Small-radius coated optical fibers having large mode field diameter and low bending losses. The coated fiber may have an outer radius of 110 μm or less, while providing a mode field diameter of 9.0 μm or greater and a bending loss when wrapped about a 15 mm mandrel of 0.5 dB/km or less at wavelength of 1550 nm. The coated fiber may have a mode field diameter of 9.2 μm or greater and may have a bending loss at 1550 nm of 0.25 dB/km or less when wrapped about a 20 mm mandrel or a bending loss at 1550 nm of 0.02 dB/km or less when wrapped about a 30 mm mandrel.

Small-radius coated optical fibers having large mode field diameter and low bending losses. The coated fiber may have an outer radius of 110 μm or less, while providing a mode field diameter of 9.0 μm or greater and a bending loss when wrapped about a 15 mm mandrel of 0.5 dB/km or less at wavelength of 1550 nm. The coated fiber may have a mode field diameter of 9.2 μm or greater and may have a bending loss at 1550 nm of 0.25 dB/km or less when wrapped about a 20 mm mandrel or a bending loss at 1550 nm of 0.02 dB/km or less when wrapped about a 30 mm mandrel.

Curable compositions include: a) at least one (meth)acrylate monomer or oligomer and b) at least one mono-functional (meth)acrylate monomer comprising a polycyclic moiety having at least three rings that are fused or condensed. The compositions may comprise an initiator system to render the compositions as curable. The compositions may comprise both the a) and b) components in an amount from about 30% to about 70% by weight. The compositions described herein are advantageous with respect to properties such as viscosity, toughness, tensile strength and tensile elongation. Due to their advantageous properties, the compositions are viable for a wide range of applications including coatings, adhesives, sealants, inks and stereolithography. The compositions are liquid at ambient temperature and impart a high glass transition temperature, Tg, without sacrificing other properties, such as elongation. The compositions are useful in 3D printing.

Diffractive optical element includes two resin layers stacked on first substrate. One of the two resin layers is cured article of first resin containing thiol group and sulfide group, the cured article having diffraction grating shape. The other is cured article of second resin, the cured article having diffraction grating shape. When measurement is performed by laser Raman spectroscopy, α<β, where α is the ratio of the intensity of peak corresponding to the sulfide group to the intensity of peak corresponding to the thiol group in first region containing no interface between the cured articles of the first and second resins, and β is the ratio of the intensity of peak corresponding to the sulfide group to the intensity of peak corresponding to the thiol group in second region containing the interface.

Diffractive optical element includes two resin layers stacked on first substrate. One of the two resin layers is cured article of first resin containing thiol group and sulfide group, the cured article having diffraction grating shape. The other is cured article of second resin, the cured article having diffraction grating shape. When measurement is performed by laser Raman spectroscopy, α<β, where α is the ratio of the intensity of peak corresponding to the sulfide group to the intensity of peak corresponding to the thiol group in first region containing no interface between the cured articles of the first and second resins, and β is the ratio of the intensity of peak corresponding to the sulfide group to the intensity of peak corresponding to the thiol group in second region containing the interface.

The present invention provides a wavelength conversion member including a wavelength conversion layer, the wavelength conversion layer including a quantum dot phosphor, and having a structure derived from a hindered amine-based compound, and a sulfide structure.

The present invention provides a wavelength conversion member including a wavelength conversion layer, the wavelength conversion layer including a quantum dot phosphor, and having a structure derived from a hindered amine-based compound, and a sulfide structure.

A UV-curable and recyclable thermoset shape memory polymer is provided. The polymer includes a vitrimer-based monomer and a photoinitiator. The vitrimer-based monomer includes a first unit rendering a high chain stiffness upon polymerization of the monomer, and a second photopolymerizable unit for photopolymerization of the monomer under a UV irradiation. The polymer has high strength, high stiffness, high recovery stress, high energy storage, reasonable recycling efficiency, and is printable using SLA with high resolution.

A UV-curable and recyclable thermoset shape memory polymer is provided. The polymer includes a vitrimer-based monomer and a photoinitiator. The vitrimer-based monomer includes a first unit rendering a high chain stiffness upon polymerization of the monomer, and a second photopolymerizable unit for photopolymerization of the monomer under a UV irradiation. The polymer has high strength, high stiffness, high recovery stress, high energy storage, reasonable recycling efficiency, and is printable using SLA with high resolution.

Provided herein are crosslinked polymers useful in orthodontic appliances and light polymerizable liquid compositions and formulations useful for making crosslinked polymers. Also provided are methods of making an orthodontic appliance comprising a cross-linked polymer formed by a direct fabrication technique.