C08L1/284

SUSTAINABLE CORE-SHELL MICROCAPSULES PREPARED WITH COMBINATIONS OF CROSS-LINKERS

A biodegradable core-shell microcapsule composition with controlled release of an active material is provided, wherein the shell of the microcapsule is composed of a biopolymer cross-linked with a combination of two or more different types of cross-linking agents.

SUSTAINABLE CORE-SHELL MICROCAPSULES PREPARED WITH COMBINATIONS OF CROSS-LINKERS

A biodegradable core-shell microcapsule composition with controlled release of an active material is provided, wherein the shell of the microcapsule is composed of a biopolymer cross-linked with a combination of two or more different types of cross-linking agents.

COMPOSITION

The present invention relates to a composition capable of improving properties of cleaning a dirt during cleaning.

The composition of the present invention is a composition containing a modified hydroxyalkyl cellulose (A) and a cationic surfactant (B), wherein the modified hydroxyalkyl cellulose (A) has a cationic group and a hydrophobic group represented by a formula (1), each of which is bound to a group resulting from eliminating a hydrogen atom from a hydroxy group of the hydroxyalkyl cellulose; a degree of substitution of the hydroxyalkyl group in the hydroxyalkyl cellulose is 0.1 or more and 3 or less; and a content of the cationic surfactant (B) is more than 1 part by mass and 1,500 parts by mass or less relative to 1 part by mass of the modified hydroxyalkyl cellulose (A).


*—Z—R.sup.1  (1)

BINDER

A novel binder is provided. The binder comprises a polyvinyl alcohol-based polymer which has an average saponification value of 85.0 mol % to 89.0 mol % as measured according to JIS K6726 and meets requirement (A): based on data obtained by measurement of the polyvinyl alcohol-based polymer by liquid chromatography, a value represented by formula (3) shown below is 22 or more, wherein the measurement is performed with a liquid chromatography system equipped with a charged aerosol detector and a Thermo Scientific Acclaim™ 300 column (catalog number: 060266, carbon load: 8%, maximum pressure: 4500 psi, particle size: 3 μm, pore size: 300 A, stationary phase: C18, surface area: 100 m.sup.2/g, length: 150 mm, diameter: 4.6 mm, pH: 2.5 to 7.5, material: glass lined tubing) under the measurement conditions described below, wherein the data represent a baseline-normalized intensity over a retention time of 5.0 to 12.0 minutes at a sampling interval of 500 ms, and wherein the value represented by formula (3) is calculated from formulae (1) and (2) shown below, wherein the intensity at a retention time T.sub.i [min] is represented by P.sub.i [pA].
Measurement Conditions Concentration of an aqueous polyvinyl alcohol-based polymer solution: 0.1% by mass Injection volume of the aqueous polyvinyl alcohol-based polymer solution: 2 μL Column temperature: 50° C. Flow rate: 1.0 mL/min Eluent: a mixed solvent of water and methanol Eluent gradient conditions: the ratio of water and methanol in the eluent changes from 95:5 to 15:85 at a constant rate over a run time from minutes 0 to 10; and the ratio of water and methanol in the eluent is constant at 15:85 over a run time from minutes 10 to 15.


Formulae


T.sub.n=Σ(T.sub.i×P.sub.i)/Σ(P.sub.i)  Formula (1)


T.sub.w=Σ(T.sub.i.sup.2×P.sub.i)/Σ(T.sub.i×P.sub.i)  Formula (2)


{(T.sub.w/T.sub.n)−1}×1000  Formula (3)

BINDER

A novel binder is provided. The binder comprises a polyvinyl alcohol-based polymer which has an average saponification value of 85.0 mol % to 89.0 mol % as measured according to JIS K6726 and meets requirement (A): based on data obtained by measurement of the polyvinyl alcohol-based polymer by liquid chromatography, a value represented by formula (3) shown below is 22 or more, wherein the measurement is performed with a liquid chromatography system equipped with a charged aerosol detector and a Thermo Scientific Acclaim™ 300 column (catalog number: 060266, carbon load: 8%, maximum pressure: 4500 psi, particle size: 3 μm, pore size: 300 A, stationary phase: C18, surface area: 100 m.sup.2/g, length: 150 mm, diameter: 4.6 mm, pH: 2.5 to 7.5, material: glass lined tubing) under the measurement conditions described below, wherein the data represent a baseline-normalized intensity over a retention time of 5.0 to 12.0 minutes at a sampling interval of 500 ms, and wherein the value represented by formula (3) is calculated from formulae (1) and (2) shown below, wherein the intensity at a retention time T.sub.i [min] is represented by P.sub.i [pA].
Measurement Conditions Concentration of an aqueous polyvinyl alcohol-based polymer solution: 0.1% by mass Injection volume of the aqueous polyvinyl alcohol-based polymer solution: 2 μL Column temperature: 50° C. Flow rate: 1.0 mL/min Eluent: a mixed solvent of water and methanol Eluent gradient conditions: the ratio of water and methanol in the eluent changes from 95:5 to 15:85 at a constant rate over a run time from minutes 0 to 10; and the ratio of water and methanol in the eluent is constant at 15:85 over a run time from minutes 10 to 15.


Formulae


T.sub.n=Σ(T.sub.i×P.sub.i)/Σ(P.sub.i)  Formula (1)


T.sub.w=Σ(T.sub.i.sup.2×P.sub.i)/Σ(T.sub.i×P.sub.i)  Formula (2)


{(T.sub.w/T.sub.n)−1}×1000  Formula (3)

SUPPORT MATERIALS FOR THREE-DIMENSIONAL PRINTING
20210387422 · 2021-12-16 · ·

The present disclosure relates generally to a support material for three-dimensional printing comprising a blend of at least two cellulose ethers or a blend of at least one cellulose ether and at least one vinyl pyrrolidone polymer. Additionally, the present disclosure relates to a shaped material and a three-dimensionally printed object comprising the support material. Furthermore, a process for producing a three-dimensional object using the support material is also disclosed.

SUPPORT MATERIALS FOR THREE-DIMENSIONAL PRINTING
20210387422 · 2021-12-16 · ·

The present disclosure relates generally to a support material for three-dimensional printing comprising a blend of at least two cellulose ethers or a blend of at least one cellulose ether and at least one vinyl pyrrolidone polymer. Additionally, the present disclosure relates to a shaped material and a three-dimensionally printed object comprising the support material. Furthermore, a process for producing a three-dimensional object using the support material is also disclosed.

SMOOTH HIGH SOLIDS FILM COATING COMPOSITION COMPRISING WATER SOLUBLE CELLULOSE ETHER, PROCESS FOR PREPARING THE SAME AND METHOD OF USE THEREOF
20210371691 · 2021-12-02 · ·

The present application provides high solids film coating compositions comprising a water-soluble cellulose ether, hydroxy propyl cellulose (HPC), a poly (N-vinyl pyrrolidone-co-vinyl acetate) copolymer, a film-forming agent based on D-glucose, plasticizer, medium chain triglycerides (MCT) and an anti-tack agent. The invention further provides a process for preparing the above described film coating compositions and method of coating solid substrate with such coating compositions.

SMOOTH HIGH SOLIDS FILM COATING COMPOSITION COMPRISING WATER SOLUBLE CELLULOSE ETHER, PROCESS FOR PREPARING THE SAME AND METHOD OF USE THEREOF
20210371691 · 2021-12-02 · ·

The present application provides high solids film coating compositions comprising a water-soluble cellulose ether, hydroxy propyl cellulose (HPC), a poly (N-vinyl pyrrolidone-co-vinyl acetate) copolymer, a film-forming agent based on D-glucose, plasticizer, medium chain triglycerides (MCT) and an anti-tack agent. The invention further provides a process for preparing the above described film coating compositions and method of coating solid substrate with such coating compositions.

COMPOSITE MATERIAL, SHEET, AND HEAT INSULATOR

A composite material containing aerogel particles and at least one cellulose-based resin selected from the group consisting of cellulose and a cellulose derivative, in which a content of the aerogel particles is 95 vol % or more. A sheet containing the composite material, and a heat insulator containing the composite material.