An overbased sulfonate modified lithium carboxylate grease composition and method of manufacture comprising overbased calcium sulfonate, overbased magnesium sulfonate, or both added to a source of lithium hydroxide, base oil, and optionally one or more acids when a complex grease is desired. When overbased sulfonate is added, the amount of dicarboxylic acid relative monocarboxylic acid may be reduced. Additionally, the amount of lithium hydroxide added may be less than stoichiometrically needed to react with the acids. A sulfonate modified lithium grease with improved thickener yield and dropping point may be made without multiple heating and cooling cycles or using a pressurized kettle.

The present invention relates to a compound of the Formula I:

##STR00001##

and a lubricating composition containing and a method for preparing the same. In Formula I, R.sub.1-R.sub.5 and R.sub.6-R.sub.10 are independently selected from the group consisting of hydrogen, hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from Q.sub.1 and Q.sub.2 is from 6 to 166 carbon atoms, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2−, [Mo.sub.2S.sub.9O].sup.2−, and [Mo.sub.2S.sub.10].sup.2.

The present invention relates to lubricating compositions comprising a compound of Formula I:

##STR00001##

wherein R.sub.1-R.sub.4 and R.sub.5-R.sub.8 are independently selected from the group consisting of hydrocarbyl groups and hydrocarbyl groups containing heteroatoms, such that the total carbon atoms from counterions Q.sub.1 and Q.sub.2 is from 8 to 76, and molybdate anion (Y) is a binuclear sulfur-containing dianion selected from the group consisting of [Mo.sub.2S.sub.8O.sub.2].sup.2−, [Mo.sub.2S.sub.9O].sup.2−, [Mo.sub.2S.sub.10].sup.2−, and mixtures thereof, and are present in the lubricating composition in an amount sufficient to provide about 100-15,000 ppm molybdenum.

To provide a grease composition for a tapered roller bearing having superior bearing lifetime under a condition of high temperature and a condition of high load, and a tapered roller bearing in which the grease composition for the tapered roller bearing is filled. A tapered roller bearing 11 includes an inner ring 12 having a raceway surface 12a, an outer ring 13 having a raceway surface 13a and a plurality of tapered rollers 14, and a flange part of the inner ring 12 gets into sliding contact with the tapered rollers 14. Grease 16 is filled around the tapered rollers 14. The grease 16 includes a base oil, a thickener and an additive. A frequency in which a storage modulus, which varies depending on frequency, of the grease 16 becomes minimum is equal to 7 Hz or more.

To provide a grease composition for a tapered roller bearing having superior bearing lifetime under a condition of high temperature and a condition of high load, and a tapered roller bearing in which the grease composition for the tapered roller bearing is filled. A tapered roller bearing 11 includes an inner ring 12 having a raceway surface 12a, an outer ring 13 having a raceway surface 13a and a plurality of tapered rollers 14, and a flange part of the inner ring 12 gets into sliding contact with the tapered rollers 14. Grease 16 is filled around the tapered rollers 14. The grease 16 includes a base oil, a thickener and an additive. A frequency in which a storage modulus, which varies depending on frequency, of the grease 16 becomes minimum is equal to 7 Hz or more.

The invention relates to lubricating greases based on alkali metal soaps and/or earth-alkali metal soaps and metal complex soaps based on (R)-10-hydroxyoctadecanoic acid and to the use thereof.

The present invention provides a paper ball-like graphene microsphere, a composite material thereof, and a preparation method therefor. Such paper ball-like graphene microspheres are obtained by chemically reducing graphene oxide microspheres to slowly remove oxygen-containing functional groups on the surface of the graphene oxide to avoid the volume expansion caused by rapid removal of the groups, thereby maintaining a tight bond between graphene sheets without separation; and removing the remaining small number of oxygen-containing functional groups and repairing defect structures in the graphene oxide sheets by means of high temperature treatment, such that the graphene structure becomes perfect at an ultrahigh temperature (2500 to 3000° C.), thereby further improving the bonding ability between the graphene sheets in the microspheres and achieving a dense structure.

A silole derivative is of formula (I):

##STR00001## each of the groups in the above formula is defined as those in the description. The silole derivative of formula (I) has aggregation-induced emission performance, and is particularly applicable in luminescent parts and devices, fluorescent probes, biological imaging, lubricating oils and greases. A lubricating grease composition has photoluminescence performance, as well as one or more of advantageous anti-oxidation properties, anti-wear properties, extreme pressure properties and anti-rust properties. It is applicable in many mechanical equipment in electrical industry, metallurgical industry, food industry, paper industry, automobile industry and aircraft industry.

The invention provides a grease composition for lubrication of a sliding surface made of resin, including a fluorine-based base oil and a synthetic hydrocarbon oil as a base oil; a fluorine-based thickener, and a lithium soap thickener or a lithium complex soap thickener as a thickener; and an extreme pressure additive as an additive. The invention also provides a sliding member including a sliding surface made of a resin wherein the grease composition for lubrication is applied to the sliding surface made of a resin.

A grease composition containing a base oil and a calcium complex soap as a thickening agent, wherein a C18-22 straight chain, substituted or unsubstituted higher fatty acid; a substituted or unsubstituted aromatic monocarboxylic acid having a benzene ring; a C2-4 straight-chain saturated lower fatty acid; and a substituted or unsubstituted saturated dicarboxylic acid are used as carboxylic acids constituting the calcium complex soap.