The invention discloses Method for whole component microwave fast digestion and precious metal extraction from ionic liquid of waste circuit board, and belongs to the field of hydrometallurgy. Based on the theory that microwaves can directly penetrate through a leaching medium to directly heat a circuit board, microwave-assisted leaching can reinforce mass transfer and heat transfer in the traditional leaching process, the leaching time is greatly shortened, and the leaching efficiency is improved. Before leaching, a waste circuit board does not need to be smashed, and environmental protection is achieved while energy is saved. The temperature rising process and reaction time of the reaction can be controlled, the whole process is conducted under the airtight condition, heat loss in the leaching process is avoided, the valuable leaching rate is high, the selectivity is high, and efficient leaching of valuable metal can be achieved. Precious metal leachate is extracted through imidazolium ionic liquid, the selectivity of the imidazolium ionic liquid to gold is high, and the co-extraction phenomenon of gold, nickel, copper and other ions is avoided. The method for extracting the precious metal leachate through ionic liquid is a green and clean recycling method, and the overall recycling rate of gold, nickel and copper can reach 99% or above

A metallurgical method for operating an autogenous production circuit for producing metal(s), said method using one or more oxidizing agents generated electrolytically in a cell with one or more interfaces which allows anion exchange; said method comprising steps of: (a) leaching of mineral(s) or material(s) containing at least one metal of interest (LX) in a first cell (A) to produce a pregnant leach solution (2) and an acid-ferrous aqueous solution (8); (b) using solvent extraction process(es) or selection process(es) in a second cell (B) to concentrate said metal(s) of interest (SX) of said pregnant leach solution (2) to produce a rich electrolyte (5) and a raffinate solution (4), said raffinate solution (4) being recycled in said first cell (A); and (c) electrowinning (EW) in a third cell (C) of said rich electrolyte (5) received from said second cell (B) and said acid-ferrous aqueous solution (8) received from said first cell (A), for producing a metal cathode (6) and an acid-ferric acid solution (9), said acid-ferric acid solution (9) being recycled in said first cell (A), wherein said steps (a), (b) and (c) are performed in said autogenous circuit that includes said first, second and third cells (A, B, C) with one or more anionic interfaces producing anodic and cathode reactions.

The present invention relates to a chemical and physical hydrometallurgical method with solid-liquid-solid interaction for the solubilization of copper sulphides, by Selective Transformation and Precipitation of soluble, chlorinated, copper species, where said method does not depend on the redox potential and can be carried out in a wide range of pH under conditions of salts supersaturation, which is a condition that is generated by periods of non-irrigation, from ores or copper concentrates, mainly primary sulphides, such as chalcopyrite comprising said copper. This method is composed of 3 steps, called “Moistening and Solvation Step”, “Selective Transformation and Precipitation Step” and “Acid-Chlorinated Washing step”, wherein said method does neither require the addition of oxidizing or reducing agents, nor oxygen. Furthermore, the steps of the method can be applied only with the presence of water, where acid addition is not required. On the other hand, the repetitions of the steps of the method potentiate the physical effects on the ore or concentrate through the phenomena of haloclasty and crystallization of salts. The invention can also be applied to sulphide base metals such as nickel, zinc, cobalt, lead, molybdenum, among others, independently of the usual impurities of the sulphide ores, as occurs with the presence of arsenic.

The invention relates to a method for multi-metal products recovery from pyrolytic waste integrated circuit boards. The method mainly comprises the steps of smelting and blending, atomization, acidolysis and filtration, noble metal recycling, copper extraction and back extraction, nickel extraction and back extraction. Compared with the prior art, the method has the advantages that smoke pollution and the smelting slag treatment in the process of preparing a black copper ingot through multi-metal collaborative smelting are reduced, and the problems of low anode efficiency of the black copper electrolysis process are solved. Meanwhile, the high-temperature high-oxygen atomized gas generated in the atomizing process provides a heat source and an oxygen source for subsequent acidolysis, so that the energy consumption is further reduced. The method has the advantages such as short process, remarkable energy conservation and emission reduction.

THIS invention relates a method for processing a sulphide ore containing metal values comprising the integration of a sand heap leach (10) and a flotation process (12), providing a method which is suited to processing ores with significant quantities of leachable sulphides. The method includes a comminution step (14), and the classification of the comminuted ore into an oversize coarse fraction (16), a fine fraction (18) suitable for fine flotation and optionally an intermediate fraction (20) suitable for coarse flotation. A concentrate (30) containing iron sulphides from a fine flotation step (22) and optionally a concentrate (36) from a coarse flotation step (34) are blended with the oversize coarse fraction (16), to obtain a blended ore (39) is stacked and subjected to a heap leach process (40).

A method of controlling the acid balance in a high chloride heap leach process tomaximise the copper dissolution in a cure step and to increase overall copper recovery which include an agglomeration stage in which acid and process solutions are combined with the ore prior to stacking to form a heap followed by a cure phase to leach a portion of the copper in the ore in the heap followed by an irrigated leach phase in which the remaining copper minerals are leached and copper is recovered from a pregnant leach solution by a solvent extraction step followed by an electrowinning step wherein the acid concentration in the pregnant leach solution which reports to the solvent extraction step is less than 10 g/L to allow effective copper recovery from the pregnant leach solution in the solvent extraction step.

The present disclosure relates to the use of carbonaceous matter and a reagent comprising a thiocarbonyl functional group, for example, in a method for extracting a base metal such as copper from a material comprising the base metal. Such methods can comprise contacting the material under acidic conditions with the carbonaceous matter and the reagent comprising the thiocarbonyl functional group; and optionally recovering the base metal.

Provided is a method for separating copper from nickel and cobalt, which can efficiently and selectively separate copper from nickel and cobalt in a substance containing copper, nickel, and cobalt in a waste lithium ion battery, etc. In this method, a substance containing copper, nickel, and cobalt is sulfurated to obtain a sulfide, the obtained sulfide that contains copper, nickel, and cobalt is brought into contact with an acid solution to obtain a solid containing copper and a leachate containing nickel and cobalt. The sulfide preferably contains copper sulfide as a main component, and contains nickel metal and cobalt metal. In-addition, when bringing the sulfide into contact with the acid solution, the added amounts of the sulfide and the acid solution are preferably adjusted such that the oxidation-reduction potential of the obtained leachate is maintained at 150 mV or less where a silver/silver chloride electrode is a reference electrode.

The present disclosure provides a method of recovering copper, molybdenum, and a precious metal value from a metal-bearing material, the method comprising bulk flotation of the metal-bearing material to form a flotation product, wherein the metal-bearing material comprises a copper compound, a molybdenum compound, and at least one precious metal value, pressure oxidizing the flotation product to form a pressure oxidized discharge, separating the pressure oxidized discharge to form a separated liquid and separated solid, extracting molybdenum, via a molybdenum solution extraction, from the separated liquid to form a molybdenum-containing stream and a copper-containing stream, extracting copper, via a copper solution extraction, from the copper-containing stream, and extracting the precious metal value, via a cyanide leaching process, from the separated solid.

The present disclosure provides a method of recovering copper, molybdenum, and a precious metal value from a metal-bearing material, the method comprising bulk flotation of the metal-bearing material to form a flotation product, wherein the metal-bearing material comprises a copper compound, a molybdenum compound, at least one precious metal value, and a silicate, pressure oxidizing the flotation product to form a pressure oxidized discharge, separating the pressure oxidized discharge to form a separated liquid and separated solid, extracting molybdenum, via a molybdenum solution extraction, from the separated liquid to form a molybdenum-containing stream and a copper-containing stream, extracting copper, via a copper solution extraction, from the copper-containing stream, and extracting the precious metal value, via a cyanide leaching process, from the separated solid.