This disclosure relates to use of a conversion coating for reduction or prevention of hydrogen sulfide production in cans holding hydrogen sulfide producing liquids, such as wine. This disclosure also relates to metal cans comprising a conversion coating layer deposited on at least a portion of the inside surface of the metal can, a film-forming layer deposited on such conversion coating layer, and a hydrogen sulfide producing liquid deposited inside the metal can.

The present invention relates to a method for substantially nickel-free phosphating of a metallic surface, wherein a metallic surface is treated one after the other with the following compositions: i) with an alkaline, aqueous cleaner composition which comprises at least one water-soluble silicate, and ii) with an acidic, aqueous, substantially nickel-free phosphating composition which comprises zinc ions, manganese ions and phosphate ions. The invention also relates to the above cleaner composition itself and also to a metallic surface phosphate-coated by the above method, and to the use of said surface.

Described herein is an aqueous, chromium-free composition for a pretreatment of aluminum surfaces, which includes at least one water-soluble phosphorus compound, at least one water-soluble zirconium compound, at least one water-soluble titanium compound, and at least one water-soluble molybdenum compound, a phosphorus compound content being in a range from 15 to 50 mg/l (calculated as phosphorus), a zirconium compound content being in a range from 400 to 600 mg/l (calculated as metal), a titanium compound content being in a range from 85 to 400 mg/l (calculated as metal), and a molybdenum compound content being in a range from 40 to 150 mg/l (calculated as metal). Also described herein are a corresponding method and a correspondingly pretreated component or strip.

The present invention relates to a solution that is free of chromium in all its oxidising states, comprising: - at least one chemical oxidising compound, - at least one aluminium complexing agent, - at least one corrosion inhibiting compound, and -optionally, a chemical sealant compound, the solution having a pH in the range from 1 to 5. The present invention also relates to a method for treating a metal surface, comprising the application, on the surface, of a solution as defined above. The present invention additionally relates to a coating of a metal surface that can be obtained by the method for treating a metal surface as defined above, to a metal surface comprising the coating and to the use of the solution in an anti-corrosion treatment of a metal surface.

The invention relates to a process for coating metal surfaces with an aqueous composition in the form of a solution or in the form of a dispersion, the composition comprising at least one phosphate, at least 3 g/l of at least one titanium or/and zirconium compound and at least one complexing agent, and also to corresponding aqueous compositions. The coatings prepared thereby have very good bare corrosion protection in the NSS salt spray test and in the condensation-water/constant-climate test

Disclosed are pretreatment compositions and associated methods for treating metal substrates with pretreatment compositions, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The pretreatment composition includes: (a) a group IIIB and/or IVB metal; (b) free fluorine; (c) a source of aluminum ions; and (d) water. The methods include contacting the metal substrates with the pretreatment composition.

The present invention is directed to a particle having a chemical conversion coating on at least a portion of the particle surface. The present invention is further directed to a coated substrate comprising: (a) a surface that has been contacted with a particle having a chemical conversion coating on at least a portion of the particle surface such that at least some portion of the substrate becomes treated with the conversion coating.

The invention relates to a process for producing a corrosion-inhibiting coating for substrates having a surface consisting of zinc, magnesium, aluminum or one of their alloys, wherein the surface to be treated is brought into contact in direct succession with two aqueous treatment solutions containing chromium(III) ions, metal ions of the substrate surface to be treated and at least one complexing agent. The first treatment solution has a pH in the range from 1.0 to 4.0, while the second treatment solution has a pH of from 3.0 to 12.0. The process of the invention produces a smaller amount of wastewater polluted with heavy metals.

A manufacturing method for steel sheets for containers produces steel sheets with excellent film adhesion qualities. This steel sheet for containers has, on a steel sheet, a chemical conversion coating with a metal Zr content of 1-100 mg/m.sup.2, a P content of 0.1-50 mg/m.sup.2, and an F content of no more than 0.1 mg/m.sup.2, upon which is formed a phenolic resin layer with a C content of 0.1-50 mg/m.sup.2. Moreover, the manufacturing method for steel sheets for containers is a method for obtaining the steel sheet for containers wherein the chemical conversion coating is formed on the steel sheet by subjecting the steel sheet to immersion in or electrolytic treatment with a treatment solution containing Zr ions, phosphoric acid ions, and F ions; and subsequently, the steel sheet upon which the chemical conversion coating has been formed is immersed in, or undergoes topical application of, an aqueous solution containing phenolic resin, then dried.

A manufacturing method for steel sheets for containers produces steel sheets with excellent film adhesion qualities. This steel sheet for containers has, on a steel sheet, a chemical conversion coating with a metal Zr content of 1-100 mg/m.sup.2, a P content of 0.1-50 mg/m.sup.2, and an F content of no more than 0.1 mg/m.sup.2, upon which is formed a phenolic resin layer with a C content of 0.1-50 mg/m.sup.2. Moreover, the manufacturing method for steel sheets for containers is a method for obtaining the steel sheet for containers wherein the chemical conversion coating is formed on the steel sheet by subjecting the steel sheet to immersion in or electrolytic treatment with a treatment solution containing Zr ions, phosphoric acid ions, and F ions; and subsequently, the steel sheet upon which the chemical conversion coating has been formed is immersed in, or undergoes topical application of, an aqueous solution containing phenolic resin, then dried.