Patent classifications
C08J3/096
Ionic liquid and method for dissolving cellulose using the same
The present invention provides an ionic liquid represented by the following chemical formula (I):
[(CH.sub.3).sub.3N(CH.sub.2).sub.2OH].sup.+[NH.sub.2-L-COO].sup.(I) where L is (CH.sub.2).sub.2 or (CH.sub.2).sub.3. The present invention also provides an ionic liquid composition containing an ionic liquid; and water. The ionic liquid is represented by the above chemical formula (I). A molar ratio of [(CH.sub.3).sub.3N(CH.sub.2).sub.2OH].sup.+ to [NH.sub.2-L-COO].sup. is not less than 0.86 and not more than 1.12. A weight ratio of the water to the ionic liquid composition is not more than 4.7%. The present invention provides an ionic liquid capable of dissolving cellulose without an cellulose-degrading enzyme (namely, an enzyme capable of hydrolyzing cellulose).
Ionic liquid composition and method for dissolving cellulose using the same
The present invention provides an ionic liquid composition containing an ionic liquid and water. The ionic liquid composition does not contain an enzyme capable of hydrolyzing cellulose. The ionic liquid is represented by the following chemical formula (I): [(CH.sub.3).sub.3N(CH.sub.2).sub.2OH].sup.+[NH.sub.2-L-CHNH.sub.2COO].sup. (I); where L is absent or a linker. A molar ratio of [(CH.sub.3).sub.3N(CH.sub.2).sub.2OH].sup.+ to [NH.sub.2-L-CHNH.sub.2COO].sup. is not less than 0.87 and not more than 1.14. A weight ratio of the water to the ionic liquid composition is not more than 7.3%. The present invention provides an ionic liquid composition capable of dissolving cellulose without a cellulose-degrading enzyme, namely, an enzyme capable of hydrolyzing cellulose.
Method of forming a composition and the composition formed therefrom
In an aspect, a method of making a composition, comprising forming a solvent mixture comprising a polymer and a solvent; precipitating the solvent mixture with a non-solvent to form the composition comprising the filler in a fibrillated polymer matrix, wherein the composition is in the form of a particulate and at least one of the solvent and the non-solvent comprises a filler; and separating the composition from the solvent and the non-solvent to isolate the composition. In another aspect, a porous material wherein the filler particles are mechanically bonded together by the polymer and wherein the polymer is present as filaments adhering to and connecting the filler particles across interstitial spaces between the filler particles. In another aspect, a precipitated polymer solution produced by a phase inversion where the majority of the liquids can be mechanically removed.
RESIN COMPOSITION FOR MANUFACTURING SEPARATOR, PREPARATION METHOD THEREFOR, AND BATTERY COMPRISING SAME
A resin composition for fabricating a separator which is easy to control viscosity, a method of preparing the same, and a battery including the same, are disclosed.
IONIC LIQUID AND METHOD FOR DISSOLVING CELLULOSE USING THE SAME
The present invention provides an ionic liquid represented by the following chemical formula (I):
[(CH.sub.3).sub.3N(CH.sub.2).sub.2(OH].sup.+[NH.sub.2LCOO].sup.
where L is (CH.sub.2).sub.2 or (CH.sub.2).sub.3. (I)
The present invention also provides an ionic liquid composition containing an ionic liquid; and water. The ionic liquid is represented by the above chemical formula (I). A molar ratio of [(CH.sub.3).sub.3N(CH.sub.2).sub.2OH].sup.+ to [NH.sub.2LCOO].sup. is not less than 0.86 and not more than 1.12. A weight ratio of the water to the ionic liquid composition is not more than 4.7%. The present invention provides an ionic liquid capable of dissolving cellulose without an cellulose-degrading enzyme (namely, an enzyme capable of hydrolyzing cellulose).
Membrane Manufacturing With A Cosolvent In The Polymer Dope Solution
The invention relates to a process for making a membrane M comprising the following steps: providing a dope solution D comprising a polymer P selected from polyphenylenesulfone or mixtures of polyphenylenesulfone with nonionic polyarylene ethers, a first solvent selected from aprotic polar solvents, and a cosolvent selected from C.sub.2-C.sub.8 alkanediol, C.sub.3-C.sub.8 alkanetriol, polyethylene glycol, or mixtures thereof; and preparing the membrane by bringing the dope solution D into contact with a coagulating agent. The invention further relates to a membrane M obtainable in said process.
Process for preparing cellulose solution and equipment therefor
The present invention provides a process for preparing a cellulose solution. NMMO with a relatively low concentration and non-activated pulp are continuously mixed online, the mixed premix is dewatered in evaporation dewatering equipment until an NMMO concentration suitable for swelling is achieved, then, sufficient swelling is carried out under this condition, and the uniformly-mixed and sufficiently swelled pre-swelling solution is subjected to depressurized evaporation dewatering and dissolving by thin-film-evaporation equipment thereby obtaining a high-concentration, uniformly-dissolved and excellently-uniformity cellulose solution. The present invention further provides continuous preparation equipment for the process for preparing a cellulose solution. According to the present invention, the conflict between uniform mixing and sufficient swelling during the preparation of a high-concentration cellulose solution is solved, and problems in storage and transportation safety caused by using high concentration NMMO in the conventional technologies are prevented.
Supercritical CO2 cellulose spraydrying
The present invention provides for a process for producing dry, water-dispersible, non-surface modified nanocellulose particles or a powderous composition r comprising said particles comprising the steps of: i. providing a first suspension of non-surface modified cellulose particles in an first aqueous liquid, which aqueous liquid is non-solubilizing for the non-surface modified nanocellulose particles, ii. exchanging substantially all of the first aqueous liquid of the first suspension for a second solvent, which is miscible with the first aqueous liquid and non-solubilizing for the non-surface modified nanocellulose particles, to form a second suspension of non-surface modified nanocellulose particles in said second solvent, iii. contacting a flow of the second suspension of non-surface modified nanocellulose particles with a flow of a fluid in a supercritical or critical state, which fluid in a supercritical or critical state is miscible with the second solvent and non-solvating for the non-surface modified nanocellulose particles under conditions suitable for the transfer of substantially all of the second solvent into the supercritical fluid, iv. removing the second solvent and the fluid in a supercritical or critical state, preferably by controlling pressure and/or temperature, to form the dry, water-dispersible nanocellulose particles, v. collecting the dry, water-dispersible, non-surface modified nanocellulose particles and/or forming the powderous composition comprising said particles.
Fabrication of Green Polymeric Membranes
Provided herein are methods of fabricating membranes using polymers with functionalized groups such as sulfone (e.g., PSf and PES), ether (e.g., PES), acrylonitrile (e.g., PAN), fluoride(e.g., pvdf and other fluoropolymers), and imide (e.g., extem) and ionic liquids. Also provided are membranes made by the provided methods.
Dissolution of oxidized cellulose
A process for dissolving modified cellulose is disclosed. The process includes contacting modified cellulose with a solvent in a mixture to form swelled modified cellulose and then contacting the mixture with a salt to dissolve the swelled modified cellulose.