker region. The hydrocarbon chains are bonded to one another at a branch point at an internal carbon of the chain attached to the linker region, which branch point comprises a functional group having an electronegative atom. The hydrocarbon chains each have between 1 and 40 carbon atoms, wherein the hydrocarbon structure in total comprises between 10 and 150 carbon atoms. Advantageously, the hydrocarbon structure may assume a generally flared shape for enhanced delivery of cargo molecules. Further provided are delivery vehicles comprising the lipids.
Functionalized choline chloride ionic liquid, preparation method thereof and use in electrochemical energy storage device
The present invention discloses a process for preparing a functionalized choline chloride ionic liquid as defined in formula (I), and thereof use in an electrochemical energy storage device, as an electrolyte solution or an additive for a lithium ion battery and a supercapacitor. The ionic liquid electrolyte material has better biocompatibility, flame retardance, high ionic conductivity, low viscosity, and wide electrochemical window. ##STR00001## wherein R.sup.1 is selected from the group consisting of: (CH.sub.2═CH—(CH.sub.2).sub.n)—, CN(CH.sub.2).sub.n—, or R.sup.2.sub.3Si—; R.sup.2 is selected from CH.sub.3—(CH.sub.2).sub.m—, n is an integer selected from 1 to 3, m is an integer selected from 0 to 2; or one of R.sup.2 is (CH.sub.3).sub.3Si—O—. Anion A in Formula I is selected from the group consisting of: Cl.sup.−, Br.sup.−, I.sup.−, BF.sub.4.sup.−, NO.sub.3.sup.−, SO.sub.4.sup.2−, CF.sub.3COO.sup.−, CF.sub.3SO.sub.3.sup.−, (CF.sub.3SO.sub.2).sub.2N.sup.−, PF.sub.6.sup.−, BF.sub.2C.sub.2O.sub.4.sup.−, or B(C.sub.2O.sub.4).sub.2.sup.−.
Functionalized choline chloride ionic liquid, preparation method thereof and use in electrochemical energy storage device
The present invention discloses a process for preparing a functionalized choline chloride ionic liquid as defined in formula (I), and thereof use in an electrochemical energy storage device, as an electrolyte solution or an additive for a lithium ion battery and a supercapacitor. The ionic liquid electrolyte material has better biocompatibility, flame retardance, high ionic conductivity, low viscosity, and wide electrochemical window. ##STR00001## wherein R.sup.1 is selected from the group consisting of: (CH.sub.2═CH—(CH.sub.2).sub.n)—, CN(CH.sub.2).sub.n—, or R.sup.2.sub.3Si—; R.sup.2 is selected from CH.sub.3—(CH.sub.2).sub.m—, n is an integer selected from 1 to 3, m is an integer selected from 0 to 2; or one of R.sup.2 is (CH.sub.3).sub.3Si—O—. Anion A in Formula I is selected from the group consisting of: Cl.sup.−, Br.sup.−, I.sup.−, BF.sub.4.sup.−, NO.sub.3.sup.−, SO.sub.4.sup.2−, CF.sub.3COO.sup.−, CF.sub.3SO.sub.3.sup.−, (CF.sub.3SO.sub.2).sub.2N.sup.−, PF.sub.6.sup.−, BF.sub.2C.sub.2O.sub.4.sup.−, or B(C.sub.2O.sub.4).sub.2.sup.−.
Acid gas absorbent, acid gas removal device, and acid gas removal method
An acid gas absorbent includes at least one kind of secondary amine compound represented by formula (1): ##STR00001##
where R.sup.1 is a cyclopentyl group or a cyclohexyl group which may be substituted by a substituted or non-substituted alkyl group having 1 to 3 carbon atoms, R.sup.2 and R.sup.3 each indicate an alkylene group having 2 to 4 carbon atoms, and R.sup.2 and R.sup.3 may each be the same or different, and be a straight chain or have a side chain.
Acid gas absorbent, acid gas removal device, and acid gas removal method
An acid gas absorbent includes at least one kind of secondary amine compound represented by formula (1): ##STR00001##
where R.sup.1 is a cyclopentyl group or a cyclohexyl group which may be substituted by a substituted or non-substituted alkyl group having 1 to 3 carbon atoms, R.sup.2 and R.sup.3 each indicate an alkylene group having 2 to 4 carbon atoms, and R.sup.2 and R.sup.3 may each be the same or different, and be a straight chain or have a side chain.