Patent classifications
C08F222/1025
POLYMERIZABLE MONOMER, METHOD OF PRODUCING POLYMERIZABLE MONOMER, CURABLE COMPOSITION AND RESIN MEMBER
Provided are: a polymerizable monomer excellent in mechanical strength of its cured product and excellent also in handling property with low viscosity even under a room temperature environment, specifically, a polymerizable monomer, which is represented by the following general formula (1):
##STR00001##
in the general formula (1), Ar.sup.1 and Ar.sup.2 each represent an aromatic group having a valence selected from divalence to tetravalence, L.sup.1 and L.sup.2 each represent a divalent hydrocarbon group having a main chain with a number of atoms within a range of from 2 to 10 and containing at least one hydroxy group, and may be identical to or different from each other, R.sup.1 and R.sup.2 each represent hydrogen or a methyl group, q represents 0 or 1, and m1 and m2 each represent 1 or 2; and a method of producing the polymerizable monomer, a curable composition and a resin member each using the polymerizable monomer.
POLYMERIZABLE MONOMER, METHOD OF PRODUCING POLYMERIZABLE MONOMER, CURABLE COMPOSITION AND RESIN MEMBER
Provided are: a polymerizable monomer excellent in mechanical strength of its cured product and excellent also in handling property with low viscosity even under a room temperature environment, specifically, a polymerizable monomer, which is represented by the following general formula (1):
##STR00001##
in the general formula (1), Ar.sup.1 and Ar.sup.2 each represent an aromatic group having a valence selected from divalence to tetravalence, L.sup.1 and L.sup.2 each represent a divalent hydrocarbon group having a main chain with a number of atoms within a range of from 2 to 10 and containing at least one hydroxy group, and may be identical to or different from each other, R.sup.1 and R.sup.2 each represent hydrogen or a methyl group, q represents 0 or 1, and m1 and m2 each represent 1 or 2; and a method of producing the polymerizable monomer, a curable composition and a resin member each using the polymerizable monomer.
COATING METHOD
The present invention provides a coating method including: a step of supplying a coating agent to a surface of a lens base material; a spreading step of spreading the coating agent supplied to the surface by rotation of the lens base material; a first removal step of removing at least a part of a liquid pool of the coating agent generated on a peripheral edge portion and/or a side surface portion of the lens base material by rotation of the lens base material after the spreading step; and a second removal step of removing the liquid pool remaining on the peripheral edge portion and/or the side surface portion of the lens base material by bringing an adsorption member into contact with at least the side surface of the lens base material after the first removal step. According to the present invention, it is possible to provide a coating method capable of obtaining a base material having a coating layer excellent in uniformity of film thickness by reducing the liquid pool of the coating agent generated on the peripheral edge portion and/or the side surface portion of the lens base material when the coating layer is formed on the surface of the base material by spin coating the coating agent.
COATING METHOD
The present invention provides a coating method including: a step of supplying a coating agent to a surface of a lens base material; a spreading step of spreading the coating agent supplied to the surface by rotation of the lens base material; a first removal step of removing at least a part of a liquid pool of the coating agent generated on a peripheral edge portion and/or a side surface portion of the lens base material by rotation of the lens base material after the spreading step; and a second removal step of removing the liquid pool remaining on the peripheral edge portion and/or the side surface portion of the lens base material by bringing an adsorption member into contact with at least the side surface of the lens base material after the first removal step. According to the present invention, it is possible to provide a coating method capable of obtaining a base material having a coating layer excellent in uniformity of film thickness by reducing the liquid pool of the coating agent generated on the peripheral edge portion and/or the side surface portion of the lens base material when the coating layer is formed on the surface of the base material by spin coating the coating agent.
Cured product, optical member, lens, and compound
The present invention provides a cured product obtained by curing a curable composition including a compound represented by General Formula 1, in which a birefringence Δn (587 nm) is 0.00≤Δn (587 nm)≤0.01.
Pol.sub.1-Sp.sub.1-L.sub.1-Ar-L.sub.2-Sp.sub.2-Pol.sub.2 (General Formula 1) In the formula, Ar represents a divalent group containing a ring structure selected from the group consisting of a quinoxaline ring and a quinazoline ring; L.sub.1 and L.sub.2 each represent a single bond, —O—, —OC(═O)—, —OC(═O)O—, —OC(═O)NH—, and the like; Sp.sub.1 and Sp.sub.2 each represent a single bond or a divalent linking group; Pol.sub.1 and Pol.sub.2 each represent a hydrogen atom or a polymerizable group; and the compound represented by General Formula 1 has at least one polymerizable group. The cured product of the present invention has a small Abbe number (νd) and a large partial dispersion ratio (θg, F), and is therefore useful for production of optical members.
Cured product, optical member, lens, and compound
The present invention provides a cured product obtained by curing a curable composition including a compound represented by General Formula 1, in which a birefringence Δn (587 nm) is 0.00≤Δn (587 nm)≤0.01.
Pol.sub.1-Sp.sub.1-L.sub.1-Ar-L.sub.2-Sp.sub.2-Pol.sub.2 (General Formula 1) In the formula, Ar represents a divalent group containing a ring structure selected from the group consisting of a quinoxaline ring and a quinazoline ring; L.sub.1 and L.sub.2 each represent a single bond, —O—, —OC(═O)—, —OC(═O)O—, —OC(═O)NH—, and the like; Sp.sub.1 and Sp.sub.2 each represent a single bond or a divalent linking group; Pol.sub.1 and Pol.sub.2 each represent a hydrogen atom or a polymerizable group; and the compound represented by General Formula 1 has at least one polymerizable group. The cured product of the present invention has a small Abbe number (νd) and a large partial dispersion ratio (θg, F), and is therefore useful for production of optical members.
FUNCTIONALIZED POLY(2,6-DIMETHYL PHENYLENE OXIDE) OLIGOMERS CONTAINING DICYCLOPENTADIENE, METHOD OF PRODUCING THE SAME AND USE THEREOF
The invention discloses functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers containing dicyclopentadiene, a method of producing the same and use thereof. The cured products of the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention exhibit low dielectric constant, low dissipation, and high glass transition temperature. As the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention have number-average molecular weight ranging from 2500 to 6000 g/mol, the substrate made of theses functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers can pass the pressure cook test. Besides, the low dissipation factor characteristic the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention can only be demonstrated at number-average molecular weight higher than 2500 g/mol.
Dual cure stereolithography resins containing diels-alder adducts
Provided herein according to some embodiments is a dual cure stereolithography resin that includes a Diels-Alder adduct, which adduct is light polymerizable in the first, light, cure to produce an intermediate object, and on heating the intermediate object yields a bis-maleimide that can further react and/or polymerize during the second, heat, cure.
Dual cure stereolithography resins containing diels-alder adducts
Provided herein according to some embodiments is a dual cure stereolithography resin that includes a Diels-Alder adduct, which adduct is light polymerizable in the first, light, cure to produce an intermediate object, and on heating the intermediate object yields a bis-maleimide that can further react and/or polymerize during the second, heat, cure.
Polymerizable triptycene derivative compound, and polymer compound including same as constituent component
It is an objective of the present invention to provide a novel polymerizable triptycene derivative and a polymer compound as constituent component thereof that has a structure in which three benzene rings arranged at the axis formed by barrelene of the triptycene skeleton can rotate evenly and that has hydrophilicity imparted to it as compared to any of the prior art triptycene derivatives and is thus highly useful in functional materials. The above objective is achieved by the polymerizable triptycene derivative and a polymer compound as constituent component thereof having substituents with an unsaturated bonding functional group at position 9 and/or position 10 of the triptycene skeleton, the polymerizable triptycene derivative having two carboxyl groups and the polymerizable triptycene derivative having one carboxyl group and one amino group.