Patent classifications
C08L23/142
Power cable
Provided is a power cable including an insulating layer formed of an insulating material that is environmentally friendly and has not only high heat resistance and mechanical strength but also excellent flexibility, bendability, impact resistance, thermal stability, cold resistance, installability, workability, etc., which are trade-off with the physical properties.
Polymer blends with improved processability for TPO roofing membranes and methods for making same
A polymer blend includes 35 to 50 wt % of at least one propylene-based elastomer, 25 to 50 wt % of at least one impact copolymer; and 15 to 25 wt % of at least one low density polyethylene component. The propylene-based elastomer has a heat of fusion less than about 80 J/g, greater than 50 wt % propylene and from about 3 wt % to about 25 wt % units derived from one or more C2 or C4-C12 α-olefins, based on a total weight of the propylene-based elastomer. The low density polyethylene has a density of about 0.90 g/cm.sup.3 to about 0.94 g/cm.sup.3. The polymer blend is useful for making a roofing membrane.
Polymer blends with improved processability for TPO roofing membranes and methods for making same
A polymer blend includes 35 to 50 wt % of at least one propylene-based elastomer, 25 to 50 wt % of at least one impact copolymer; and 15 to 25 wt % of at least one low density polyethylene component. The propylene-based elastomer has a heat of fusion less than about 80 J/g, greater than 50 wt % propylene and from about 3 wt % to about 25 wt % units derived from one or more C2 or C4-C12 α-olefins, based on a total weight of the propylene-based elastomer. The low density polyethylene has a density of about 0.90 g/cm.sup.3 to about 0.94 g/cm.sup.3. The polymer blend is useful for making a roofing membrane.
Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom
Pellet-stable olefinic copolymer bimodal rubber is made using parallel reactors, with one reactor synthesizing higher molecular weight (MW) rubber with dual catalysts, with an improved molecular weight split ratio and an improved composition distribution of the moderate and ultra-high MW components, while another reactor synthesizes random isotactic polypropylene copolymer (RCP). The effluents are reactor-blended and result in pellet-stable bimodal rubber (P-SBR), which may be pelletized. When making thermoplastic vulcanizates (TPVs) with P-SBR, the need to granulate rubber bales and subsequently use talc, clay, or other anti-agglomeration agents to prevent granulated rubber crumbs from agglomerating are eliminated. TPVs made with P-SBR have vulcanized rubber particles that are smaller and more uniform in size, resulting in TPVs with higher particle counts and more thermoplastic “ligaments” between the particles, with such ligaments being made stronger by the added RCP. Such thus-produced TPVs have a lower hysteresis and flexural modulus, and better elastic properties.
Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom
Pellet-stable olefinic copolymer bimodal rubber is made using parallel reactors, with one reactor synthesizing higher molecular weight (MW) rubber with dual catalysts, with an improved molecular weight split ratio and an improved composition distribution of the moderate and ultra-high MW components, while another reactor synthesizes random isotactic polypropylene copolymer (RCP). The effluents are reactor-blended and result in pellet-stable bimodal rubber (P-SBR), which may be pelletized. When making thermoplastic vulcanizates (TPVs) with P-SBR, the need to granulate rubber bales and subsequently use talc, clay, or other anti-agglomeration agents to prevent granulated rubber crumbs from agglomerating are eliminated. TPVs made with P-SBR have vulcanized rubber particles that are smaller and more uniform in size, resulting in TPVs with higher particle counts and more thermoplastic “ligaments” between the particles, with such ligaments being made stronger by the added RCP. Such thus-produced TPVs have a lower hysteresis and flexural modulus, and better elastic properties.
Long chain branched propylene polymer composition
The present invention relates to a propylene polymer composition comprising a long chain branched propylene polymer, wherein said propylene polymer composition has a) a crystallization temperature Tc of less than 115° C., b) a melting temperature Tm of less than 155° C. c) a F30 melt strength of from 5.0 to less than 30.0 cN, and d) a V30 melting extensibility of more than 190 mm/s, a process for producing said propylene polymer composition by reactive modification of a propylene polymer in the presence of a peroxide, an article comprising said propylene polymer composition, the use of said propylene polymer composition for producing an article.
Long chain branched propylene polymer composition
The present invention relates to a propylene polymer composition comprising a long chain branched propylene polymer, wherein said propylene polymer composition has a) a crystallization temperature Tc of less than 115° C., b) a melting temperature Tm of less than 155° C. c) a F30 melt strength of from 5.0 to less than 30.0 cN, and d) a V30 melting extensibility of more than 190 mm/s, a process for producing said propylene polymer composition by reactive modification of a propylene polymer in the presence of a peroxide, an article comprising said propylene polymer composition, the use of said propylene polymer composition for producing an article.
POLYMER COMPOSITION HAVING IMPROVED IMPACT STRENGTH AT LOW TEMPERATURES
A polymer composition includes: (a) a propylene-based polymer having a melt mass-flow rate of ≥5.0 and ≤90.0 g/10 min; and (b) ≥5.0 and ≤30.0 wt %, with regard to the total weight of the polymer composition, of an ethylene-based polymer having: a melt mass-flow rate of 3.0 and ≤30.0 g/10 min; a density of ≥840 and ≤870 kg/m.sup.3; and a content of ≥25.0 and ≤50.0 wt % of moieties derived from 1-octene, with regard to the total weight of the ethylene-based polymer. Such polymer composition demonstrates improved low temperature impact strength, determined as Izod impact strength at −40° C. and/or at −30° C., as well as desirable toughness, determined as tensile modulus, whilst having good flowability in injection moulding and thereby allowing complex, thin-walled objects to be shaped.
POLYMER COMPOSITION HAVING IMPROVED IMPACT STRENGTH AT LOW TEMPERATURES
A polymer composition includes: (a) a propylene-based polymer having a melt mass-flow rate of ≥5.0 and ≤90.0 g/10 min; and (b) ≥5.0 and ≤30.0 wt %, with regard to the total weight of the polymer composition, of an ethylene-based polymer having: a melt mass-flow rate of 3.0 and ≤30.0 g/10 min; a density of ≥840 and ≤870 kg/m.sup.3; and a content of ≥25.0 and ≤50.0 wt % of moieties derived from 1-octene, with regard to the total weight of the ethylene-based polymer. Such polymer composition demonstrates improved low temperature impact strength, determined as Izod impact strength at −40° C. and/or at −30° C., as well as desirable toughness, determined as tensile modulus, whilst having good flowability in injection moulding and thereby allowing complex, thin-walled objects to be shaped.
POLYOLEFIN-BASED RESIN FILM AND LAMINATED BODY USING SAME
The invention provides a polyolefin-based resin film formed from a polypropylene-based resin composition and containing, in a total of 100 parts by weight of the polypropylene-based resin composition, 20-95 parts by weight of a propylene-α olefin random copolymer containing a metallocene-based olefin polymerization catalyst; 0-75 parts by weight of a propylene-α olefin random copolymer containing a Ziegler-Natta-based olefin polymerization catalyst; and 5-15 parts by weight of at least one type of an elastomer selected from the group consisting of an ethylene-butene copolymer elastomer, a propylene-butene copolymer elastomer, and an ethylene-propylene copolymer elastomer, wherein a heat shrinkage ratio in a direction in which a heat shrinkage ratio is larger among a longitudinal direction and a width direction of the polyolefin-based resin film is 1-10%, and an orientation coefficient ΔNx in an x-axis direction calculated from a refractive index of the polyolefin-based resin film is 0.0130-0.0250.