Patent classifications
C08G77/392
Modified polysiloxane and application thereof
A modified polysiloxane has formula (I) ##STR00001##
In formula (I) m is an integer between 0 and 10000; n is an integer between 0 and 10000; m and n cannot be equal to 0 simultaneously; R.sub.1-R.sub.7 are the same or different; and at least one of R.sub.1-R.sub.7 includes a group having a reversible chemical bond system based on a hydrogen bond, a coordinate bond, or a covalent bond. The polysioxane is used as a main chain to introduce a reversible chemical bond having temperature sensitivity by using a chemical method, so as to obtain a polymer material which is highly sensitive to temperature. The temperature-sensitive properties of materials provide functional materials for specific applications, such as medical external fixation materials, orthopedic materials, and packaging materials, can be obtained by using particular processing and preparation methods.
Composition for coating insulated wire comprising heat dissipation silicone elastomer compound having light shielding layer
The present invention relates to a coated insulated wire having improved heat dissipation properties, insulation properties, flame retardancy, and lightweight properties; and a method of manufacturing the same.
Composition for coating insulated wire comprising heat dissipation silicone elastomer compound having light shielding layer
The present invention relates to a coated insulated wire having improved heat dissipation properties, insulation properties, flame retardancy, and lightweight properties; and a method of manufacturing the same.
Q-T-SILOXANE-BASED POLYMERIC MATERIALS WITH HIGH SILOXANE RING CONTENT AND METHOD FOR PREPARING SAME
The present invention pertains to a branched polymeric liquid poly siloxane material comprising non-organofunctional Q-type siloxane moieties and mono-organofunctional T-type siloxane moieties, as well as optionally tri-organofunctional M-type siloxane moieties and/or di-organofunctional D-type siloxane moieties characterized in that the polysiloxane material has a specified degree of polymerization, comprises a significant amount of four-membered Q2-type and/or Q3-type siloxane ring species relative to the total Q-type siloxane species, and is optionally functionalized at specific moieties. The present invention further pertains to methods for producing the polymeric liquid polysiloxane material as well as associated uses of the material.
PHOTOCURABLE SILICONE COMPOSITION AND CURED PRODUCT THEREOF
A UV-curable silicone composition is disclosed. The UV-curable silicone composition comprises: (A) an organopolysiloxane having at least two alkenyl groups and at least one aryl group in a molecule; (B) a polysiloxane block copolymer comprising: (i) a polysiloxane block and (ii) an organo block, wherein the polysiloxane block (i) is bonded to the organo block (ii) via a specific linkage, and wherein the polysiloxane block copolymer has at least two thiol groups in a molecule; (C) a photoinitiator; and (D) an inorganic filler. The composition exhibits excellent transparency even if an inorganic filler is added to improve thixotropic property.
Bio-electrode composition, bio-electrode, and method for manufacturing a bio-electrode
The present invention provides a bio-electrode composition including a silicone bonded to a sulfonamide salt, wherein the sulfonamide salt is shown by the following general formula (1): ##STR00001##
wherein R.sup.1 represents a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms optionally having an aromatic group, an ether group, or an ester group, or an arylene group having 6 to 10 carbon atoms; Rf represents a linear, branched, or cyclic alkyl group having 1 to 4 carbon atoms and containing at least one fluorine atom; M.sup.+ is an ion selected from a lithium ion, a sodium ion, a potassium ion, and a silver ion. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.
Bio-electrode composition, bio-electrode, and method for manufacturing a bio-electrode
The present invention provides a bio-electrode composition including a silicone bonded to a sulfonamide salt, wherein the sulfonamide salt is shown by the following general formula (1): ##STR00001##
wherein R.sup.1 represents a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms optionally having an aromatic group, an ether group, or an ester group, or an arylene group having 6 to 10 carbon atoms; Rf represents a linear, branched, or cyclic alkyl group having 1 to 4 carbon atoms and containing at least one fluorine atom; M.sup.+ is an ion selected from a lithium ion, a sodium ion, a potassium ion, and a silver ion. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.
Transparent rollable folded polysiloxane film and preparation and self-repairing method thereof
This invention provides a scrollable and foldable transparent polysiloxane film and its preparation and self-healing method. 2-Hydroxyethyl disulfide, diisocyanate and alkane chloride were mixed and reacted to get disulfide-containing diisocyanate. α,ω-Aminopropyl terminated polydimethylsiloxane, diisocyanate and alkane chloride were mixed and reacted get linear chain-extended polydimethylsiloxane. Linear chain-extended polydimethylsiloxane, multi-amino terminated hyperbranched polysiloxane, disulfide-containing diisocyanate and alkane chloride were mixed and poured into a mould. After drying, the scrollable and foldable transparent polysiloxane film was obtained. The polysiloxane film described in this invention are constructed by dynamic physical crosslinking induced by hydrogen bond and permanent chemical crosslinking generated by hyperbranched polysiloxane. Hence, the polysiloxane film achieves both high stiffness and toughness. The good self-healing behavior of the polysiloxane films is originated from the temperature controlled dissociation of hydrogen bonds and exchange reaction rate of disulfide bonds.
Silicone polymer
Provided is a polymer of the formula: ##STR00001##
and compositions comprising the same. The polymers comprise a cyclic unsaturated group (Z.sup.3) within the siloxane polymer backbone. The polymers have been found to exhibit good thermal conductivity and may find utility in a variety of applications.
Silicone polymer
Provided is a polymer of the formula: ##STR00001##
and compositions comprising the same. The polymers comprise a cyclic unsaturated group (Z.sup.3) within the siloxane polymer backbone. The polymers have been found to exhibit good thermal conductivity and may find utility in a variety of applications.