C08F222/1061

Curable compositions comprising mono-functional acrylates

Curable compositions include: a) at least one (meth)acrylate monomer or oligomer and b) at least one mono-functional (meth)acrylate monomer comprising a polycyclic moiety having at least three rings that are fused or condensed. The compositions may comprise an initiator system to render the compositions as curable. The compositions may comprise both the a) and b) components in an amount from about 30% to about 70% by weight. The compositions described herein are advantageous with respect to properties such as viscosity, toughness, tensile strength and tensile elongation. Due to their advantageous properties, the compositions are viable for a wide range of applications including coatings, adhesives, sealants, inks and stereolithography. The compositions are liquid at ambient temperature and impart a high glass transition temperature, Tg, without sacrificing other properties, such as elongation. The compositions are useful in 3D printing.

CRYSTALLIZABLE RESINS
20210147672 · 2021-05-20 ·

This disclosure provides polymeric materials comprising polymer crystals, methods and resins for making the same, and objects and appliances made from said polymeric materials. Polymeric materials having polymer crystals provide favorable properties, such as enhanced durability and rigidity. This disclosure also provides polymeric materials comprising a crystalline phase comprising at least one polymer crystal, as well as an amorphous phase comprising at least one amorphous polymer. The crystalline phase can confer rigidity to the polymeric material, while the amorphous phase can confer elasticity and flexibility.

CRYSTALLIZABLE RESINS
20210147672 · 2021-05-20 ·

This disclosure provides polymeric materials comprising polymer crystals, methods and resins for making the same, and objects and appliances made from said polymeric materials. Polymeric materials having polymer crystals provide favorable properties, such as enhanced durability and rigidity. This disclosure also provides polymeric materials comprising a crystalline phase comprising at least one polymer crystal, as well as an amorphous phase comprising at least one amorphous polymer. The crystalline phase can confer rigidity to the polymeric material, while the amorphous phase can confer elasticity and flexibility.

A RADIATION-CURABLE COATING COMPOSITION FOR IMPROVING THE SURFACE PROPERTIES OF PLASTICS

The present invention relates to a specific radiation-curable coating composition for improving the surface adhesion of plastic parts and its uses as a primer coat, as a base coat or as a clear coat. The composition may be pigmented or unpigmented and may be cured by UV and/or EB. The invention also relates to cured coating resulting from this cure and to the coated plastic substrate with improved surface adhesion.

Low temperature curable adhesive composition and articles including the same

A one part curable adhesive composition that includes a multifunctional (meth)acrylate oligomer the homopolymer of which has a glass transition temperature (Tg) of at least 100° C., and a first (meth)acrylate monomer exhibiting a viscosity of no greater than 1000 centipoise (cP) at 25° C., the first (meth)acrylate monomer being at least one of a (meth)acrylate monomer whose homopolymer has a Tg of at least 100° C. and (alkoxy) tetrahydrofurfuryl (meth)acrylate, the curable adhesive composition exhibiting a viscosity of no greater than 100,000 cP when measured at 25° C. and a shear rate of 20 sec.sup.−1.

LOW MIGRATION ENERGY CURABLE INKS
20210062020 · 2021-03-04 · ·

The present invention provides energy curable ink and coating compositions that comprise polymerizable compounds, photoinitiators, and colorants. The polymerizable compounds comprise one or more polymerizable monomers and/or oligomers, wherein at least a portion is 3-methyl-1,5-pentanediol diacrylate. The inks and coatings of the invention exhibit excellent print properties after UV-LED, standard UV mercury vapor lamp, and electron beam cure.

LOW MIGRATION ENERGY CURABLE INKS
20210062020 · 2021-03-04 · ·

The present invention provides energy curable ink and coating compositions that comprise polymerizable compounds, photoinitiators, and colorants. The polymerizable compounds comprise one or more polymerizable monomers and/or oligomers, wherein at least a portion is 3-methyl-1,5-pentanediol diacrylate. The inks and coatings of the invention exhibit excellent print properties after UV-LED, standard UV mercury vapor lamp, and electron beam cure.

ACTIVE-ENERGY-RAY-CURABLE COMPOSITION, ACTIVE-ENERGY-RAY-CURABLE INK, COMPOSITION STORED CONTAINER, TWO-DIMENSIONAL OR THREE-DIMENSIONAL IMAGE FORMING METHOD AND APPARATUS, CURED PRODUCT, AND DECORATED PRODUCT

An active-energy-ray-curable composition including a pigment, a polymerizable compound, and a pigment-adsorptive component is provided. The pigment is at least one selected from the group consisting of strontium titanate, calcium titanate, zinc sulfide, and zinc oxide. The polymerizable compound contains an acrylamide compound (A1) having a specific ester structure.

ACTIVE-ENERGY-RAY-CURABLE COMPOSITION, ACTIVE-ENERGY-RAY-CURABLE INK, COMPOSITION STORED CONTAINER, TWO-DIMENSIONAL OR THREE-DIMENSIONAL IMAGE FORMING METHOD AND APPARATUS, CURED PRODUCT, AND DECORATED PRODUCT

An active-energy-ray-curable composition including a pigment, a polymerizable compound, and a pigment-adsorptive component is provided. The pigment is at least one selected from the group consisting of strontium titanate, calcium titanate, zinc sulfide, and zinc oxide. The polymerizable compound contains an acrylamide compound (A1) having a specific ester structure.

CURABLE COMPOSITION, CURED PRODUCT, AND STACKED BODY

The present invention provides a curable composition which has a viscosity suitable for spray coating even at a high solid content and from which a cured product, on which precipitation of an ultraviolet absorber is suppressed and which has excellent weatherability and hot water resistance, is obtained, a cured product using the curable composition, and a stacked body.

Provided is a curable composition including: a (meth)acrylate A; a urethane (meth)acrylate B; an ultraviolet absorber C; and a photopolymerization initiator D, in which the (meth)acrylate A has at least one of a dendrimer structure and a hyperbranched structure, a content of the (meth)acrylate A is 55 parts by mass to 95 parts by mass based on 100 parts by mass in total of the (meth)acrylate A and the urethane (meth)acrylate B, a content of the ultraviolet absorber C is 1.5 parts by mass to 60 parts by mass based on 100 parts by mass in total of the (meth)acrylate A and the urethane (meth)acrylate B, a solid content concentration of the curable composition is greater than or equal to 70 mass %, and a viscosity of the curable composition at 25 C. which is measured with an E-type viscometer is less than or equal to 200 mPa.Math.s.