In production of a polyarylene sulfide (PAS), combination/coalescence and enlargement of the PAS are prevented. A method for producing a PAS according to the present invention includes: first polymerization in which a mixture containing a sulfur source and a dihalo aromatic compound in an organic amide solvent is heated to initiate a polymerization reaction; second polymerization in which a first temperature (T.sub.1) is maintained after adding a phase separation agent to continue the reaction; third polymerization in which a second temperature (T.sub.2) is maintained to continue the reaction; and fourth polymerization in which the reaction is continued at a third temperature (T.sub.3), wherein a relationship among the temperatures is T.sub.1>T.sub.3>T.sub.2.

In production of a polyarylene sulfide (PAS), combination/coalescence and enlargement of the PAS are prevented. A method for producing a PAS according to the present invention includes: first polymerization in which a mixture containing a sulfur source and a dihalo aromatic compound in an organic amide solvent is heated to initiate a polymerization reaction; second polymerization in which a first temperature (T.sub.1) is maintained after adding a phase separation agent to continue the reaction; third polymerization in which a second temperature (T.sub.2) is maintained to continue the reaction; and fourth polymerization in which the reaction is continued at a third temperature (T.sub.3), wherein a relationship among the temperatures is T.sub.1>T.sub.3>T.sub.2.

The present invention provides a continuous polymerization apparatus capable of simply and efficiently separating a polymer and solid matter from a reaction mixture while having an apparatus configuration conducive to washing and maintenance, and a continuous production method for a polymer. A continuous polymerization apparatus (100) includes a plurality of reaction vessels (1a to 1c), wherein the plurality of reaction vessels are configured such that reaction mixtures (9a to 9c) successively move through each reaction vessel; in the plurality of reaction vessels, gas phase parts formed above the reaction mixture communicate with one another; and the continuous polymerization apparatus includes a washing part (5), the washing part configured to separate a solid included in the reaction mixture by sedimentation and to perform countercurrent washing.

The present invention provides a continuous polymerization apparatus capable of simply and efficiently separating a polymer and solid matter from a reaction mixture while having an apparatus configuration conducive to washing and maintenance, and a continuous production method for a polymer. A continuous polymerization apparatus (100) includes a plurality of reaction vessels (1a to 1c), wherein the plurality of reaction vessels are configured such that reaction mixtures (9a to 9c) successively move through each reaction vessel; in the plurality of reaction vessels, gas phase parts formed above the reaction mixture communicate with one another; and the continuous polymerization apparatus includes a washing part (5), the washing part configured to separate a solid included in the reaction mixture by sedimentation and to perform countercurrent washing.

A polyphenylene sulfide resin composition includes a blend of the following: 100 parts by weight of a polyphenylene sulfide resin (A); 100 to 250 parts by weight of a modified cross-section glass fiber (B); and 25 to 150 parts by weight of a non-fibrous inorganic filler (C) satisfying the following (C-a) and (C-b): (C-a) having a Mohs hardness of more than 2 and less than 4, and (C-b) having a melting point or softening point of 380° C. or more; wherein the ratio X/Y of the mass X of the modified cross-section glass fiber (B) to the mass Y of the non-fibrous inorganic filler (C) is more than 1 and less than 7.

A polyphenylene sulfide resin composition includes a blend of the following: 100 parts by weight of a polyphenylene sulfide resin (A); 100 to 250 parts by weight of a modified cross-section glass fiber (B); and 25 to 150 parts by weight of a non-fibrous inorganic filler (C) satisfying the following (C-a) and (C-b): (C-a) having a Mohs hardness of more than 2 and less than 4, and (C-b) having a melting point or softening point of 380° C. or more; wherein the ratio X/Y of the mass X of the modified cross-section glass fiber (B) to the mass Y of the non-fibrous inorganic filler (C) is more than 1 and less than 7.

Provided are a molded article that contains a polyarylene sulfide (PAS) resin and a glass fiber and allows a decrease in mechanical strength to be suppressed even in a hot water environment and under acidic conditions, a PAS resin composition capable of providing such a molded article, and methods for producing the same. More specifically, provided are a PAS resin composition including, per 100 parts by mass of a PAS resin, 10 to 100 parts by mass of a glass fiber having, in the glass fiber, a ZrO.sub.2 content of 16 mass % or more, a TiO.sub.2 content of 5 to 10 mass % or less, and a CaO content of 0.1 to 5 mass %, and 0.01 to 10 parts by mass of a silane coupling agent (C) blended as essential components; a molded article; and methods for producing the same.

A method for preparing polyarylene sulfide that can control a viscosity grade thereof by adjusting the molar ratio of water and amide-based compounds present in a polymerization reaction.

The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by using a dihalogenated aromatic compound in a predetermined equivalent ratio with respect to a sulfur compound and performing both dehydration and polymerization under optimum conditions.

The present disclosure relates to a preparation method of a polyarylene sulfide, and this method may produce a polyarylene sulfide having properties equal to or higher than those of the conventional method at a high yield by using a dihalogenated aromatic compound in a predetermined equivalent ratio with respect to a sulfur compound and performing both dehydration and polymerization under optimum conditions.