A continuous method for the manufacture of a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprising continuously heating an anhydride with a phenol in the presence of a catalyst and a first co-catalyst, to form a first reaction mixture comprising a phenolphthalein compound; precipitating the phenolphthalein compound; combining a primary arylamine with an acid catalyst and a second co-catalyst to form a second reaction mixture; adding the phenolphthalein compound to the second reaction mixture; continuously heating the second reaction mixture to provide a third reaction mixture comprising a crude phthalimidine; and treating the crude phthalimidine to remove aminophenol and purify the phthalimidine is provided.

A continuous method for the manufacture of a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprising continuously heating an anhydride with a phenol in the presence of a catalyst and a first co-catalyst, to form a first reaction mixture comprising a phenolphthalein compound; precipitating the phenolphthalein compound; combining a primary arylamine with an acid catalyst and a second co-catalyst to form a second reaction mixture; adding the phenolphthalein compound to the second reaction mixture; continuously heating the second reaction mixture to provide a third reaction mixture comprising a crude phthalimidine; and treating the crude phthalimidine to remove aminophenol and purify the phthalimidine is provided.

A method for the purification of a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine of formula (I), the method comprising heating a reaction mixture comprising a phenolphthalein compound of formula (II) and a primary arylamine of formula (III) in the presence of an acid catalyst to form a reaction mixture; removing water from the reaction mixture; quenching the reaction mixture with an aqueous alkali solution to form a quenched reaction mixture; extracting the quenched reaction mixture with an aminoaryl compound of formula (IV) to form an organic layer and an extracted aqueous layer comprising a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine compound; contacting the extracted aqueous layer with carbon to form a semi-purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine compound; and mixing the semi-purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine compound with a solution comprising an alcohol and an acid to form a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine of formula (I); wherein formulas (I), (II), (III), and (IV) are as provided herein.

A method for the purification of a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine of formula (I), the method comprising heating a reaction mixture comprising a phenolphthalein compound of formula (II) and a primary arylamine of formula (III) in the presence of an acid catalyst to form a reaction mixture; removing water from the reaction mixture; quenching the reaction mixture with an aqueous alkali solution to form a quenched reaction mixture; extracting the quenched reaction mixture with an aminoaryl compound of formula (IV) to form an organic layer and an extracted aqueous layer comprising a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine compound; contacting the extracted aqueous layer with carbon to form a semi-purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine compound; and mixing the semi-purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine compound with a solution comprising an alcohol and an acid to form a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine of formula (I); wherein formulas (I), (II), (III), and (IV) are as provided herein.

A purified 2-hydrocarbyl-3-(dihydroxyfluoresceinyl)phthalimidine compound of formula (I):

##STR00001##

wherein R is a C.sub.1-25 hydrocarbyl; each occurrence of R.sup.2 and R.sup.3 is independently a halogen or a C.sub.1-25 hydrocarbyl; p is 0 to 4; and each q is independently 0 to 3; and wherein the purified 2-hydrocarbyl-3-(dihydroxyfluoresceinyl)phthalimidine compound of formula (I) has a purity of greater than 99.4%, as determined by high performance liquid chromatography.

A thermoplastic composition comprising a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of formula (1a)

##STR00001##

wherein R is a C.sub.1-25 hydrocarbyl; each occurrence of R.sup.2 and R.sup.3 is independently a halogen or a C.sub.1-25 hydrocarbyl; p is 0 to 4; and each q is independently 0 to 3; and optionally a bisphenol A homopolycarbonate.

A thermoplastic composition comprising a copolycarbonate comprising bisphenol A carbonate units and second carbonate units of formula (1a)

##STR00001##

wherein R is a C.sub.1-25 hydrocarbyl; each occurrence of R.sup.2 and R.sup.3 is independently a halogen or a C.sub.1-25 hydrocarbyl; p is 0 to 4; and each q is independently 0 to 3; and optionally a bisphenol A homopolycarbonate.

A thermoplastic polymer composition including 10 to 99 wt % of a phthalimidine copolycarbonate having a glass transition temperature of greater than 150 C., preferably greater than 170 C., as measured using differential scanning calorimetry; 1 to 90 wt % of a poly(etherimide-siloxane) copolymer; and 0 to 10 wt % of an additive is provided.

A thermoplastic polymer composition including 10 to 99 wt % of a phthalimidine copolycarbonate having a glass transition temperature of greater than 150 C., preferably greater than 170 C., as measured using differential scanning calorimetry; 1 to 90 wt % of a poly(etherimide-siloxane) copolymer; and 0 to 10 wt % of an additive is provided.

Provided are copolycarbonate compositions including a stabilizer package which comprise a phosphorous-containing acid, an ester of phosphorous-containing acid, and an organosulfonic stabilizer where the phosphorous-containing acid and the ester of a phosphorous-containing acid are present in a molar ratio of 1 to 2. The total stabilization package is for example, in the amount by weight of 4 to 32 ppm, 8 to 24 ppm, or 8 to 16 ppm and the organosulfonic stabilizer is, e.g., of 2 to 30 ppm, or 4 to 24 ppm, or 8 to 16 ppm.