A curable coating composition is provided having multi-functionalized acrylic copolymer and amino-functional silicone resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups and the amino-functional silicone resin is an alkoxy functional siloxane, which optionally is derived from sterically hindered alcohol-amine precursor moieties. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.

A curable coating composition is provided having multi-functionalized acrylic copolymer and amino-functional silicone resin curing agents. The acrylic copolymer of the curable coating composition has, in polymerized form, epoxy functionalized groups and cure compatibility groups and the amino-functional silicone resin is an alkoxy functional siloxane, which optionally is derived from sterically hindered alcohol-amine precursor moieties. The coating compositions are useful in the field of superior weatherable and durable coatings and are useful to replace isocyanate-containing polyurethane based coatings. Also provided are coated articles produced from the curable composition.

Described herein is a 2K clearcoat composition including, Component I including a). at least one resin having carboxylic acid groups with acid value of 50 to 400 mg KOH/g; b). at least one resin having hydroxyl functional groups with a hydroxyl value of 10 to 800 mg KOH/g; c). at least one catalyst; and d). at least one solvent, and Component II including e). at least one epoxy-functional alkoxysilane and/or its oligomer and/or its polymer; and f). at least one crosslinker reactive to hydroxyl groups.

Also described herein are a substrate coated with the dried and cured 2K clearcoat composition and an automotive including the substrate.

Described herein is a 2K clearcoat composition including, Component I including a). at least one resin having carboxylic acid groups with acid value of 50 to 400 mg KOH/g; b). at least one resin having hydroxyl functional groups with a hydroxyl value of 10 to 800 mg KOH/g; c). at least one catalyst; and d). at least one solvent, and Component II including e). at least one epoxy-functional alkoxysilane and/or its oligomer and/or its polymer; and f). at least one crosslinker reactive to hydroxyl groups.

Also described herein are a substrate coated with the dried and cured 2K clearcoat composition and an automotive including the substrate.

A thermoplastic resin composition of the present invention comprises: about 100 parts by weight of a polycarbonate resin; about 10 to about 40 parts by weight of a polyester resin; about 0.1 to about 1.0 parts by weight of a chain extender; about 50 to about 80 parts by weight of glass fibers; about 10 to about 25 parts by weight of a phosphorus flame retardant; and about 1 to about 7 parts by weight of a modified polyolefin, wherein the weight ratio of the polyester resin and the chain extender is about 1:0.01 to about 1:0.06. The thermoplastic resin composition is excellent in dimensional stability, flame retardancy, impact resistance, and the like.

A thermoplastic resin composition of the present invention comprises: about 100 parts by weight of a polycarbonate resin; about 10 to about 40 parts by weight of a polyester resin; about 0.1 to about 1.0 parts by weight of a chain extender; about 50 to about 80 parts by weight of glass fibers; about 10 to about 25 parts by weight of a phosphorus flame retardant; and about 1 to about 7 parts by weight of a modified polyolefin, wherein the weight ratio of the polyester resin and the chain extender is about 1:0.01 to about 1:0.06. The thermoplastic resin composition is excellent in dimensional stability, flame retardancy, impact resistance, and the like.

A composition comprising: a) one or more copolymers of i) one or more of one or more vinyl or vinylidene aromaticmonomers and/or (meth)acrylates; with ii) one or more unsaturated compounds containing one or more nucleophilic groups wherein the copolymer contains on average about 0.01 to about 5.0 percent by weight of nucleophilic groups based on the weight of the copolymer; b) one or more thermoplastic elastomer based polymers containing one or more nucleophilic groups; and c) one or more polymers having electrophilic groups; wherein the electrophilic groups have reacted with the nucleophilic groups and at least a portion of the one or more copolymers containing nucleophilic groups are bonded to at least a portion of the one or more thermoplastic elastomers containing one or more nucleophilic groups by at least a portion of the one or more polymers having electrophilic groups.

A composition comprising: a) one or more copolymers of i) one or more of one or more vinyl or vinylidene aromaticmonomers and/or (meth)acrylates; with ii) one or more unsaturated compounds containing one or more nucleophilic groups wherein the copolymer contains on average about 0.01 to about 5.0 percent by weight of nucleophilic groups based on the weight of the copolymer; b) one or more thermoplastic elastomer based polymers containing one or more nucleophilic groups; and c) one or more polymers having electrophilic groups; wherein the electrophilic groups have reacted with the nucleophilic groups and at least a portion of the one or more copolymers containing nucleophilic groups are bonded to at least a portion of the one or more thermoplastic elastomers containing one or more nucleophilic groups by at least a portion of the one or more polymers having electrophilic groups.

A composite polymer process aid is provided. The process aid includes one or more inorganic mineral fillers and one or functionalized polymers. The functionalized polymers include at least one base polymer functionalized with an epoxy, hydroxyl, β-keto ester, β-keto amide, or carboxylic acid reactive functional group. The composite polymer process aid is in the form of a plurality of individual particles. At least a portion of the individual particles include both inorganic mineral fillers and the functionalized polymers. The composite polymer modifier is formed by a process of: i) blending an aqueous solution, an aqueous dispersion, an aqueous suspension, an aqueous slurry, or a dry powder of the mineral fillers with an aqueous solution, an aqueous dispersion, an aqueous suspension or an aqueous emulsion of the functionalized polymers to form an aqueous blend, and ii) powderizing the aqueous blend to form the composite polymer process aid.

A composite polymer process aid is provided. The process aid includes one or more inorganic mineral fillers and one or functionalized polymers. The functionalized polymers include at least one base polymer functionalized with an epoxy, hydroxyl, β-keto ester, β-keto amide, or carboxylic acid reactive functional group. The composite polymer process aid is in the form of a plurality of individual particles. At least a portion of the individual particles include both inorganic mineral fillers and the functionalized polymers. The composite polymer modifier is formed by a process of: i) blending an aqueous solution, an aqueous dispersion, an aqueous suspension, an aqueous slurry, or a dry powder of the mineral fillers with an aqueous solution, an aqueous dispersion, an aqueous suspension or an aqueous emulsion of the functionalized polymers to form an aqueous blend, and ii) powderizing the aqueous blend to form the composite polymer process aid.