This invention relates to the use blends comprising HFO-1336mzz-Z, methyl formate, and optionally, HFC-152a as blowing agents for thermoplastic polymers (e.g., polystyrene).

The present disclosure relates to improving insulation properties of foams by employing an azeotropically-modified blowing agent that preserves or improves R-value at various temperatures such as lower than ambient temperatures (below 24° C.). The present disclosure also provides foams with improved long-term thermal resistance (LTTR).

Tertiary amine catalysts having isocyanate reactive groups that are capable of forming thermally stable covalent bonds able to withstand temperatures up to 120° C. are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g., indexes as low as 65 but higher than 60) while meeting all physical property requirements; b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25° C. to 90° C.); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.

The present invention relates to blowing agent compositions comprising at least one hydrofluoroolefin (HFO) selected from cis- and/or trans-1,3,3,3-tetrafluoropropene (HFO-1234ze) and at least one hydrochlorofluoroolefin (HCFO) selected from cis- and/or trans-1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) used in the preparation of foamable thermoplastic compositions. The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.

The invention refers to a method for producing expanded polymer pellets, which comprises the following steps: melting a polymer comprising a polyamide; adding at least one blowing agent; expanding the melt through at least one die for producing an expanded polymer; and pelletizing the expanded polymer. The invention further concerns polymer pellets produced with the method as well as their use, e.g. for the production of cushioning elements for sports apparel, such as for producing soles or parts of soles of sports shoes. A further aspect of the invention concerns a method for the manufacture of molded components, comprising loading pellets of an expanded to polymer material into a mold, and connecting the pellets by providing heat energy, wherein the expanded polymer material of the pellets or beads comprises a chain extender. The molded components may be used in broad ranges of application.

The present disclosure relates to unsaturated polyolefins and processes for preparing the same. The present disclosure further relates to curable formulations comprising the unsaturated polyolefins that show improved crosslinking.

Disclosed are such co-polymers of vinylidene substituted aromatic monomers and unsaturated compounds containing nucleophilic groups chain extended by a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds having pendant electrophilic groups which copolymerize with the one or more vinylidene aromatic monomers. Disclosed are compositions comprising vinylidene substituted aromatic monomers and unsaturated compounds containing nucleophilic groups and a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds having pendant electrophilic groups, which may optionally, contain salts of alkaline earth metals, alkali metals, transition metals, post transition metals or metalloids. Disclosed are methods of preparing such chain-extended and/or branched copolymers.

A structure for protecting a substrate. The structure comprises an inner tie coat layer which can bond to the substrate, a geopolymer foam layer, and an outer protective layer. The geopolymer foam layer is the reaction product of a mixture comprising an aluminosilicate source, an alkali activator, reinforcing fibres, and a plurality of microparticles.

Various uses of monochlorotrifluoropropenes, in combination with one or more other components, including other fluoroalkenes, hydrocarbons; hydrofluorocarbons (HFCs), ethers, alcohols, aldehydes, ketones, methyl formate, formic acid, water, trans-1,2-dichloroethylene, carbon dioxide and combinations of any two or more of these, in a variety of applications, including as blowing agents, are disclosed.

The present invention provides a two-component foamable silicone composition comprising: a component A comprising (a) at least one polyorganosiloxane having at least one vinyl group, (b) at least one chemical blowing agent, and (c) at least one catalyst; and a component B comprising (d) at least one polyorganosiloxane having at least one vinyl group, and (e) at least one polyorganosiloxane having at least one —SiH group, and at least one expandable graphite in an amount of less than 10% by weight, based on the total weight of the component B, which exhibits excellent flame retardancy, good sealing performance, high compression rate, low gasket density, good dispensing continuity and good cell structure. The present invention also provides a preparing method and use thereof.