The present invention relates to a highly fluorinated nanostructured polymer foam as well as to its use as a super-repellent coating of substrates. Furthermore, the present invention relates to a composition and to a method for producing the highly fluorinated nanostructured polymer foam.

Porous polymer composites and methods of preparing porous polymer composites are provided herein. In some embodiments, a method for preparing porous polymer composites may include mixing a first polymer with a solvent and a particulate filler to form a first polymer composition, wherein the amount of particulate filler in the first polymer composition is below a mechanical percolation threshold; and removing the solvent from the first polymer composition to concentrate the first polymer and particulate filler into a second polymer composition having a porous structure, wherein the particulate filler concentration in the second polymer composition is increased above the mechanical percolation threshold during solvent removal.

The invention discloses a separator with a wide temperature range and a low heat shrinkage and a method for preparing the same. The invention belongs to the field of electrochemistry. The separator of the invention includes: an irradiation crosslinked fluoropolymer A with a melting point above 150 C. and/or a polymer B containing a benzene ring in its main chain; an ultrahigh molecular weight polyethylene having a molecular weight of 1.010.sup.6-10.010.sup.6, and a high density polyethylene having a density in the range of 0.940-0.976 g/cm.sup.3; the temperature difference between pore closing temperature and film breaking temperature of the separator is 80-90 C., preferably 85-90 C., the heat shrinkage of the separator is 2.0% or less. The separator of the invention has a high temperature difference between film breaking temperature and pore closing temperature, and a low heat shrinkage; when the separator of the invention is used in an electrochemical device, the reliability and safety of electrochemical device can be effectively improved.

Polyimide-network battery-separator compositions are disclosed. The polyimide-network battery-separator compositions comprise a porous cross-linked polyimide network comprising a polyamic acid oligomer. The polyamic acid oligomer (i) comprises a repeating unit of a dianhydride and a diamine and terminal functional groups, (ii) has an average degree of polymerization of 10 to 70, (iii) has been cross-linked via a cross-linking agent, comprising three or more cross-linking groups, at a balanced stoichiometry of the cross-linking groups to the terminal functional groups, and (iv) has been chemically imidized to yield the porous cross-linked polyimide network. The polyimide-network battery-separator compositions also comprise an electrolyte composition comprising (i) a room temperature ionic liquid and (ii) a lithium ion. The electrolyte composition is interfused within the porous cross-linked polyimide network. Polyim ide-urea-network battery-separator compositions also are disclosed. Voltaic cells comprising a cathode, an anode, and the polyimide-network battery separator composition or the polyimide-urea-network battery separator composition are also disclosed.

A battery separator includes a polyolefin microporous membrane having a width of 100 mm or more, and a porous layer laminated on at least one surface of the polyolefin microporous membrane. The polyolefin microporous membrane has a variation range of an F25 value in a width direction of 1 MPa or less, and the F25 value indicates a value obtained by dividing a load value measured at 25% elongation of a specimen with use of a tensile tester by a cross-sectional area of the specimen. The porous layer contains a fluorine-based resin and an inorganic particle.

Composite materials including cellulose nanocrystals incorporated into a polymer aerogel scaffold, wherein the cellulose nanocrystals serve as a reinforcement agent to result in the formation of less dense aerogels, improve the tensile mechanical properties of aerogel films, and reduce aerogel shrinkage upon thermal exposure. After gelation, the gel is dried via a suitable method such as supercritical CO.sub.2 extraction, freeze drying or other method, to produce the CNC/polymer composite aerogel. Properties of the composite aerogel can be tailored via surface modification of the cellulose nanocrystals as well as through the backbone structure of the polymer.

The present invention discloses novel porous polymeric compositions comprising random copolymers of amides, imides, ureas, and carbamic-anhydrides, useful for the synthesis of monolithic bimodal microporous/macroporous carbon aerogels. It also discloses methods for producing said microporous/macroporous carbon aerogels by the reaction of a polyisocyanate compound and a polycarboxylic acid compound, followed by pyrolytic carbonization, and by reactive etching with CO.sub.2 at elevated temperatures. Also disclosed are methods for using the microporous/macroporous carbon aerogels in the selective capture and sequestration of carbon dioxide.

The present application provides a separator and a preparation method thereof, an electrochemical device, an electrochemical apparatus and a powered device. The separator comprises a base film, the base film has a tensile energy per unit thickness of ?1.8 J/10 ?m in both MD direction and TD direction, and an elongation of ?150% in both MD direction and TD direction, and the thickness of the base film is 2 ?m?40 ?m.

Method for preparing porous polyurethane materials with controlled pore size and shape using isocyanates, polyols, and additives, and the porous polyurethane materials prepared therefrom. Method for preparing porous polyimides using at least one polyamine and a dianhydride and the porous polyimides materials prepared therefrom. The porous materials are useful for energy management, such as thermal, impact and vibration energy, and can exhibit improved fire-resistant performance.

The present invention provides porous particles made of an organic polymer, uniform in shape, and having through holes that are not closed. The porous particles according to the present invention are porous particles having a substantially spherical shape. The porous particles are made of an organic polymer. Each of the porous particles has an interconnected pore structure in which through holes provided inside the porous particle communicate with each other, and ends of the through holes are open toward an outside of the porous particle.