Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, a method of producing crosslinked polymers using said curable compositions, crosslinked polymers thus produced, and orthodontic appliances comprising the crosslinked polymers.

1) Ionic silylated copolyurethane of formula:

##STR00001##

in which R.sup.1 is a hydrocarbon radical; R.sup.2 is a C2-C4 alkylene; n is an integer such that the molecular mass of —[OR.sup.2].sub.n is 2500-20 000 g/mol; R.sup.∘ is H or C1-C18 alkyl; R, R′ and R″ are a hydrocarbon-based radical; x and y are integers from 1 à 8; z is an integer from 0 to 8; m and q are an integer of greater than or equal to 1, such that q/m ranges from 0.04 to 20; F.sup.1 is a radical of formula (IIa) and F.sup.2 is a radical of formula (IIb):

##STR00002## in which R.sup.3 is methylene or n-propylene; R.sup.4 and R.sup.5 are methyl or ethyl; p is equal to 0 or 1; R.sup.6 is a C1-C4 alkyl.

2) Process for preparing copolyurethane 1), comprising: (i) polyaddition between a polyisocyanate, a polyether diol and a carboxylic diol; (ii) neutralization of the product formed with the amine N(R)(R′)(R″); then (iii) reaction with an aminosilane derived from a secondary amine.

3) Composition, usable as sealant and/or adhesive, comprising copolyurethane 1) and a filler.

Described are sealing primer compositions that can be used to reduce paint defects such as pops or vapor boil on painted plastic substrates, as well as related methods for sealing plastic substrates, and sealed plastic substrates. Sealing primer compositions of the invention include a functionalized polydiene polymer such as a hydroxylated or other functional-group-containing polybutadiene polymer.

The present invention relates to gel compositions comprising a polyurethane elastomer. The polyurethane elastomer is formed from the reaction of a polyol, a polyisocyanate, and optionally a polyurethane reaction catalyst, optionally in the presence of a topically acceptable carrier fluid. In some embodiments, the gel composition comprises a personal active ingredient or a healthcare active ingredient, which may be incorporated into the gel composition via a pre-load method or a post-load method. Also provided herein are gel pastes and topical formulations comprising the polyurethane elastomers, and methods of making the same.

Provided is a composition capable of forming a cured product excelling in adhesion to a substrate, hardness, scratch resistance, and chemical resistance. The composition of the present disclosure contains a polyol compound (A) and an isocyanate compound (B) The polyol compound (A) includes a compound (a1) represented by Formula (1) below, where R.sup.1 to R.sup.3 each are a group represented by Formula (1a), the compound (a1) having a number average molecular weight (calibrated with polystyrene standard) of 800 or greater. The isocyanate compound (B) includes a polyisocyanate compound having an isocyanurate skeleton.

Provided is a composition capable of forming a cured product excelling in adhesion to a substrate, hardness, scratch resistance, and chemical resistance. The composition of the present disclosure contains a polyol compound (A) and an isocyanate compound (B) The polyol compound (A) includes a compound (a1) represented by Formula (1) below, where R.sup.1 to R.sup.3 each are a group represented by Formula (1a), the compound (a1) having a number average molecular weight (calibrated with polystyrene standard) of 800 or greater. The isocyanate compound (B) includes a polyisocyanate compound having an isocyanurate skeleton.

This disclosure provides methods for the chemical modification of microbial derived triglyceride oils, use thereof in polyurethane chemistries, and incorporation thereof in the production of sporting goods equipment, including, for example, alpine skis, touring skis, cross country skis, approach skis, split boards, snowboards, surfboards, paddleboards, and water skis.

This disclosure provides methods for the chemical modification of microbial derived triglyceride oils, use thereof in polyurethane chemistries, and incorporation thereof in the production of sporting goods equipment, including, for example, alpine skis, touring skis, cross country skis, approach skis, split boards, snowboards, surfboards, paddleboards, and water skis.

A moisture-curable composition, including at least one organic polymer P containing reactive silane groups, between 1.0 wt.-% and 25.0 wt.-%, preferably between 2.0 wt.-% and 20 wt.-%, in particular between 2.5 wt.-% and 10 wt.-%, based on the total composition, of dimethyl or diethyl esters of aliphatic C3 to C5 dicarboxylic acids, and at least one curing catalyst for alkoxysilane groups. The moisture-curable composition is particularly suitable as elastic adhesive, coating, filler, or sealant and shows superior overpaintability, in particular with automotive topcoats or similar paints.

The present invention relates to a crosslinkable composition comprising a polyol, a polyisocyanate crosslinker, a catalyst for catalysing the reaction between —OH groups of said polyol and —NCO groups of said crosslinker, a tertiary acid of formula RR′R″CCOOH (I), wherein each R, R′ and R″ group, independently, is an alkyl, alkenyl, aryl or aralkyl group containing at least one carbon atom, with the proviso that two or three of the R, R′ and R″ groups can be linked to form a ring structure and wherein the R, R′ and/or R″ groups can be substituted, and optionally, a complexing agent containing at least one —SH group, as well as its use for making coatings having improved application properties.