The continuous dehydration method for a raw material mixture to be used in the production of PAS includes supply and dehydration of the raw material mixture and extraction of the raw material mixture having a water content reduced by the dehydration, the supply, dehydration and extraction being carried out concurrently in parallel. A dehydration efficiency index determined according to Equation (1) is not less than 0.3. In Equation (1), the dehydration time is a period of time until a moisture content per mole of the sulfur source in the raw material mixture having a reduced water content reaches not greater than 1.7 mol, including moisture consumed by the hydrolysis of the organic polar solvent.

Dehydration efficiency index=[Number of moles (mol) of the sulfur source in the raw material mixture having a reduced water content]/[Dehydration time (hr)×(Total internal volume (L) of the dehydration tanks).sup.2/3]  (1)

Provided is a method for producing a polyarylene sulfide resin, the method including subjecting a dihaloaromatic compound and a sulfidizing agent to a polymerization reaction in the presence of an aliphatic cyclic compound having a ring openable by hydrolysis, in which corrosion of a production apparatus is suppressed. More particularly, provided is a method for producing a polyarylene sulfide resin, the method including a dehydration step (1) in which a water-containing sulfidizing agent and an aliphatic cyclic compound having a ring openable by hydrolysis are heated in the presence of a dihaloaromatic compound to a liquid temperature in the range of 90° C. or higher and 170° C. or lower under the atmospheric pressure, and then dehydration is performed while maintaining the liquid temperature and reducing the pressure to a pressure in the range of 30 [kPa abs] or higher and 80 [kPa abs] or lower to thus obtain a mixture.

Provided is a method for producing a polyarylene sulfide resin, the method including subjecting a dihaloaromatic compound and a sulfidizing agent to a polymerization reaction in the presence of an aliphatic cyclic compound having a ring openable by hydrolysis, in which corrosion of a production apparatus is suppressed. More particularly, provided is a method for producing a polyarylene sulfide resin, the method including a dehydration step (1) in which a water-containing sulfidizing agent and an aliphatic cyclic compound having a ring openable by hydrolysis are heated in the presence of a dihaloaromatic compound to a liquid temperature in the range of 90° C. or higher and 170° C. or lower under the atmospheric pressure, and then dehydration is performed while maintaining the liquid temperature and reducing the pressure to a pressure in the range of 30 [kPa abs] or higher and 80 [kPa abs] or lower to thus obtain a mixture.

The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by using a dihalogenated aromatic compound in a predetermined equivalent ratio with respect to a sulfur compound and performing both dehydration and polymerization under optimum conditions.

The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by using a dihalogenated aromatic compound in a predetermined equivalent ratio with respect to a sulfur compound and performing both dehydration and polymerization under optimum conditions.

The present disclosure relates to a polysulfide copolymer particle and a method of preparing the polysulfide copolymer particle.

The present disclosure relates to a polysulfide copolymer particle and a method of preparing the polysulfide copolymer particle.

The present invention relates to a method of preparing a polyphenylene sulfide and a high-viscosity polyphenylene sulfide prepared using the method. In this method, the ratio of an organic phase to an aqueous phase is controlled by controlling dehydration conditions, so that high viscosity may be realized without adversely affecting a reaction or physical properties during preparation of the polyphenylene sulfide.

The present disclosure relates to a method of more efficiently separating and purifying a polyarylene sulfide exhibiting excellent strength, heat resistance, flame retardancy, and processability when processed into a molded product after polymerization.

The present disclosure relates to a method of more efficiently separating and purifying a polyarylene sulfide exhibiting excellent strength, heat resistance, flame retardancy, and processability when processed into a molded product after polymerization.