Provided is an aqueous resin composition containing a polycarbonate-modified acrylic resin that is a reaction product of a polycarbonate diol (A) made from 1,4-butanediol as an essential raw material and an unsaturated monomer mixture (B) containing methyl methacrylate, an unsaturated monomer (b1) having a hydroxy group, an unsaturated monomer (b2) having a carboxy group, and an unsaturated monomer (b3) having an alicyclic structure as essential components, and an aqueous medium, in which the ratio of the unsaturated monomer (b3) in the unsaturated monomer mixture (B) is in the range of 3 to 60% by mass. This aqueous resin composition is suitable for aqueous paints and plastic molded articles since the composition can form a coating film having high adhesion to a plastic substrate and having high water-resistant adhesion and fragrance resistance.

A superhydrophobic coating having a three-dimensional porous nanocomposite structure, includes: a constructing unit and a bonding unit; the constructing unit comprises inorganic hydrophobic nanoparticles, the bonding unit comprises hydrophobic polymer nanomicrospheres, and the inorganic hydrophobic nanoparticles and the hydrophobic polymer nanomicrospheres are interconnected to form uniform pores. A method for preparation of the superhydrophobic coating includes: mixing the inorganic hydrophobic nanoparticles with the hydrophobic polymer nanomicrospheres in a dispersant to form a coating solution; and coating the coating solution on the surface of a substrate using a dip coating, roll coating or spray coating process, and drying to form the superhydrophobic coating of a three-dimensional porous nanocomposite structure.

A superhydrophobic coating having a three-dimensional porous nanocomposite structure, includes: a constructing unit and a bonding unit; the constructing unit comprises inorganic hydrophobic nanoparticles, the bonding unit comprises hydrophobic polymer nanomicrospheres, and the inorganic hydrophobic nanoparticles and the hydrophobic polymer nanomicrospheres are interconnected to form uniform pores. A method for preparation of the superhydrophobic coating includes: mixing the inorganic hydrophobic nanoparticles with the hydrophobic polymer nanomicrospheres in a dispersant to form a coating solution; and coating the coating solution on the surface of a substrate using a dip coating, roll coating or spray coating process, and drying to form the superhydrophobic coating of a three-dimensional porous nanocomposite structure.

A composition including: (a) at least one anionically stabilized acrylic polymer dispersion where the acrylic polymer contains acid monomer units; and (b) at least on polyamino siloxane relative to the weight of the total polymers in the composition, wherein the polyaminosiloxane copolymer containing steric stabilizing groups having a pendant group with a secondary or a primary amine functionality; and (ii) at least a portion of the silicon atoms in the polyaminosiloxane copolymer containing steric stabilizing groups having a pendant alkyl-poly(ethylene oxide) chain with 5 ethylene oxide units to 20 ethylene oxide units.

A composition including: (a) at least one anionically stabilized acrylic polymer dispersion where the acrylic polymer contains acid monomer units; and (b) at least on polyamino siloxane relative to the weight of the total polymers in the composition, wherein the polyaminosiloxane copolymer containing steric stabilizing groups having a pendant group with a secondary or a primary amine functionality; and (ii) at least a portion of the silicon atoms in the polyaminosiloxane copolymer containing steric stabilizing groups having a pendant alkyl-poly(ethylene oxide) chain with 5 ethylene oxide units to 20 ethylene oxide units.

Methods of producing colored and superhydrophobic surfaces, objects, and coatings using a colored paint that imparts a superhydrophobic surface on an object is a suspension of hydrophobic particles in a polymeric binder and a plasticizer in a solvent or mixed solvent, wherein at least a portion of the hydrophobic particles are colored particles. Colored particles can be ultramarine, iron oxide, chromium oxide, or any other colored metal oxide. The hydrophobic particles can be metal oxide particles that are surface functionalized with a fluorinated alkyl silane or an alkyl silane. The binder is a mixture of PDVF and PMMA in a ratio of 3:1 to 10:1. The plasticizer is a mixture of triethyl phosphate and perfluoro(butyltetrahydrofuran) or other perfluorinated hydrocarbon. Surfaces coated using this paint display contact angles in excess of 150° and resist abrasion.

Methods of producing colored and superhydrophobic surfaces, objects, and coatings using a colored paint that imparts a superhydrophobic surface on an object is a suspension of hydrophobic particles in a polymeric binder and a plasticizer in a solvent or mixed solvent, wherein at least a portion of the hydrophobic particles are colored particles. Colored particles can be ultramarine, iron oxide, chromium oxide, or any other colored metal oxide. The hydrophobic particles can be metal oxide particles that are surface functionalized with a fluorinated alkyl silane or an alkyl silane. The binder is a mixture of PDVF and PMMA in a ratio of 3:1 to 10:1. The plasticizer is a mixture of triethyl phosphate and perfluoro(butyltetrahydrofuran) or other perfluorinated hydrocarbon. Surfaces coated using this paint display contact angles in excess of 150° and resist abrasion.

A multiphase emulsion polymer for aqueous coating compositions containing little or no organic solvent includes at least one soft phase and at least one hard phase prepared by a multi-stage emulsion polymerization. The hard phase contains a hard phase polymer having a glass transition temperature in a range from 10 C to 100 C which is more than 50 C higher than that of the soft phase polymer. The hard phase is formed as a first stage polymer and the one soft phase is subsequently polymerized in the presence of the first stage polymer. The hard phase polymer includes at least one carboxylic acid monomer and at least one ethylenically unsaturated monomer. A method of making a multiphase emulsion polymer for aqueous coating compositions containing zero or low levels of organic solvent is disclosed. Such aqueous coating compositions may simultaneously have excellent block resistance, freeze thaw stability and low temperature coalescence characteristics.

A multiphase emulsion polymer for aqueous coating compositions containing little or no organic solvent includes at least one soft phase and at least one hard phase prepared by a multi-stage emulsion polymerization. The hard phase contains a hard phase polymer having a glass transition temperature in a range from 10 C to 100 C which is more than 50 C higher than that of the soft phase polymer. The hard phase is formed as a first stage polymer and the one soft phase is subsequently polymerized in the presence of the first stage polymer. The hard phase polymer includes at least one carboxylic acid monomer and at least one ethylenically unsaturated monomer. A method of making a multiphase emulsion polymer for aqueous coating compositions containing zero or low levels of organic solvent is disclosed. Such aqueous coating compositions may simultaneously have excellent block resistance, freeze thaw stability and low temperature coalescence characteristics.

Embodiments provide a coating material containing: (A) 100 parts by mass of an acrylic curable resin; (B) 5-200 parts by mass of aluminum oxide particles having an average particle size of 1-100 μm; (C) 0.1-20 parts by mass of aluminum oxide fine particles having an average particle size of 1-100 nm; and (D) 1-100 parts by mass of a compound having two or more isocyanate groups per molecule. In one embodiment, the acrylic curable resin (A) includes: (a1) a structural unit derived from a hydroxy group-containing (meth)acrylic acid ester; (a2) a structural unit derived from a vinyl aromatic compound; and (a3) a structural unit derived from a (meth)acrylic acid alkyl ester. In one embodiment, the acrylic curable resin (A) may contain, in addition to the structural units (a1) and (a2): (a3-1) a structural unit derived from methyl methacrylate; and (a3-2) a structural unit derived from an aliphatic (including alicyclic) alkyl ester having 4 or more carbon atoms of a (meth)acrylic acid.