Electrically conductive thermoplastic polymer composites of particulate thermoplastic polyester polymers, electrically conductive components (carbon nanofibers, graphene nanoplatelets, and/or conductive metal nanoparticulates), processing aids such as plasticizers, thermal stabilizers, etc., as well as nanoscopic particulate fillers such as nanoscopic titanium dioxide, etc., the electrically conductive components being distributed substantially uniformly in the composite to form an electrically conductive network. Also, methods for preparing thermoplastic polymer composites, a system for collecting extruded filaments prepared from thermoplastic polymer composites as a coil of filament, as well as method for tempering articles formed from thermoplastic polymer composites to increase the degree of crystallinity of the thermoplastic polymers and thus their mechanical strength properties.

Electrically conductive thermoplastic polymer composites of particulate thermoplastic polyester polymers, electrically conductive components (carbon nanofibers, graphene nanoplatelets, and/or conductive metal nanoparticulates), processing aids such as plasticizers, thermal stabilizers, etc., as well as nanoscopic particulate fillers such as nanoscopic titanium dioxide, etc., the electrically conductive components being distributed substantially uniformly in the composite to form an electrically conductive network. Also, methods for preparing thermoplastic polymer composites, a system for collecting extruded filaments prepared from thermoplastic polymer composites as a coil of filament, as well as method for tempering articles formed from thermoplastic polymer composites to increase the degree of crystallinity of the thermoplastic polymers and thus their mechanical strength properties.

In various aspects, the disclosure relates to polycarbonate compositions exhibiting improved impact strength, both multi axial and notched Izod, as well as thin-walled flame resistance while free or substantially free of bromine or chlorine flame retardant additives. The polycarbonate compositions may comprise non-bonding glass fiber, butyl tosylate, and/or a phosphorous based stabilizer.

In various aspects, the disclosure relates to polycarbonate compositions exhibiting improved impact strength, both multi axial and notched Izod, as well as thin-walled flame resistance while free or substantially free of bromine or chlorine flame retardant additives. The polycarbonate compositions may comprise non-bonding glass fiber, butyl tosylate, and/or a phosphorous based stabilizer.

The invention provides a stabilising composition for a polyol and/or a polyurethane, comprising: a) a first derivatised phenolic antioxidant having a molecular weight of at least about 400 g/mol and a melting point of less than about 100° C.; b) a second derivatised phenolic antioxidant having lower steric hindrance than the first derivatised phenolic antioxidant, which is a solid at ambient conditions; and c) a secondary antioxidant comprising a phosphite and/or a thioester,
and also disclosed is a fire retardant blend comprising the stabilising composition and a fire retardant.

The invention provides a stabilising composition for a polyol and/or a polyurethane, comprising: a) a first derivatised phenolic antioxidant having a molecular weight of at least about 400 g/mol and a melting point of less than about 100° C.; b) a second derivatised phenolic antioxidant having lower steric hindrance than the first derivatised phenolic antioxidant, which is a solid at ambient conditions; and c) a secondary antioxidant comprising a phosphite and/or a thioester,
and also disclosed is a fire retardant blend comprising the stabilising composition and a fire retardant.

A flame retardant composition includes poly(carbonate-bisphenol phthalate ester) or a combination of poly(carbonate-bisphenol phthalate ester) and a poly(ester), an organophosphorous flame retardant present in an amount effective to provide 0.5-0.8 wt % of added phosphorous; 5-45 wt % of glass fibers; optionally, a poly(carbonate-siloxane); optionally, 0.01-10 wt % of a flame retardant sulfonate salt; optionally, 0.1-0.6 wt % of an anti-drip agent; and optionally, 0.01-10 wt % an additive composition, wherein the amount of the polymer component, the organophosphorous flame retardant, the glass fibers, and the optional components total 100 wt %; and wherein a molded sample of the flame retardant composition has a UL 94 rating of V0 at a thickness of 1.2 millimeter, preferably a CA UL 94 rating of V0 at a thickness 0.8 millimeter.

Provided is a polycarbonate-based resin composition including: a polycarbonate-polyorganosiloxane copolymer (A); and at least one kind of compound (B) selected from the group consisting of an antioxidant, a dye, a release agent, a light-diffusing agent, a flame retardant, a UV absorber, a silicone-based compound, an epoxy compound, and a polyether compound, wherein the polycarbonate-polyorganosiloxane copolymer (A) contains a polycarbonate block (A-1) and a polyorganosiloxane block (A-2), and satisfies the following requirements (1) to (3): (1) the content of the polyorganosiloxane block (A-2) is from more than 40 mass % to 70 mass % or less; (2) the copolymer has a viscosity-average molecular weight of from 10,000 to 23,000; and (3) the copolymer contains a specific polycarbonate block as the polycarbonate block (A-1).

Provided is a polycarbonate-based resin composition including: a polycarbonate-polyorganosiloxane copolymer (A); and at least one kind of compound (B) selected from the group consisting of an antioxidant, a dye, a release agent, a light-diffusing agent, a flame retardant, a UV absorber, a silicone-based compound, an epoxy compound, and a polyether compound, wherein the polycarbonate-polyorganosiloxane copolymer (A) contains a polycarbonate block (A-1) and a polyorganosiloxane block (A-2), and satisfies the following requirements (1) to (3): (1) the content of the polyorganosiloxane block (A-2) is from more than 40 mass % to 70 mass % or less; (2) the copolymer has a viscosity-average molecular weight of from 10,000 to 23,000; and (3) the copolymer contains a specific polycarbonate block as the polycarbonate block (A-1).

Polymer compositions containing an ethylene polymer, 50-1500 ppm by weight of a glycerol stearate, and 250-7500 ppm by weight of an antioxidant selected from a phenolic antioxidant, a phosphite antioxidant, a thioester antioxidant, or any combination thereof, are described. These polymer compositions have improved initial color, improved color after long-term aging, or improved color after multi-pass extrusion processing.