Materials, methods of making, and methods of using a stable and regenerable immobilized amine sorbents for rare earth element and heavy metal recovery from liquid sources. Embodiments of the invention relate to the novel combination of different polyamines, primarily polyethylenimine Mw=800 (PEI.sub.800), and an epoxysilane, namely 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane (ECTMS), covalently immobilizing theREE and heavy metal-adsorbing amine sites within low cost, porous silica particles.

Materials, methods of making, and methods of using a stable and regenerable immobilized amine sorbents for rare earth element and heavy metal recovery from liquid sources. Embodiments of the invention relate to the novel combination of different polyamines, primarily polyethylenimine Mw=800 (PEI.sub.800), and an epoxysilane, namely 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane (ECTMS), covalently immobilizing theREE and heavy metal-adsorbing amine sites within low cost, porous silica particles.

A room temperature curable organopolysiloxane composition comprises: (A) an organopolysiloxane having alkoxysilyl-containing groups at both molecular terminals; (B) an organopolysiloxane resin; (C) an alkoxysilane; and (D) a condensation-reaction catalyst. The room temperature curable organopolysiloxane composition exhibits good to excellent storage stability. In addition, the room temperature curable organopolysiloxane composition can form a cured product exhibiting good to excellent mechanical properties.

A room temperature curable organopolysiloxane composition comprises: (A) an organopolysiloxane having alkoxysilyl-containing groups at both molecular terminals; (B) an organopolysiloxane resin; (C) an alkoxysilane; and (D) a condensation-reaction catalyst. The room temperature curable organopolysiloxane composition exhibits good to excellent storage stability. In addition, the room temperature curable organopolysiloxane composition can form a cured product exhibiting good to excellent mechanical properties.

A room temperature curable organopolysiloxane composition comprises: (A) an organopolysiloxane having alkoxysilyl-containing groups at both molecular terminals; (B) an organopolysiloxane resin; (C) an alkoxysilane; and (D) a condensation-reaction catalyst. The room temperature curable organopolysiloxane composition exhibits good to excellent storage stability. In addition, the room temperature curable organopolysiloxane composition can form a cured product exhibiting good to excellent mechanical properties.

A method of producing an adhesive resin includes: a heating and kneading step of kneading a mixture containing a ring structure-containing hydrocarbon resin, an adhesive functional group-containing compound, and a peroxide while heating the mixture to obtain a heated and kneaded product; and a cooling and kneading step, performed in succession to the heating and kneading step, of kneading the heated and kneaded product while cooling the heated and kneaded product to obtain a cooled and kneaded product. The adhesive resin has a yellowness index (Yi) of 3.0 or less when 0.8 parts by mass of 2-(5-chloro-2-benzotriazolyl)-6-tert-butyl-p-cresol is added to 100 parts by mass of the adhesive resin.

A method of producing an adhesive resin includes: a heating and kneading step of kneading a mixture containing a ring structure-containing hydrocarbon resin, an adhesive functional group-containing compound, and a peroxide while heating the mixture to obtain a heated and kneaded product; and a cooling and kneading step, performed in succession to the heating and kneading step, of kneading the heated and kneaded product while cooling the heated and kneaded product to obtain a cooled and kneaded product. The adhesive resin has a yellowness index (Yi) of 3.0 or less when 0.8 parts by mass of 2-(5-chloro-2-benzotriazolyl)-6-tert-butyl-p-cresol is added to 100 parts by mass of the adhesive resin.

To provide one liquid type dental adhesive composition that exhibits excellent adhesive property to glass ceramics, oxide-base ceramics and tooth substance, and has excellent storage stability, which are contrary features. One liquid type dental adhesive composition contains (a) silane coupling agent represented by general formula (1), (b) acidic group-containing polymerizable monomer, (c) volatile organic solvent, and (d) water. ##STR00001##
(In the formula, R.sup.1 represents an organic group having at least one functional group selected from the group consisting of a (meth)acryloyl group, a vinyl group and an epoxy group, R.sup.2 represents C4-C8 linear alkyl group, R.sup.3 represents C1-C8 alkyl group, and n is integer selected from 1 to 3.)

To provide one liquid type dental adhesive composition that exhibits excellent adhesive property to glass ceramics, oxide-base ceramics and tooth substance, and has excellent storage stability, which are contrary features. One liquid type dental adhesive composition contains (a) silane coupling agent represented by general formula (1), (b) acidic group-containing polymerizable monomer, (c) volatile organic solvent, and (d) water. ##STR00001##
(In the formula, R.sup.1 represents an organic group having at least one functional group selected from the group consisting of a (meth)acryloyl group, a vinyl group and an epoxy group, R.sup.2 represents C4-C8 linear alkyl group, R.sup.3 represents C1-C8 alkyl group, and n is integer selected from 1 to 3.)

Photocurable adhesion-promoting compositions containing organic titanates and/or organic zirconates and partially reacted alkoxysilanes and the use of the photocurable adhesion-promoting compositions to provide adhesion between metal substrates and an overlying radiation-cured sealant are disclosed.