Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF═CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

The present invention relates to a process for the manufacture of foamed polymeric material characterised by the presence of two or more cellular layers and aggregates that exhibit variations in cell size and cell density distribution. The heterogeneous polymeric material is foamed using a single expansion step, thus eliminating the assembly steps and improving the mechanical proprieties of the foam. The invention allows producing custom foam with predefined profiles of cell size, cell density distribution, and with correlated variations of its physical properties. The key to this invention is that the polymer material before expansion is made in multiple polymerisation steps from the original monomers. In each polymerisation step, a different recipe of monomers and physical blowing agents' concentration is used. These recipes within the final polymer material will expand under the same temperature to produce various aggregates of cell sizes and cell distribution in the final foam.

A resin composition to be cross-linked and foamed includes thermoplastic resin, a cross-linking agent, and a foaming agent, further including: ethylene propylene diene monomer rubber having an ethylene content lower than 70 mass %. The ethylene propylene diene monomer rubber amounts for 5 mass % or more of a sum of the thermoplastic resin and the ethylene propylene diene monomer rubber.

A heat transfer composition includes: (i) trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)); (ii) a second component selected from difluoromethane (R-32), propene (R-1270), propane (R290) and mixtures thereof; (iii) a third component selected from pentafluoroethane (R-125), 1,1,1,2-tetrafluoroethane (R-34a), and mixtures thereof; and optionally (iv) a fourth component selected from fluoroethane (R-161), 1,1-difluoroethane (R-152a) and mixtures thereof.

A composition for preparing polyisocyanurate and polyurethane foams is provided, comprising A) a first isocyanate-reactive component comprising a bisphenol, B) a second isocyanate-reactive component different from the first isocyanate-reactive component, and C) a polyisocyanate component. A method for preparing the polyisocyanurate and polyurethane foams, and foams prepared thereby are also provided.

Disclosed are such co-polymers of vinylidene substituted aromatic monomers and unsaturated compounds containing nucleophilic groups chain extended by a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds having pendant electrophilic groups which copolymerize with the one or more vinylidene aromatic monomers. Disclosed are compositions comprising vinylidene substituted aromatic monomers and unsaturated compounds containing nucleophilic groups and a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds having pendant electrophilic groups, which may optionally, contain salts of alkaline earth metals, alkali metals, transition metals, post transition metals or metalloids. Disclosed are methods of preparing such chain-extended and/or branched copolymers.

A foaming composition useful to make an extruded foam is comprised of: a copolymer of a vinylidene aromatic monomer and an unsaturated compound containing nucleophilic groups, a copolymer of vinylidene aromatic monomer and an unsaturated compound having electrophilic groups; and a blowing agent. The foaming composition may be made into a foam by heating the foaming composition to a temperature sufficient to melt and react said copolymers to form a chain extended/branched copolymer and extruding the foaming composition from a higher pressure to a lower pressure to form an extruded foam comprised of the chain extended/branched copolymer. The foam is comprised of a chain extended/branched copolymer that is the reaction product of (i) a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds containing nucleophilic groups, and (ii) a copolymer of one or more vinylidene aromatic monomers and one or more unsaturated compounds having electrophilic groups.

A process for producing a polyurethane or polyisocyanurate construction board, the process comprising: (i) providing an A-side reactant stream that includes an isocyanate-containing compound; (ii) providing a B-side reactant stream that includes a polyol, where the B-side reactant stream includes a blowing agent that includes a pentane and a blowing agent additive that has a Hansen Solubility Parameter (8t) that is greater than 17 MPa°′.sup.5; and (iii) mixing the A-side reactant stream with the B-side reactant stream to produce a reaction mixture.

The present disclosure provides minimum-boiling, homogeneous azeotropic and azeotrope-like compositions of 1,2,2-trifluoro-1-trifluoromethylcyclobutane (“TFMCB”) with each of ethanol, n-pentane, cyclopentane, trans-1,2-dichloroethylene, and perfluoro(2-methyl-3-pentanone).

A mixed liquid agent of the present invention comprises a polyol compound, a catalyst, a flame retardant, and an organic solvent. The flame retardant includes a solid flame retardant. The organic solvent has a vapor pressure at 20° C. of 0.1 MPaG or more. A viscosity at 1 rpm and 25° C. after the organic solvent has been volatilized is 4,000 mPa.Math.s or more and less than 250,000 mPa.Math.s.