A multi component braze filler alloy is described having a melting temperature less than about 1235 deg. C. and greater than about 1150 deg. C. This alloy can be processed by hot isostatic pressing (HIP) at a temperature above about 1065 deg. C. and is particularly suited for the repair of gas turbine blades and vanes, especially those made from Alloy 247. The relatively low Ti content in the present braze alloy tends to form less MC carbides at the joint interface, particularly in comparison with other braze alloys high in Zr and/or Hf. Processes for employing this braze filler alloy in processing of nickel-base superalloys, especially Alloy 247, are presented.

The present invention provides a cast product that can further enhance the stability of an alumina barrier layer and can exhibit further superior oxidation resistance, carburization resistance, nitriding resistance, corrosion resistance, and the like when used under a high-temperature atmosphere. The cast product according to the present invention is a cast product having an alumina barrier layer including an aluminum oxide on a surface of a matrix, and the aluminum oxide is (Al.sub.(1-x)M.sub.(x)).sub.2O.sub.3, where M is at least one of Cr, Ni, Si, and Fe, and x satisfies a relationship 0<x<0.5. Furthermore, the cast product according to the present invention is a cast product having an alumina barrier layer including an aluminum oxide on a surface of a matrix, and at least one of Cr, Ni, Si, and Fe forms a solid solution in the aluminum oxide, and at least one of Cr, Ni, Si, and Fe forming the solid solution with Al is contained so as to satisfy a relationship Al/(Cr+Ni+Si+Fe)≧2.0 in an atomic % ratio.

The disclosure describes example systems and techniques for controlling microstructure of a superalloy substrate by controlling temperature during forging and using multiple die forging stages to formation of grain boundary phases of the superalloy, and components formed by such example systems and techniques. The method includes heating a substrate to within a forging temperature range. The substrate includes a nickel-based superalloy, and the forging temperature range is below an eta phase solvus temperature of the substrate. The method includes applying a plurality of die forging stages to the substrate to form a component preform. The method includes maintaining the substrate within the forging temperature range during application of the plurality of die forging stages and cooling the component preform.

Static thermal chemical vapor deposition treatment processes and static thermal chemical vapor deposition treatment systems are disclosed. The process includes providing an enclosed chamber configured to produce a material on a surface of an article within the enclosed chamber in response thermal energy being applied to a gaseous precursor, providing a liquid handling system in selective fluid communication with the enclosed chamber, flowing a liquid precursor through the liquid handling system, converting the liquid precursor to the gaseous precursor, and producing the material on the surface of the article in response to the thermal energy being applied to the gaseous precursor within the enclosed chamber. The system includes the enclosed chamber and the liquid handling system.

A nickel braze alloy may include less than about 2.0 wt. % aluminum, about 18.0-23.0 wt. % cobalt, about 12.0-15.0 wt. % chromium, about 3.8-4.5 wt. % molybdenum, about 0.8-1.5 wt. % niobium, about 1.8-3.0 wt. % tantalum, less than about 2.0 wt. % titanium, about 2.0-3.5 wt. % tungsten, about 0.8-1.2 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

A composition of matter comprises, in combination, in weight percent: a content of nickel as a largest content; 3.10-3.75 aluminum; 0.02-0.09 boron; 0.02-0.09 carbon; 9.5-11.25 chromium; 20.0-22.0 cobalt; 2.8-4.2 molybdenum; 1.6-2.4 niobium; 4.2-6.1 tantalum; 2.6-3.5 titanium; 1.8-2.5 tungsten; and 0.04-0.09 zirconium.

A superalloy component such as a gas turbine engine blade (40) having a ceramic thermal barrier coating (41) is repaired using a textured repair foil (30). A degraded region of the thermal barrier coating is removed (14) and the underlying superalloy material surface is prepared (16) for re-coating. The repair foil is includes a layer of boron-free braze material (34) and a layer of superalloy material (32) having a textured surface (36). The foil is brazed (18) to the prepared surface during a solution heat treatment effective to homogenize the braze (20). A new area of thermal barrier coating (46) is applied over the foil with a bond that is enhanced by the texturing of the foil surface.

A nickel superalloy has the following composition, the concentrations of the different elements being expressed as wt-%: Formula (I), the remainder consisting of nickel and impurities resulting from the production of the superalloy. In addition, the composition satisfies the following equation, wherein the concentrations of the different elements are expressed as atomic percent: Formula (II).

There is provided a method of manufacturing an Ni-base superalloy which enables a uniform coat of a glass lubricant to be maintained even after heated to hot forging temperature. The method of manufacturing an Ni-base superalloy in which a forging stock containing an Ni-base superalloy, coated with a lubricant, is subjected to hot forging includes: a preliminary oxidation step of previously generating a Cr oxide coating film having a film thickness of 0.5 to 50 μm on the forging stock thereby to obtain a preliminarily oxidized material; a lubricant coating step of coating the preliminarily oxidized material with a glass lubricant containing borosilicate glass as a main component thereby to obtain a material to be forged; and a hot forging step of hot forging the material to be forged thereby to obtain a hot forged material.

Treated articles and a process of producing the treated articles, systems having treated articles, and processes incorporating treated articles are disclosed. The treated articles include a metal or metallic substrate, and a surface treatment of the metal or metallic substrate, the surface treatment having fluorine, silicon, and carbon. The systems include a flow path, with the surface treatment being within the flow path. The processes include flowing a fluid through the flow path.