C08G65/326

SUBSTOICHIOMETRIC ALKOXYLATED POLYETHERS

Provided herein are polymers obtainable by a process including the steps a) and b) described below. In Step a) at least one component a1) is condensed to obtain a polyether having remaining hydroxyl groups. Component a1) is at least one component selected from N-(hydroxyalkyl) am ins according to formula (Ia) and/or (Ib) as defined below. Besides component a1), further components can be present in the condensation step a). In step b) a part of the remaining hydroxyl groups are reacted with at least one alkylene oxide. The alkoxylation according to step b) is carried out in a substoichiometric way. The ratio of i) the alkylene oxide versus ii) the sum of the amount of the remaining hydroxyl groups is >0:1 to <1:1 [mol/mol]. Further provided herein is a process for preparing such polymers and derivatives of the polymers by quaternization, protonation, sulphation and/or phosphation.

SUBSTOICHIOMETRIC ALKOXYLATED POLYETHERS

Provided herein are polymers obtainable by a process including the steps a) and b) described below. In Step a) at least one component a1) is condensed to obtain a polyether having remaining hydroxyl groups. Component a1) is at least one component selected from N-(hydroxyalkyl) am ins according to formula (Ia) and/or (Ib) as defined below. Besides component a1), further components can be present in the condensation step a). In step b) a part of the remaining hydroxyl groups are reacted with at least one alkylene oxide. The alkoxylation according to step b) is carried out in a substoichiometric way. The ratio of i) the alkylene oxide versus ii) the sum of the amount of the remaining hydroxyl groups is >0:1 to <1:1 [mol/mol]. Further provided herein is a process for preparing such polymers and derivatives of the polymers by quaternization, protonation, sulphation and/or phosphation.

CHALCOGENIDE NANOOBJECTS AND USE THEREOF AS ADDITIVE

The present invention provides a Molybdenum or Tungsten chalcogenide nanoobject having: (a) an object size comprised from 0.1 to 500 nm, and (b) from 1 to 99% by weight of molecules of formula (I) with respect to the total weight of the nanoobject, wherein: A is OH; X is selected from: (C.sub.1-C.sub.20)alkyl optionally substituted with one or more radicals; a 2 to 20-member heteroalkyl optionally substituted with one or more radicals; and a homopolymer or copolymer comprising a polymeric chain; B is selected from: H, OH, NH.sub.2, (C.sub.1-C.sub.4)alkyl, halogen, phenyl substituted with one or more halogen radicals, benzyl substituted with one or more halogen radicals, C(O)R.sub.3, C(O)(R.sub.7), OC(O)(O)R.sub.3, C(O)(O.sup.), C(O)(O)R.sub.3, OR.sub.3, CH(OR.sub.3)(OR.sub.4), C(OR.sub.3)(OR.sub.4)(R.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5)(OR.sub.6), NR.sub.1R.sub.2, N.sup.+R.sub.1R.sub.2R.sub.3, C(NR.sub.1)(R.sub.2), C(O)(NR.sub.1R.sub.2), N(C(O)(R.sub.1)) (C(O)(R.sub.2))(R.sub.3), O(CN), NC(O), ONO.sub.2, CN, NC, ON(O), NO.sub.2, NO, C.sub.5H.sub.4N, SR.sub.1, SSR.sub.1, S(O)(R.sub.1), S(O)(O)(R.sub.1), S(O)(OH), S(O)(O)(OH), SCN, NCS, C(S)(R.sub.1), PR.sub.1R.sub.2, P(O)(OH).sub.2, OP(O)(OH).sub.2, OP(O)(OR.sub.1)(OR.sub.2), B(OH), B(OR.sub.1)(OR.sub.2), and B(OR.sub.1)(R.sub.2); provided that when B is H or (C.sub.1-C.sub.4) alkyl, then X is a homopolymer, a copolymer, or a 2 to 20-member heteroalkyl optionally substituted with one or more radicals as defined above.

The present invention also provides processes for the preparation of the nanoobjects, their use as additive for reducing the friction coefficient of a material, and compositions comprising thereof.


A-X-B(I)

CHALCOGENIDE NANOOBJECTS AND USE THEREOF AS ADDITIVE

The present invention provides a Molybdenum or Tungsten chalcogenide nanoobject having: (a) an object size comprised from 0.1 to 500 nm, and (b) from 1 to 99% by weight of molecules of formula (I) with respect to the total weight of the nanoobject, wherein: A is OH; X is selected from: (C.sub.1-C.sub.20)alkyl optionally substituted with one or more radicals; a 2 to 20-member heteroalkyl optionally substituted with one or more radicals; and a homopolymer or copolymer comprising a polymeric chain; B is selected from: H, OH, NH.sub.2, (C.sub.1-C.sub.4)alkyl, halogen, phenyl substituted with one or more halogen radicals, benzyl substituted with one or more halogen radicals, C(O)R.sub.3, C(O)(R.sub.7), OC(O)(O)R.sub.3, C(O)(O.sup.), C(O)(O)R.sub.3, OR.sub.3, CH(OR.sub.3)(OR.sub.4), C(OR.sub.3)(OR.sub.4)(R.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5), C(OR.sub.3)(OR.sub.4)(OR.sub.5)(OR.sub.6), NR.sub.1R.sub.2, N.sup.+R.sub.1R.sub.2R.sub.3, C(NR.sub.1)(R.sub.2), C(O)(NR.sub.1R.sub.2), N(C(O)(R.sub.1)) (C(O)(R.sub.2))(R.sub.3), O(CN), NC(O), ONO.sub.2, CN, NC, ON(O), NO.sub.2, NO, C.sub.5H.sub.4N, SR.sub.1, SSR.sub.1, S(O)(R.sub.1), S(O)(O)(R.sub.1), S(O)(OH), S(O)(O)(OH), SCN, NCS, C(S)(R.sub.1), PR.sub.1R.sub.2, P(O)(OH).sub.2, OP(O)(OH).sub.2, OP(O)(OR.sub.1)(OR.sub.2), B(OH), B(OR.sub.1)(OR.sub.2), and B(OR.sub.1)(R.sub.2); provided that when B is H or (C.sub.1-C.sub.4) alkyl, then X is a homopolymer, a copolymer, or a 2 to 20-member heteroalkyl optionally substituted with one or more radicals as defined above.

The present invention also provides processes for the preparation of the nanoobjects, their use as additive for reducing the friction coefficient of a material, and compositions comprising thereof.


A-X-B(I)

Hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof
20240352190 · 2024-10-24 ·

A hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof are provided. The hydrocarbyl tetralin polyethersulfonate is of formula (I-0),

##STR00001##

The hydrocarbyl tetralin polyethersulfonate has a high surface and interface activity, can be used in an oil reservoir exploitation, especially in a high-temperature and high-salt oil reservoir exploitation, to improve crude oil recovery.

Hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof
20240352190 · 2024-10-24 ·

A hydrocarbyl tetralin polyethersulfonate, preparation method therefor and use thereof are provided. The hydrocarbyl tetralin polyethersulfonate is of formula (I-0),

##STR00001##

The hydrocarbyl tetralin polyethersulfonate has a high surface and interface activity, can be used in an oil reservoir exploitation, especially in a high-temperature and high-salt oil reservoir exploitation, to improve crude oil recovery.

Anionic surfactant compositions and use thereof

Provided are surfactant compositions that are useful as alternatives to alkylphenol ethoxylates (APEs) type surfactants in emulsion polymerization. The surfactant compositions comprise: an alkyl alkoxylate sulfate of formula (I): R.sup.1O(CH.sub.2CH(R.sup.2)O).sub.x(CH.sub.2CH.sub.2O).sub.ySO.sub.3M wherein R.sup.1, R.sup.2, x, y, and M are as defined herein.

Anionic surfactant compositions and use thereof

Provided are surfactant compositions that are useful as alternatives to alkylphenol ethoxylates (APEs) type surfactants in emulsion polymerization. The surfactant compositions comprise: an alkyl alkoxylate sulfate of formula (I): R.sup.1O(CH.sub.2CH(R.sup.2)O).sub.x(CH.sub.2CH.sub.2O).sub.ySO.sub.3M wherein R.sup.1, R.sup.2, x, y, and M are as defined herein.

Additives to improve open-time and freeze-thaw characteristics of water-based paints and coatings

Waterborne coatings are described having an acceptable balance of properties both during the storage of coating, application and drying. The period in which irregularities in a freshly applied coating can be repaired without resulting in brush marks is referred to as the open time. Aqueous coatings generally employ dispersed high molecular weight polymers as binders. These binders often provide short open times when the coating is dried since the dispersed polymer particles tend to be immobilized quickly in the edge region of an applied coating. As a result, the viscosity of the coating increases rapidly, which leads to a limited window of workability. The instant invention provides additives that are not volatile but that will extend the time that the film is malleable after it is applied without interfering with other attributes, such as the resistance of the coating to freezing while in the can prior to application.

Alkylaniline polyether benzenesulfonate and process of producing same

A process for the conversion of methanol to olefins includes the steps of passing a feedstock comprising methanol to a fluidized bed reactor in contact with a catalyst to produce an olefin product, wherein the process at least partially deactivates the catalyst to form an at least partially deactivated catalyst; and passing spent catalyst from said at least partially deactivated catalyst to a regenerator for regeneration thereby forming regenerated catalyst and returning activated catalyst from said regenerated catalyst to said reactor via a regenerated catalyst line. An oxygen volume content in the gas-phase component at the outlet of the regenerated catalyst pipeline is controlled to be less than 0.1 percent, preferably less than 0.05% and more preferably less than 0.01% on the regenerated catalyst pipeline.