A variety of plates for footwear are provided including a polyolefin resin. Sole structures and articles of footwear formed therefrom are also provided. Methods of making the polyolefin resin compositions, plates, sole structures, and articles of footwear are also provided. In some aspects, the polyolefin resin composition includes an effective amount of a polymeric resin modifier. The effective amount can be an amount effective to allow the resin composition to pass a flex test, and in particular to pass a flex test without significant change in abrasion loss. In some aspects, the resin composition also includes a clarifying agent to improve optical clarity of the plate. In some aspects, the plates include a textile disposed on one or both of a first side and the second side of the plate. The textile can provide for improved bonding of the plate to other components such as a chassis or an upper.

The present disclosure provides polypropylene compositions that have a high gloss and minimum or no haze while also having a high melt strength (e.g., high temperature resistance) and a relative high stiffness. Polypropylene compositions contain one or more base polypropylenes (e.g., trimmed polypropylenes (tPPs)) and one or more clarifying agents. The base or trimmed polypropylene contains at least 50 mol % of propylene and has a molecular weight distribution (Mw/Mn) in a range from 7 to 22, a z-average molecular weight of less than 2,500,000 g/mol, a branching index (g′.sub.vis) of at least 0.95, and a melt strength of less than 20 cN determined using an extensional rheometer at 190° C. The base or trimmed polypropylene can be produced from one or more high melt strength polypropylenes (HMS PPs).

The present disclosure provides polypropylene compositions that have a high gloss and minimum or no haze while also having a high melt strength (e.g., high temperature resistance) and a relative high stiffness. Polypropylene compositions contain one or more base polypropylenes (e.g., trimmed polypropylenes (tPPs)) and one or more clarifying agents. The base or trimmed polypropylene contains at least 50 mol % of propylene and has a molecular weight distribution (Mw/Mn) in a range from 7 to 22, a z-average molecular weight of less than 2,500,000 g/mol, a branching index (g′.sub.vis) of at least 0.95, and a melt strength of less than 20 cN determined using an extensional rheometer at 190° C. The base or trimmed polypropylene can be produced from one or more high melt strength polypropylenes (HMS PPs).

A latent additive which is represented by general formula (1). (In the formula, A represents a five-membered or six-membered aromatic ring or heterocyclic ring; each of R.sup.1 and R.sup.2 independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an optionally substituted alkyl group having 1-40 carbon atoms, an aryl group having 6-20 carbon atoms, an arylalkyl group having 7-20 carbon atoms or a heterocyclic ring-containing group having 2-20 carbon atoms; and R.sup.4 represents an alkyl group having 1-20 carbon atoms, an alkenyl group having 2-20 carbon atoms, an aryl group having 6-20 carbon atoms, an arylalkyl group having 7-20 carbon atoms, a heterocyclic ring-containing group having 2-20 carbon atoms or a trialkylsilyl group.)

A latent additive which is represented by general formula (1). (In the formula, A represents a five-membered or six-membered aromatic ring or heterocyclic ring; each of R.sup.1 and R.sup.2 independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an optionally substituted alkyl group having 1-40 carbon atoms, an aryl group having 6-20 carbon atoms, an arylalkyl group having 7-20 carbon atoms or a heterocyclic ring-containing group having 2-20 carbon atoms; and R.sup.4 represents an alkyl group having 1-20 carbon atoms, an alkenyl group having 2-20 carbon atoms, an aryl group having 6-20 carbon atoms, an arylalkyl group having 7-20 carbon atoms, a heterocyclic ring-containing group having 2-20 carbon atoms or a trialkylsilyl group.)

The present invention relates to an additive composition and a low haze polyolefin material which may be prepared using said additive composition. In particular, the polyolefin material is prepared from a polyolefin resin composition comprising bis-3,4-dimethylbenzylidene sorbitol and bis-p-ethylbenzylidene sorbitol at a certain weight ratio. In an aspect, the present invention relates to a method for forming a polyolefin material; said method comprising: (i) preparing a polyolefin resin composition comprising polyolefin resin and bis-3,4-dimethylbenzylidene sorbitol and bis-p-ethylbenzylidene sorbitol, wherein the weight ratio of bis-3,4-dimethylbenzylidene sorbitol to bis-p-ethylbenzylidene sorbitol in the polyolefin resin composition is 45:55 to 25:75; (ii) processing said polyolefin resin composition to form said polyolefin material.

The present invention relates to an additive composition and a low haze polyolefin material which may be prepared using said additive composition. In particular, the polyolefin material is prepared from a polyolefin resin composition comprising bis-3,4-dimethylbenzylidene sorbitol and bis-p-ethylbenzylidene sorbitol at a certain weight ratio. In an aspect, the present invention relates to a method for forming a polyolefin material; said method comprising: (i) preparing a polyolefin resin composition comprising polyolefin resin and bis-3,4-dimethylbenzylidene sorbitol and bis-p-ethylbenzylidene sorbitol, wherein the weight ratio of bis-3,4-dimethylbenzylidene sorbitol to bis-p-ethylbenzylidene sorbitol in the polyolefin resin composition is 45:55 to 25:75; (ii) processing said polyolefin resin composition to form said polyolefin material.

The present invention relates to an additive composition and a low haze polyolefin material which may be prepared using said additive composition. In particular, the polyolefin material is prepared from a polyolefin resin composition comprising bis-3,4-dimethylbenzylidene sorbitol and bis-p-ethylbenzylidene sorbitol at a certain weight ratio. In an aspect, the present invention relates to a method for forming a polyolefin material; said method comprising: (i) preparing a polyolefin resin composition comprising polyolefin resin and bis-3,4-dimethylbenzylidene sorbitol and bis-p-ethylbenzylidene sorbitol, wherein the weight ratio of bis-3,4-dimethylbenzylidene sorbitol to bis-p-ethylbenzylidene sorbitol in the polyolefin resin composition is 45:55 to 25:75; (ii) processing said polyolefin resin composition to form said polyolefin material.

A BOPP multilayer film having at least three layers made from or containing a nucleated propylene polymer composition having: A) from 77 wt % to 91 wt %, of a propylene homopolymer having a fraction insoluble in xylene at 25° C. higher than 95%; B) from 9 wt % to 23 wt %, of a copolymer of propylene with from 28.0 wt % to 42.0 wt % of ethylene derived units; and C) a nucleating agent selected from aromatic or aliphatic carboxylic acids, aromatic metal phosphates, sorbitol derivatives and talc, wherein the composition has an intrinsic viscosity (IV) of the fraction soluble in xylene at 25° C. between 1.0 dl/g and 1.9 dl/g, a fraction soluble (Xs) in xylene at 25° C. between 9.0 wt % and 21.0 wt %, a total melt flow rate (MFR) between 1.5 and 5 g/10 min and the value of the relation (I):

22.5+0.2*MFR−1.2*Xs+0.2*IV  (I) higher than 5.9.

A BOPP multilayer film having at least three layers made from or containing a nucleated propylene polymer composition having: A) from 77 wt % to 91 wt %, of a propylene homopolymer having a fraction insoluble in xylene at 25° C. higher than 95%; B) from 9 wt % to 23 wt %, of a copolymer of propylene with from 28.0 wt % to 42.0 wt % of ethylene derived units; and C) a nucleating agent selected from aromatic or aliphatic carboxylic acids, aromatic metal phosphates, sorbitol derivatives and talc, wherein the composition has an intrinsic viscosity (IV) of the fraction soluble in xylene at 25° C. between 1.0 dl/g and 1.9 dl/g, a fraction soluble (Xs) in xylene at 25° C. between 9.0 wt % and 21.0 wt %, a total melt flow rate (MFR) between 1.5 and 5 g/10 min and the value of the relation (I):

22.5+0.2*MFR−1.2*Xs+0.2*IV  (I) higher than 5.9.