Provided are a solid electrolyte composition including: an inorganic solid electrolyte having conductivity of an ion of metal belong to Group 1 or 2 in the periodic table; and a high polymer binder, in which the high polymer binder is formed of a polymer having a hard segment and a soft segment, a binder for all-solid-state secondary batteries, and an electrode sheet for batteries and an all-solid-state secondary battery each using the solid electrolyte composition.

Provided are an imide-terminated prepolymer, a preparation method therefor, a curable resin composition, use thereof and a dual curing method. An end capped, imide-terminated prepolymer is mixed with at least one photopolymerizable ethylenic monomer, at least one photoinitiator and diamine, and optionally a pigment to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one ethylenic monomer. The irradiated composition is then heat-treated under conditions effective to cause a transimidation reaction between the prepolymer and the diamine to provide a solid polymer.

In a first aspect, a polyimide corn position has a glass transition temperature of less than 300° C. and includes a polyimide derived from a dianhydride, a fluorinated aromatic diamine and an aliphatic diamine. A polyimide film made from the polyimide composition has a b* of less than one for a film thickness of at least 30 microns.

A polyimide resin composition containing a polyimide resin (A) and a fluororesin (B), wherein the polyimide resin (A) contains a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), a content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) is 20 to 70 mol %, and the fluororesin (B) has a weight loss percentage measured using a differential scanning calorimeter after heating from 100° C. to 450° C. at a heating rate of 10° C./min in an air atmosphere of 1% or less:

##STR00001##

wherein R.sub.1 represents a divalent group having from 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; R.sub.2 represents a divalent chain aliphatic group having from 5 to 16 carbon atoms; and X.sub.1 and X.sub.2 each independently represent a tetravalent group having from 6 to 22 carbon atoms containing at least one aromatic ring; and a molded article thereof.

Examples of the present disclosure provide fluoropolymers and methods for forming and using such fluoropolymers. Fluoropolymers include polyfluorobenzoxazines and polyfluoroimides. Methods for forming polyphthalonitriles are also provided. The present disclosure is further directed to compositions containing one or more fluoropolymers and one or more metal oxides.

A dual-cure method for forming a solid polymeric structure is provided. An end-capped, imide-terminated prepolymer is combined with at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one olefinic monomer, thus forming a scaffold composed of the prepolymer and the polyolefin with the diamine trapped therein. The irradiated composition is then thermally treated at a temperature effective to cause a transimidization reaction to occur between the prepolymer and the diamine, thereby releasing the end caps of the prepolymer and providing the solid polymeric structure. A curable resin composition comprising an end-capped, imide-terminated prepolymer, at least one photopolymerizable olefinic monomer, at least one photoinitiator, and a diamine, is also provided, as are related methods of use.

A method for producing an aqueous polyimide precursor solution composition includes forming a polyamic acid by the reaction of a tetracarboxylic acid component and a diamine component in an aqueous solvent together with an imidazole in an amount of 1.6 mole or more per mole of the tetracarboxylic acid component of the polyamic acid.

An object of the present invention is to provide a polyimide binder which can be prepared under lower temperature conditions. The binder composition for a secondary battery of the present invention is characterized in comprising a polyamic acid and an aromatic compound comprising an electron donating group and an organic acid group.

A dual-cure method for forming a solid polymeric structure is provided. An end-capped, imide-terminated prepolymer is combined with at least one photopolymerisable olefinic monomer, at least one photoinitiator, and a diamine, to form a curable resin composition, which, in a first step, is irradiated under conditions effective to polymerize the at least one olefinic monomer, thus forming a scaffold composed of the prepolymer and the polyolefin with the diamine trapped therein. The irradiated composition is then thermally treated at a temperature effective to cause a transimidization reaction to occur between the prepolymer and the diamine, thereby releasing the end caps of the prepolymer and providing the solid polymeric structure. A curable resin composition comprising an end-capped, imide-terminated prepolymer, at least one photopolymerisable olefinic monomer, at least one photoinitiator, and a diamine, is also provided, as are related methods of use.

A polyimide resin composition includes a polyimide resin (A) including a repeating structural units of formulas (1) and (2). The content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural units of the formulas (1) and (2) is 20 to 70 mol %. The polyimide resin composition further includes a fatty acid metal salt (B) including a fatty acid having 12 to 36 carbon atoms and optionally having a hydroxy group and at least one of an alkali metal, an alkaline earth metal, and a transition metal:

##STR00001##

wherein R.sub.1 represents a divalent group having 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; R.sub.2 represents a divalent chain aliphatic group having 5 to 16 carbon atoms; and X.sub.1 and X.sub.2 each independently represent a tetravalent group having 6 to 22 carbon atoms containing at least one aromatic ring.