Embodiments of the invention relate to methods and systems for producing ammonium perchlorate.

Disclosed is an integrally combined electrical current carrier, circulation chamber and frame (CCF) formed as a single or double part (CCF) for use in unipolar electrochemical devices. The CCF is structured to define an internal circulation chamber for circulation of electrolyte, products, and reactants as well as apertures which form flow passageways when the filter press device is assembled. Affixed on opposed surfaces of the CCFs are electrically conductive planar electroactive structures which are in electrical contact with the CCF. The circulation chamber is formed by the depth of the CCF itself between opposing electroactive structures. Multiple CCFs are assembled and compressed together to form the filter press electrolyser apparatus. When power is applied to the CCFs and electroactive structures, the reactants, once they flow into the circulation chamber with the electrolyte, undergo redox reactions to produce products that are collected and exit the electrolyser in upper flow pathways.

The present invention provides a method for manufacturing a chlorous acid aqueous solution using salt as a raw material. The present invention provides a method for manufacturing a chlorous acid aqueous solution, the method including 1) a step for electrolyzing salt and obtaining a chlorate or an aqueous solution thereof, and 2) a step for reducing the chlorate or aqueous solution thereof and manufacturing an aqueous solution including chlorous acid. The method for manufacturing a chlorous acid aqueous solution includes a step for mixing an inorganic acid or an inorganic acid salt as a simple substance or two or more types thereof with the aqueous solution including chlorous acid, and then mixing any of an inorganic acid, an inorganic acid salt, an organic acid, or an organic acid salt as a simple substance or two or more types thereof.

The present invention provides a method for manufacturing a chlorous acid aqueous solution using salt as a raw material. The present invention provides a method for manufacturing a chlorous acid aqueous solution, the method including 1) a step for electrolyzing salt and obtaining a chlorate or an aqueous solution thereof, and 2) a step for reducing the chlorate or aqueous solution thereof and manufacturing an aqueous solution including chlorous acid. The method for manufacturing a chlorous acid aqueous solution includes a step for mixing an inorganic acid or an inorganic acid salt as a simple substance or two or more types thereof with the aqueous solution including chlorous acid, and then mixing any of an inorganic acid, an inorganic acid salt, an organic acid, or an organic acid salt as a simple substance or two or more types thereof.

There is provided a new type of electro-synthetic (electrochemical) or electro-energy cell, such as a fuel cell. The cell includes a liquid electrolyte and at least one gas diffusion electrode (GDE). The GDE operates as a gas depolarized electrode and includes a gas permeable material that is substantially impermeable to the liquid electrolyte, as well as a porous conductive material provided on a liquid electrolyte facing side of the gas diffusion electrode. The porous conductive material can be attached to the gas permeable material by being laminated. Alternatively, the porous conductive material is deposited or coated on at least part of the gas permeable material. A depolarizing gas can be received by the at least one gas diffusion electrode to gas depolarize the electrode. The depolarizing gas changes a half-reaction that would occur at the gas diffusion electrode to a half-reaction that is energetically more favorable.

A side stream subsystem can be used to remove impurity species from the recirculating alkali metal chloride solution in certain electrolysis systems. Silicon and/or aluminum species can be removed via precipitation after introducing an alkali metal hydroxide and magnesium chloride in a side stream line in the subsystem. The invention can allow for a substantial reduction in raw material and capital costs.

A method and/or electrochemical cell for utilising one or more gas diffusion electrodes (GDEs) in an electrochemical cell, the one or more gas diffusion electrodes have a wetting pressure and/or a bubble point exceeding 0.2 bar. The one or more gas diffusion electrodes can be subjected to a pressure differential between a liquid side and a gas side. A pressure on the liquid side of the GDE over the gas side does not exceed the wetting pressure of the GDE during operation (in cases where a liquid electrolyte side has higher pressure), and/or a pressure on the gas side of the GDE over the liquid side, does not exceeds the bubble point of the GDE (in cases where the gas side has the higher pressure).

A method and/or electrochemical cell for utilizing one or more gas diffusion 5 electrodes (GDEs) in an electrochemical cell, the one or more gas diffusion electrodes have a wetting pressure and/or a bubble point exceeding 0.2 bar. The one or more gas diffusion electrodes can be subjected to a pressure differential between a liquid side and a gas side. A pressure on the liquid side of the GDE over the gas side does not exceed the wetting pressure of the GDE during 10 operation (in cases where a liquid electrolyte side has higher pressure), and/or a pressure on the gas side of the GDE over the liquid side, does not exceeds the bubble point of the GDE (in cases where the gas side has the higher pressure).

The present invention provides a method for manufacturing a chlorous acid aqueous solution using salt as a raw material. The present invention provides a method for manufacturing a chlorous acid aqueous solution, the method including 1) a step for electrolyzing salt and obtaining a chlorate or an aqueous solution thereof, and 2) a step for reducing the chlorate or aqueous solution thereof and manufacturing an aqueous solution including chlorous acid. The method for manufacturing a chlorous acid aqueous solution includes a step for mixing an inorganic acid or an inorganic acid salt as a simple substance or two or more types thereof with the aqueous solution including chlorous acid, and then mixing any of an inorganic acid, an inorganic acid salt, an organic acid, or an organic acid salt as a simple substance or two or more types thereof.

Disclosed are gas permeable 3D electrodes, preferably that have practical utility in, particularly, electro-energy and electro-synthetic applications. Gas permeable materials, such as non-conductive porous polymer membranes, are attached to one or more porous conductive materials. In another aspect there is provided a method for the fabrication of gas permeable 3D electrodes, for example gas diffusion electrodes (GDEs). The 3D electrodes can be utilised in electrochemical cells or devices.