A roofing membrane and a method of making the same is provided. The roofing membrane includes a top layer having a flame retardant and a first silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm.sup.3; a scrim layer; and a bottom layer having a flame retardant and a second silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm.sup.3. The top and bottom layers of the roofing membrane both exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.).

A roofing membrane and a method of making the same is provided. The roofing membrane includes a top layer having a flame retardant and a first silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm.sup.3; a scrim layer; and a bottom layer having a flame retardant and a second silane-crosslinked polyolefin elastomer with a density less than 0.90 g/cm.sup.3. The top and bottom layers of the roofing membrane both exhibit a compression set of from about 5.0% to about 35.0%, as measured according to ASTM D 395 (22 hrs @ 70° C.).

A rubber composition contains: a diene rubber; 1 to 25 parts by weight of aromatic modified terpene resin; 80 to 150 parts by weight of silica; 5 to 50 parts by weight of carbon black; an oil component; and 0.1 to 20 wt. % of the weight of the silica of alkyltriethoxysilane having an alkyl group having 3 to 20 carbons, the diene rubber containing 10 to 30 wt. % of natural rubber, 10 to 30 wt. % of solution polymerized styrene butadiene rubber having a styrene unit content of 30 to 40 wt. % and 80 to 40 wt. % of emulsion polymerized styrene butadiene rubber, and a ratio of a total amount of an oil-extending component in the solution polymerized styrene butadiene rubber and/or the emulsion polymerized styrene butadiene rubber, the aromatic modified terpene resin, and the oil component to a weight of the natural rubber being 3.0 to 4.0.

A rubber composition contains: a diene rubber; 1 to 25 parts by weight of aromatic modified terpene resin; 80 to 150 parts by weight of silica; 5 to 50 parts by weight of carbon black; an oil component; and 0.1 to 20 wt. % of the weight of the silica of alkyltriethoxysilane having an alkyl group having 3 to 20 carbons, the diene rubber containing 10 to 30 wt. % of natural rubber, 10 to 30 wt. % of solution polymerized styrene butadiene rubber having a styrene unit content of 30 to 40 wt. % and 80 to 40 wt. % of emulsion polymerized styrene butadiene rubber, and a ratio of a total amount of an oil-extending component in the solution polymerized styrene butadiene rubber and/or the emulsion polymerized styrene butadiene rubber, the aromatic modified terpene resin, and the oil component to a weight of the natural rubber being 3.0 to 4.0.

Particles are prepared in an emulsion using a method that includes providing a first reactant having at least two unsaturated carbon-carbon moieties and a second reactant having at least two Si—H moieties, so long as at least one of the unsaturated carbon-carbon moieties of the first reactant or the Si—H moieties of the second reactant is pendant. The method also includes providing a third reactant having a silicon atom and a condensable reactive group bonded to the silicon atom and also having an unsaturated carbon-carbon moiety and/or a Si—H moiety, providing a hydrosilylation catalyst, and providing a polar liquid. The method further includes combining the first, second, and third reactants to form particles that have a cross-linked network wherein the condensable reactive group is disposed on the particles, and adding a silane having an organic moiety and a condensation leaving group to form the particles.

Particles are prepared in an emulsion using a method that includes providing a first reactant having at least two unsaturated carbon-carbon moieties and a second reactant having at least two Si—H moieties, so long as at least one of the unsaturated carbon-carbon moieties of the first reactant or the Si—H moieties of the second reactant is pendant. The method also includes providing a third reactant having a silicon atom and a condensable reactive group bonded to the silicon atom and also having an unsaturated carbon-carbon moiety and/or a Si—H moiety, providing a hydrosilylation catalyst, and providing a polar liquid. The method further includes combining the first, second, and third reactants to form particles that have a cross-linked network wherein the condensable reactive group is disposed on the particles, and adding a silane having an organic moiety and a condensation leaving group to form the particles.

A curable organopolysiloxane composition contains: (A) 100 mass parts of a functional organopolysiloxane component having at least one radical curable group selected from an acrylate group and a methacrylate group and optionally one or more alkoxysilyl groups; (B) 0 to 100 mass parts of a condensation curable organo polysiloxane component; (C) one to 10 mass parts of tetraalkoxysilanes or a hydrolyate of the tetraalkoxysilanes; and optionally one or more of (D) a radical initiator, (E) a condensation catalyst, (F) fillers, (G) adhesion promoters, (H) pigments, (I) a non-reactive organopolysiloxane, and (J) inhibitors.

A curable organopolysiloxane composition contains: (A) 100 mass parts of a functional organopolysiloxane component having at least one radical curable group selected from an acrylate group and a methacrylate group and optionally one or more alkoxysilyl groups; (B) 0 to 100 mass parts of a condensation curable organo polysiloxane component; (C) one to 10 mass parts of tetraalkoxysilanes or a hydrolyate of the tetraalkoxysilanes; and optionally one or more of (D) a radical initiator, (E) a condensation catalyst, (F) fillers, (G) adhesion promoters, (H) pigments, (I) a non-reactive organopolysiloxane, and (J) inhibitors.

Provided is an adhesive which, in a metal foil-containing laminated composite film used in a high temperature sterilization treatment, is resistant to the effects of moisture in the air during curing, has good workability when used as a solvent-free adhesive, and exhibits excellent adhesive strength and acid resistance. Provided is a method for producing an adhesive composition, the method including: a step of obtaining an alcohol-added isocyanate (E) by reacting a trifunctional or higher isocyanate compound (C2) and a monofunctional alcohol (D) at an equivalence ratio of isocyanate groups in the trifunctional or higher isocyanate compound (C2):monofunctional alcohol (D)=100 mol %:25 to 65 mol %, and a step of mixing a polyisocyanate (A) containing a trifunctional or higher isocyanate compound (C1) and the alcohol-added isocyanate (E), and an alcohol (B) having an acid value of 0.5 to 30 mgKOH/g, so that the equivalence ratio between isocyanate groups in the polyisocyanate (A) and hydroxyl groups in the alcohol (B) (isocyanate groups/hydroxyl groups) is within a range from 0.7 to 2.5.

Provided is an adhesive which, in a metal foil-containing laminated composite film used in a high temperature sterilization treatment, is resistant to the effects of moisture in the air during curing, has good workability when used as a solvent-free adhesive, and exhibits excellent adhesive strength and acid resistance. Provided is a method for producing an adhesive composition, the method including: a step of obtaining an alcohol-added isocyanate (E) by reacting a trifunctional or higher isocyanate compound (C2) and a monofunctional alcohol (D) at an equivalence ratio of isocyanate groups in the trifunctional or higher isocyanate compound (C2):monofunctional alcohol (D)=100 mol %:25 to 65 mol %, and a step of mixing a polyisocyanate (A) containing a trifunctional or higher isocyanate compound (C1) and the alcohol-added isocyanate (E), and an alcohol (B) having an acid value of 0.5 to 30 mgKOH/g, so that the equivalence ratio between isocyanate groups in the polyisocyanate (A) and hydroxyl groups in the alcohol (B) (isocyanate groups/hydroxyl groups) is within a range from 0.7 to 2.5.