Embodiments of the disclosure include swellable smart gel sealants and methods of using smart gel sealants. In certain embodiments, the smart gel sealants reversibly swell when exposed to a certain trigger, such as carbonic acid and/or sulfuric acid. In specific embodiments, the smart gel is comprised within a cement composition.

Methods of cementing include providing a geopolymer cement composition that includes a monophase amorphous hydraulic binder material (MAHBM), a metal silicate, an alkaline activator, and a carrier fluid, introducing the geopolymer cement composition into a subterranean formation, and allowing the geopolymer cement composition to set in the subterranean formation. The MAHBM includes silica or alumina core particulates coated with an amorphous calcium silicate hydrate.

Methods of cementing include providing a geopolymer cement composition that includes a monophase amorphous hydraulic binder material (MAHBM), a metal silicate, an alkaline activator, and a carrier fluid, introducing the geopolymer cement composition into a subterranean formation, and allowing the geopolymer cement composition to set in the subterranean formation. The MAHBM includes silica or alumina core particulates coated with an amorphous calcium silicate hydrate.

A cement composition can include: water; cement, wherein less than 75 w/w % of the total amount of the cement is Portland cement; and a fluid loss additive, wherein the fluid loss additive comprises a polymer network having at least one branching point formed with a monomer and a cross-linking agent that comprises at least three active functional groups. The cement can also be a non-Portland cement. The monomer can be a vinyl ester-based monomer that is polymerized with the cross-linking agent to form the polymer network. The cement composition can be used in an oil and gas operation.

A cement composition can include: water; cement, wherein less than 75 w/w % of the total amount of the cement is Portland cement; and a fluid loss additive, wherein the fluid loss additive comprises a polymer network having at least one branching point formed with a monomer and a cross-linking agent that comprises at least three active functional groups. The cement can also be a non-Portland cement. The monomer can be a vinyl ester-based monomer that is polymerized with the cross-linking agent to form the polymer network. The cement composition can be used in an oil and gas operation.

Methods of cementing include providing a geopolymer cement composition that includes a monophase amorphous hydraulic binder material (MAHBM), a metal silicate, an alkaline activator, and a carrier fluid, introducing the geopolymer cement composition into a subterranean formation, and allowing the geopolymer cement composition to set in the subterranean formation. The MAHBM includes silica or alumina core particulates coated with an amorphous calcium silicate hydrate.

Methods of cementing include providing a geopolymer cement composition that includes a monophase amorphous hydraulic binder material (MAHBM), a metal silicate, an alkaline activator, and a carrier fluid, introducing the geopolymer cement composition into a subterranean formation, and allowing the geopolymer cement composition to set in the subterranean formation. The MAHBM includes silica or alumina core particulates coated with an amorphous calcium silicate hydrate.

A method of reducing corrosion in tubular strings installed in wellbores includes dispensing an accelerated cement composition into a wellbore annulus, a casing-casing annulus, or both, the accelerated cement composition comprising a cement composition and an accelerant composition, where: the cement composition comprises a cement precursor and water; the accelerant composition comprises triethanolamine; and a concentration of the triethanolamine in the accelerated cement composition is greater than or equal to 10,000 parts per million by weight; allowing the accelerated cement composition to cure in the annulus to form a cured cement, where the triethanolamine reacts with a metal of the tubular string, the reaction forming a protective layer on the surfaces of the tubular string that inhibits dissolution of iron from the metal of the tubular string.

Compositions comprising: (i) a hydraulic cement; and (ii) a polymer comprising at least one monomer having an oxazoline group. Methods of cementing in a well comprising: (A) forming a hydraulic cement composition comprising: (i) a hydraulic cement; (ii) a polymer comprising at least one monomer having an oxazoline group; and (iii) water; (B) introducing the hydraulic cement composition into the well.

Compositions comprising: (i) a hydraulic cement; and (ii) a polymer comprising at least one monomer having an oxazoline group. Methods of cementing in a well comprising: (A) forming a hydraulic cement composition comprising: (i) a hydraulic cement; (ii) a polymer comprising at least one monomer having an oxazoline group; and (iii) water; (B) introducing the hydraulic cement composition into the well.