A binder composition for a secondary battery which includes a copolymer binder including at least one unit selected from (A) a unit derived from a vinyl-based monomer, (B) a unit derived from a conjugated diene-based monomer or a conjugated diene-based polymer, (C) a unit derived from a (meth)acrylic acid ester-based monomer, and (D) a unit derived from a water-soluble polymer, wherein the copolymer binder has a wet modulus of 0.02 MPa or more, and a negative electrode for a lithium secondary battery and a lithium secondary battery which include the same.

A binder composition contains an organic solvent and a binder that includes a particulate polymer A and a highly soluble polymer B. The particulate polymer A includes an ethylenically unsaturated acid monomer unit in a proportion of not less than 1.0 mass % and not more than 10.0 mass % and a (meth)acrylic acid ester monomer unit in a proportion of not less than 30.0 mass % and not more than 98.0 mass %. The particulate polymer A includes two particulate polymers A1 and A2 having different volume-average particle diameters. The volume-average particle diameters D50.sub.A1 and D50.sub.A2 of these particulate polymers A1 and A2 satisfy a formula: D50.sub.A2>D50.sub.A1≥50 nm.

A binder composition contains an organic solvent and a binder that includes a particulate polymer A and a highly soluble polymer B. The particulate polymer A includes an ethylenically unsaturated acid monomer unit in a proportion of not less than 1.0 mass % and not more than 10.0 mass % and a (meth)acrylic acid ester monomer unit in a proportion of not less than 30.0 mass % and not more than 98.0 mass %. The particulate polymer A includes two particulate polymers A1 and A2 having different volume-average particle diameters. The volume-average particle diameters D50.sub.A1 and D50.sub.A2 of these particulate polymers A1 and A2 satisfy a formula: D50.sub.A2>D50.sub.A1≥50 nm.

A waterproof architectural element comprising an elongated panel member composed of compressed fibrous material having a first planar surface and an opposed second planar surface. At least one elongated cellulose layer is composed of Kraft paper having paper basis weight between 30 and 90 pounds and an average thickness between 0.003 and 0.009 inches. The elongated substrate has a first planar face and an opposed second planar face. A polymeric layer overlies at least a portion of the first planar face of the elongated substrate and comprises a polymeric blend of between 50 and 80 wt. % styrene butadiene copolymer and 0.2 and 3 wt. % of a cellulose ether compound. The cellulose ether compound comprises hydrogen or an alkyl group selected from the group consisting of methyl, ethyl, hydroxyethyl, hydroxypropyl carboxymethyl, hydroxyethyl methyl, hydroxypropyl and between 30 and 50 wt. % calcium carbonate and water.

A waterproof architectural element comprising an elongated panel member composed of compressed fibrous material having a first planar surface and an opposed second planar surface. At least one elongated cellulose layer is composed of Kraft paper having paper basis weight between 30 and 90 pounds and an average thickness between 0.003 and 0.009 inches. The elongated substrate has a first planar face and an opposed second planar face. A polymeric layer overlies at least a portion of the first planar face of the elongated substrate and comprises a polymeric blend of between 50 and 80 wt. % styrene butadiene copolymer and 0.2 and 3 wt. % of a cellulose ether compound. The cellulose ether compound comprises hydrogen or an alkyl group selected from the group consisting of methyl, ethyl, hydroxyethyl, hydroxypropyl carboxymethyl, hydroxyethyl methyl, hydroxypropyl and between 30 and 50 wt. % calcium carbonate and water.

A binder composition for a non-aqueous secondary battery electrode contains: a polymer A including a (meth)acrylic acid ester monomer unit; a polymer B having an iodine value of not less than 5 g/100 g and not more than 100 g/100 g; a polymer C including a nitrile group-containing monomer unit in a proportion of not less than 70 mass % and not more than 98 mass %; and an organic solvent.

The present disclosure relates to compositions comprising a copolymer derived from polymerizing monomers comprising a vinyl aromatic monomer, butadiene, and an acid monomer, in the presence of a chain transfer agent. The chain transfer agent can be present in an amount sufficient to reduce the theoretical glass transition temperature (T.sub.g) of the copolymer by at least 5 C. compared to a copolymer polymerized using identical monomers in the absence of the chain transfer agent. The compositions can be used to prepare compositions such as coatings that have improved water resistance. Methods of making the copolymers are also provided.

The present disclosure relates to compositions comprising a copolymer derived from polymerizing monomers comprising a vinyl aromatic monomer, butadiene, and an acid monomer, in the presence of a chain transfer agent. The chain transfer agent can be present in an amount sufficient to reduce the theoretical glass transition temperature (T.sub.g) of the copolymer by at least 5 C. compared to a copolymer polymerized using identical monomers in the absence of the chain transfer agent. The compositions can be used to prepare compositions such as coatings that have improved water resistance. Methods of making the copolymers are also provided.

The invention relates to a use of a coating layer on a paper substrate for blocking oxygen transfer through the coated paper substrate, wherein the coating layer on the paper substrate is obtainable by a process, which comprises the steps of (a) providing a paper substrate with a surface, (b) applying onto the surface of the provided paper substrate an aqueous coating mass, and (c) drying of the paper substrate with the applied aqueous coating mass to obtain the coated paper substrate, wherein the aqueous coating mass contains an aqueous dispersion of a copolymer P, which is obtainable by radically initiated emulsion polymerization of at least 40 parts by weight of styrene and 22 to 49 parts by weight of butadiene and optionally other monomers based on the sum total of the parts by weight of all monomers, which is always 100, in the presence of a first degraded starch. It relates further to a coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and a further saccharide, which is added after the polymerization of the monomers. It relates also to a process for manufacturing the coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and the further saccharide.

The invention relates to a use of a coating layer on a paper substrate for blocking oxygen transfer through the coated paper substrate, wherein the coating layer on the paper substrate is obtainable by a process, which comprises the steps of (a) providing a paper substrate with a surface, (b) applying onto the surface of the provided paper substrate an aqueous coating mass, and (c) drying of the paper substrate with the applied aqueous coating mass to obtain the coated paper substrate, wherein the aqueous coating mass contains an aqueous dispersion of a copolymer P, which is obtainable by radically initiated emulsion polymerization of at least 40 parts by weight of styrene and 22 to 49 parts by weight of butadiene and optionally other monomers based on the sum total of the parts by weight of all monomers, which is always 100, in the presence of a first degraded starch. It relates further to a coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and a further saccharide, which is added after the polymerization of the monomers. It relates also to a process for manufacturing the coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and the further saccharide.