Synthesis of organyloxyfunctional organosilicon compounds is facilitated by a two-step process using a basic lithium, guanidine or amidine catalyst in the first step, and a phosphorus compound having a PO linkage in a second step.

Synthesis of organyloxyfunctional organosilicon compounds is facilitated by a two-step process using a basic lithium, guanidine or amidine catalyst in the first step, and a phosphorus compound having a PO linkage in a second step.

Synthesis of organyloxyfunctional organosilicon compounds is facilitated by a two-step process using a basic lithium, guanidine or amidine catalyst in the first step, and a phosphorus compound having a PO linkage in a second step.

The present technology provides a rubber composition containing: (A) a diene rubber, (B) from 5 to 200 parts by mass of silica per 100 parts by mass of the diene rubber, (C) from 1 to 20 mass % of a sulfur-containing silane coupling agent relative to the amount of the silica, (D) for example, from 1 to 20 mass % of n-octyltriethoxysilane relative to the amount of the silica; and (E) from 1 to 20 mass % of a glycerol monofatty acid ester derived from a fatty acid having from 8 to 24 carbons relative to the mass of the silica (B).

The present technology provides a rubber composition containing: (A) a diene rubber, (B) from 5 to 200 parts by mass of silica per 100 parts by mass of the diene rubber, (C) from 1 to 20 mass % of a sulfur-containing silane coupling agent relative to the amount of the silica, (D) for example, from 1 to 20 mass % of n-octyltriethoxysilane relative to the amount of the silica; and (E) from 1 to 20 mass % of a glycerol monofatty acid ester derived from a fatty acid having from 8 to 24 carbons relative to the mass of the silica (B).

The present technology provides a rubber composition containing: (A) a diene rubber, (B) from 5 to 200 parts by mass of silica per 100 parts by mass of the diene rubber, (C) from 1 to 20 mass % of a sulfur-containing silane coupling agent relative to the amount of the silica, (D) for example, from 1 to 20 mass % of n-octyltriethoxysilane relative to the amount of the silica; and (E) from 1 to 20 mass % of a glycerol monofatty acid ester derived from a fatty acid having from 8 to 24 carbons relative to the mass of the silica (B).

The present disclosure provides a polyester composition suitable for ultrasonic welding and preparation method thereof, the composition includes the following components in parts by weight: 3050 parts of poly(1,4-cyclohexylene dimethylene terephthalate), 4060 parts of ABS, 510 parts of a melt enhancer, 0.11 parts of an antioxidant, and 0.11 parts of a lubricant. Compared with the existing technologies, the polyester composition provided by the present disclosure improves melt strength by using the melt enhancer. The melt enhancer used is an ultra-high density polyethylene resin having a glycidyl methacrylate group after an irradiation treatment, so that the compatibility of the melt enhancer to the poly(1,4-cyclohexylene dimethylene terephthalate) is improved. In addition, by controlling a glass-transition temperature of the composition, no chipping is generated during ultrasonic welding, and the composition has a high welding strength, which is suitable for ultrasonic welding.

The present disclosure provides a polyester composition suitable for ultrasonic welding and preparation method thereof, the composition includes the following components in parts by weight: 3050 parts of poly(1,4-cyclohexylene dimethylene terephthalate), 4060 parts of ABS, 510 parts of a melt enhancer, 0.11 parts of an antioxidant, and 0.11 parts of a lubricant. Compared with the existing technologies, the polyester composition provided by the present disclosure improves melt strength by using the melt enhancer. The melt enhancer used is an ultra-high density polyethylene resin having a glycidyl methacrylate group after an irradiation treatment, so that the compatibility of the melt enhancer to the poly(1,4-cyclohexylene dimethylene terephthalate) is improved. In addition, by controlling a glass-transition temperature of the composition, no chipping is generated during ultrasonic welding, and the composition has a high welding strength, which is suitable for ultrasonic welding.

A curable formulation containing a metal aprotic organosilanoxide compound of formula (I): {R.sup.1Si(R.sup.2)(R.sup.3)[OSi(R.sup.4)(R.sup.5)].sub.mO}.sub.n-M.sup.1(L).sub.o(X.sup.1)p (I), wherein M.sup.1 is a metal atom Al, Ce, Fe, Sn, Ti, V, or Zr, a polymerizable organosilicon compound, an organosilicon crosslinker for crosslinking the polymerizable organosilicon compound, and a silicon-based adhesion promoter. Also included is a cured product of curing the curable formulation; a manufactured article containing or prepared from the curable formulation or cured product; and methods of making and using the foregoing. The cured product may be free-standing or disposed on a substrate.

The present invention relates to a thermally conductive polysiloxane composition comprising: (A) a thermally conductive filler, (B) a siloxane compound having a specified structure; (C) an alkoxysilane compound having a specified structure; (D) a polyorganosiloxane containing at least one aliphatic unsaturated group per molecule; (E) a polyorganohydrogensiloxane having two or more hydrogen atoms bonded to silicon atoms per molecule; and (F) a platinum-based catalyst.