A photocurable composition for a hard coating material according to an aspect of the present invention contains (A) a polyfunctional polymerizable compound having three or more polymerizable double bonds, (B) an acrylic resin having a polymerizable double bond, (C) a polymerizable fluorine compound, and (D) a photopolymerization initiator.

Provided is a hard coating film for foldable displays that does not form creases or cracks in the folding portion, and that is also excellent in reducing iridescent colors (interference mottling) caused by fine cracks in an easy-to-adhere resin layer or other layers. The hard coating film for foldable displays contains a polyester film having a thickness of 10 to 80 μm, an easy-to-adhere resin layer, and a hard coating layer, the easy-to-adhere resin layer and the hard coating layer being stacked in this order on at least one surface of the polyester film, wherein the easy-to-adhere resin layer is a cured product of a composition containing at least one compound selected from the group consisting of titanium compounds and zirconium compounds and a polyester resin, and the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon satisfies characteristics within specific ranges.

Provided is a hard coating film for foldable displays that does not form creases or cracks in the folding portion, and that is also excellent in reducing iridescent colors (interference mottling) caused by fine cracks in an easy-to-adhere resin layer or other layers. The hard coating film for foldable displays contains a polyester film having a thickness of 10 to 80 μm, an easy-to-adhere resin layer, and a hard coating layer, the easy-to-adhere resin layer and the hard coating layer being stacked in this order on at least one surface of the polyester film, wherein the easy-to-adhere resin layer is a cured product of a composition containing at least one compound selected from the group consisting of titanium compounds and zirconium compounds and a polyester resin, and the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon satisfies characteristics within specific ranges.

According to the present invention, a lens adhesive including a compound represented by General Formula 1 is provided.
Pol.sub.1-Sp.sub.1-L.sub.1-Ar-L.sub.2-Sp.sub.2-Pol.sub.2  (General Formula 1) In the formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. ##STR00001## In the formula, Z.sub.1 and Z.sub.2 each represent a hydrogen atom, a methyl group, and the like; A.sub.1 and A.sub.2 each represent —S— and the like; X represents C(Rz).sub.2 and the like (where Rz is a substituent, and two Rz's may form a ring); L.sub.1 and L.sub.2 each represent a single bond, —O—, —OC(═O)—, —OC(═O)O—, —OC(═O)NH—, and the like; Sp.sub.1 and Sp.sub.2 each represent a single bond or a linking group such as a linear alkylene group; Pol.sub.1 and Pol.sub.2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group. Using the lens adhesive, it is possible to provide a cemented lens that is unlikely to deteriorate due to light, and an imaging module having high durability.

According to the present invention, a lens adhesive including a compound represented by General Formula 1 is provided.
Pol.sub.1-Sp.sub.1-L.sub.1-Ar-L.sub.2-Sp.sub.2-Pol.sub.2  (General Formula 1) In the formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. ##STR00001## In the formula, Z.sub.1 and Z.sub.2 each represent a hydrogen atom, a methyl group, and the like; A.sub.1 and A.sub.2 each represent —S— and the like; X represents C(Rz).sub.2 and the like (where Rz is a substituent, and two Rz's may form a ring); L.sub.1 and L.sub.2 each represent a single bond, —O—, —OC(═O)—, —OC(═O)O—, —OC(═O)NH—, and the like; Sp.sub.1 and Sp.sub.2 each represent a single bond or a linking group such as a linear alkylene group; Pol.sub.1 and Pol.sub.2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group. Using the lens adhesive, it is possible to provide a cemented lens that is unlikely to deteriorate due to light, and an imaging module having high durability.

A radiation-curable composition includes at least one monofunctional acrylate monomer and/or methacrylate monomer and/or at least one monofunctional acrylamide monomer, at least one multifunctional acrylate monomer and/or methacrylate monomer and at least one oligomer and/or at least one polymer, wherein the composition at 40° C. has a viscosity of ≥50 mPas, in particular >50 mPas.

A radiation-curable composition includes at least one monofunctional acrylate monomer and/or methacrylate monomer and/or at least one monofunctional acrylamide monomer, at least one multifunctional acrylate monomer and/or methacrylate monomer and at least one oligomer and/or at least one polymer, wherein the composition at 40° C. has a viscosity of ≥50 mPas, in particular >50 mPas.

The present invention is an optically clear, curable adhesive including a polyvinylbutyral, a polyurethane (meth)acrylate, a (meth)acrylate monomer, and a photoinitiator. The polyvinylbutyral has a dynamic viscosity of between about 9 and about 13 mPa.Math.s and a polyvinyl alcohol weight percent of less than about 18%. The polyurethane (meth)acrylate includes the reaction product of a diol, at least one diisocyanate, and a hydroxyfunctional (meth)acrylate or an isocyanatofunctional (meth)acrylate. When the optically clear, curable adhesive is placed between two transparent substrates and made into a laminate, the laminate has a haze of less than about 6%, a transmission of greater than about 88%, and an optical clarity of greater than about 98% when cured. The optically clear, curable adhesive also has a peel adhesion of at least about 100 g/cm based on ASTM 3330 when cured.

The present invention is an optically clear, curable adhesive including a polyvinylbutyral, a polyurethane (meth)acrylate, a (meth)acrylate monomer, and a photoinitiator. The polyvinylbutyral has a dynamic viscosity of between about 9 and about 13 mPa.Math.s and a polyvinyl alcohol weight percent of less than about 18%. The polyurethane (meth)acrylate includes the reaction product of a diol, at least one diisocyanate, and a hydroxyfunctional (meth)acrylate or an isocyanatofunctional (meth)acrylate. When the optically clear, curable adhesive is placed between two transparent substrates and made into a laminate, the laminate has a haze of less than about 6%, a transmission of greater than about 88%, and an optical clarity of greater than about 98% when cured. The optically clear, curable adhesive also has a peel adhesion of at least about 100 g/cm based on ASTM 3330 when cured.

Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.