Described are methods of depositing a metal film by chemical reaction on a substrate. The method comprises: exposing the substrate to flows of a first reactant gas comprising a group 2 metal and a second reactant gas comprising a halide to form a first layer containing a metal halide on the substrate; exposing the substrate to a third reactant gas comprising an oxidant to form a second layer containing a metal peroxide or metal hydroxide on the substrate during; exposing the substrate to heat or a plasma to convert the metal peroxide or metal hydroxide to metal oxide. The method may be repeated to form the metal oxide film absent any metal carbonate impurity.

Coatings applicable to a variety of substrate articles, structures, materials, and equipment are described. In various applications, the substrate includes metal surface susceptible to formation of oxide, nitride, fluoride, or chloride of such metal thereon, wherein the metal surface is configured to be contacted in use with gas, solid, or liquid that is reactive therewith to form a reaction product that is deleterious to the substrate article, structure, material, or equipment. The metal surface is coated with a protective coating preventing reaction of the coated surface with the reactive gas, and/or otherwise improving the electrical, chemical, thermal, or structural properties of the substrate article or equipment. Various methods of coating the metal surface are described, and for selecting the coating material that is utilized.

There is a superconducting article that includes a superconducting film comprising a substrate, one or more buffer layers, and a high temperature superconducting (HTS) layer. The superconducting layer may be comprised of the chemical composition REBa.sub.2Cu.sub.3O.sub.7?x, where RE is one or more rare earth elements, for example: Y, La, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. The superconductor layer is produced using Photo-Assisted Metal Organic Chemical Vapor Deposition (PAMOCVD) and contains non-superconducting nanoparticles. The nanoparticles are substantially provided in the a-b plane and naturally oriented. The non-superconducting nanoparticles provide flux pinning centers that improve the critical current properties of the superconducting film.

The present invention relates to a ZnMg alloy-coated steel sheet with excellent blackening resistance and excellent coating adhesion and to a method for manufacturing same. Provided are a ZnMg alloy-coated steel sheet with excellent blackening resistance and excellent adhesion and a method for manufacturing same, the steel sheet comprising: a substrate steel sheet; a ZnFe intermetallic compound layer formed on the substrate steel sheet; a first ZnMg coating layer formed on the ZnFe intermetallic compound layer and comprising a ZnFe intermetallic compound in which the content of Zn is 95% by weight or higher; a second ZnMg coating layer formed on the first ZnMg coating layer and comprising a ZnMg intermetallic compound in which the content of Zn is 80 to 95% by weight; and an oxide film formed on the second ZnMg coating layer and comprising a metallic oxide.

Coatings applicable to a variety of substrate articles, structures, materials, and equipment are described. In various applications, the substrate includes metal surface susceptible to formation of oxide, nitride, fluoride, or chloride of such metal thereon, wherein the metal surface is configured to be contacted in use with gas, solid, or liquid that is reactive therewith to form a reaction product that is deleterious to the substrate article, structure, material, or equipment. The metal surface is coated with a protective coating preventing reaction of the coated surface with the reactive gas, and/or otherwise improving the electrical, chemical, thermal, or structural properties of the substrate article or equipment. Various methods of coating the metal surface are described, and for selecting the coating material that is utilized.

A mixed material for vapor deposition of lithium contains lithium oxide M1 in an amount of 90% or more, sodium chloride (at least one material selected from oxides, sulfides, chlorides, and fluorides of alkali metals) M2 having a melting point lower than the melting point of lithium oxide M1, and magnesium oxide (at least one material selected from oxides and sulfides of alkaline-earth metals) M3 having a melting point higher than the melting point of lithium oxide M1.

A mixed material for vapor deposition of lithium contains lithium oxide M1 in an amount of 90% or more, sodium chloride (at least one material selected from oxides, sulfides, chlorides, and fluorides of alkali metals) M2 having a melting point lower than the melting point of lithium oxide M1, and magnesium oxide (at least one material selected from oxides and sulfides of alkaline-earth metals) M3 having a melting point higher than the melting point of lithium oxide M1.

Coatings applicable to a variety of substrate articles, structures, materials, and equipment are described. In various applications, the substrate includes metal surface susceptible to formation of oxide, nitride, fluoride, or chloride of such metal thereon, wherein the metal surface is configured to be contacted in use with gas, solid, or liquid that is reactive therewith to form a reaction product that is deleterious to the substrate article, structure, material, or equipment. The metal surface is coated with a protective coating preventing reaction of the coated surface with the reactive gas, and/or otherwise improving the electrical, chemical, thermal, or structural properties of the substrate article or equipment. Various methods of coating the metal surface are described, and for selecting the coating material that is utilized.

A method of forming a film layer and a substrate comprising the film layer to reduce occurrence of defects and improve the quality of the film layer are described. The method of forming a film layer comprises forming a plurality of sub-film layers of a same material overlapped with each other on a substrate by multiple steps to constitute the film layer, wherein each time a sub-film layer is formed, the newly-formed sub-film layer is cleaned immediately. The substrate comprises a film layer formed by the above method.

Described herein are methods and systems for forming oxides comprising an alkaline earth metal and optionally a transition metal. Suitable alkaline earth metals include strontium. Suitable transition metals include niobium.