There is provided a curable composition, which forms a cured product with high light transmittance, a high refractive index, and high scratch resistance, a cured product thereof, and an optical member. A curable composition contains zirconium oxide nanoparticles, a dispersant, and a (meth)acrylate compound. The dispersant has an acid value in the range of 100 to 300 mgKOH/g. The (meth)acrylate compound contains a (meth)acrylate compound having a poly(alkylene oxide) structure.

There is provided a curable composition, which forms a cured product with high light transmittance, a high refractive index, and high scratch resistance, a cured product thereof, and an optical member. A curable composition contains zirconium oxide nanoparticles, a dispersant, and a (meth)acrylate compound. The dispersant has an acid value in the range of 100 to 300 mgKOH/g. The (meth)acrylate compound contains a (meth)acrylate compound having a poly(alkylene oxide) structure.

An optical fiber comprises a glass fiber, and a coating resin layer having a primary resin layer and a secondary resin layer, wherein the primary resin layer consists of a cured resin composition containing an oligomer, a monomer and a photopolymerization initiator, the oligomer is a reaction product of a specific polyol compound, a polyisocyanate compound, and a hydroxyl group-containing acrylate compound, the photopolymerization initiator includes 2,4,6-trimethylbenzoyldiphenyl phosphine and 1-hydroxycyclohexyl phenyl ketone at a mass ratio of 5:1 to 1:1, and a content of 2,4,6-trimethylbenzoyldiphenyl phosphine in the resin composition is 1.5 to 2.5% by mass.

An optical fiber comprises a glass fiber, and a coating resin layer having a primary resin layer and a secondary resin layer, wherein the primary resin layer consists of a cured resin composition containing an oligomer, a monomer and a photopolymerization initiator, the oligomer is a reaction product of a specific polyol compound, a polyisocyanate compound, and a hydroxyl group-containing acrylate compound, the photopolymerization initiator includes 2,4,6-trimethylbenzoyldiphenyl phosphine and 1-hydroxycyclohexyl phenyl ketone at a mass ratio of 5:1 to 1:1, and a content of 2,4,6-trimethylbenzoyldiphenyl phosphine in the resin composition is 1.5 to 2.5% by mass.

There is provided a method of producing a polymerizable composition that includes a first polymerizable monomer; and a second polymerizable monomer, a polymer of the second polymerizable monomer, or both, the second polymerizable monomer, the polymer of the second polymerizable monomer, or the both being dispersed in the first polymerizable monomer, the method of producing a polymerizable composition includes dissolving the first polymerizable monomer; the second polymerizable monomer, the polymer of the second polymerizable monomer, or the both in a solvent to obtain a solution in a first step; and evaporating the solvent from the solution in a second step, wherein the first polymerizable monomer is a liquid, and wherein the second polymerizable monomer is a solid.

There is provided a method of producing a polymerizable composition that includes a first polymerizable monomer; and a second polymerizable monomer, a polymer of the second polymerizable monomer, or both, the second polymerizable monomer, the polymer of the second polymerizable monomer, or the both being dispersed in the first polymerizable monomer, the method of producing a polymerizable composition includes dissolving the first polymerizable monomer; the second polymerizable monomer, the polymer of the second polymerizable monomer, or the both in a solvent to obtain a solution in a first step; and evaporating the solvent from the solution in a second step, wherein the first polymerizable monomer is a liquid, and wherein the second polymerizable monomer is a solid.

A dental curable composition which comprises a radically polymerizable monomer component (A), a polymerizing catalyst (B) and an inorganic granular material (C), characterized in that: the radically polymerizable monomer component (A) contains a bifunctional monomer (A-1) represented by the following formula (α),
R.sub.P—SP.sup.1—R.sub.P  (α) where, R.sub.P is a radically polymerizable group represented by CH.sub.2═C(R)—COO— or CH.sub.2═C(R)—CONH—, wherein R is a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, and SP.sup.1 is a hydrocarbon group having 5 to 15 carbon atoms, and the content of the bifunctional monomer (A-1) in the radically polymerizable monomer component (A) is 5 to 40% by mass under a condition that the content of a diluting monomer (A-2) represented by the following formula (β),
R.sub.P—SP.sup.2—R.sub.P  (β) where, R.sub.P is as defined in the above formula (α), and SP.sup.2 is an aliphatic hydrocarbon group different from SP.sup.1, an oxygen-containing aliphatic hydrocarbon group having not less than 2 oxygen atoms, or an oxygen-containing aromatic hydrocarbon group having not less than 3 oxygen atoms,
is zero or not more than 10% by mass.

A dental curable composition which comprises a radically polymerizable monomer component (A), a polymerizing catalyst (B) and an inorganic granular material (C), characterized in that: the radically polymerizable monomer component (A) contains a bifunctional monomer (A-1) represented by the following formula (α),
R.sub.P—SP.sup.1—R.sub.P  (α) where, R.sub.P is a radically polymerizable group represented by CH.sub.2═C(R)—COO— or CH.sub.2═C(R)—CONH—, wherein R is a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms, and SP.sup.1 is a hydrocarbon group having 5 to 15 carbon atoms, and the content of the bifunctional monomer (A-1) in the radically polymerizable monomer component (A) is 5 to 40% by mass under a condition that the content of a diluting monomer (A-2) represented by the following formula (β),
R.sub.P—SP.sup.2—R.sub.P  (β) where, R.sub.P is as defined in the above formula (α), and SP.sup.2 is an aliphatic hydrocarbon group different from SP.sup.1, an oxygen-containing aliphatic hydrocarbon group having not less than 2 oxygen atoms, or an oxygen-containing aromatic hydrocarbon group having not less than 3 oxygen atoms,
is zero or not more than 10% by mass.

The present invention is intended to provide an adhesive composition for temporarily fixing which exhibits high adhesive strength and peeling property in water, and which is applicable to members having opaque area, and still which leaves no adhesive deposit on released members, so that it realize the excellent workability and environment. The present invention is a two-component composition for temporarily fixing members, comprising (A) a polyfunctional (meth)acrylate, (B) a mono-functional (meth)acrylate, (C) an organic peroxide, (D) a decomposition accelerator, (E) a polymerization initiator and (G) particulate matter, and composed of two-component system of a first agent and a second agent, said first agent containing at least said component (C) and said second agent containing at least said component (D), wherein cured body of said composition being used to bond members is brought into contact with water to be decomposed and release said members.

A UV-curable and recyclable thermoset shape memory polymer is provided. The polymer includes a vitrimer-based monomer and a photoinitiator. The vitrimer-based monomer includes a first unit rendering a high chain stiffness upon polymerization of the monomer, and a second photopolymerizable unit for photopolymerization of the monomer under a UV irradiation. The polymer has high strength, high stiffness, high recovery stress, high energy storage, reasonable recycling efficiency, and is printable using SLA with high resolution.