Self-cleaning electrochemical cells, systems including self-cleaning electrochemical cells, and methods of operating self-cleaning electrochemical cells are disclosed. The self-cleaning electrochemical cell can include a plurality of concentric electrodes disposed in a housing, for example, a cathode and an anode, a fluid channel defined between the concentric electrodes, a separator residing between the concentric electrodes, first and second end caps coupled to respective ends of the housing, and an inlet cone. The separators may be configured to localize the electrodes and dimensioned to minimize a zone of reduced velocity occurring downstream from the separator. The end caps and inlet cone may be dimensioned to maintain fully developed flow and minimize pressure drop across the electrochemical cell.

An electrolytic zinc dosing device that regulates the amount of zinc delivered or dosed into a flowing stream of water as a function, in part, of the current applied to an electrolytic cell and the flow rate of the flowing water. A replaceable electrolytic cell having an anode and a cathode connected to a power supply, and at least one bipolar electrode in aqueous solution between the anode and cathode. Flow rate information and/or total current information are used to determine the dosing quantity of zinc delivered.

Self-cleaning electrochemical cells, systems including self-cleaning electrochemical cells, and methods of operating self-cleaning electrochemical cells are disclosed. The self-cleaning electrochemical cell can include a plurality of concentric electrodes disposed in a housing, for example, a cathode and an anode, a fluid channel defined between the concentric electrodes, a separator residing between the concentric electrodes, first and second end caps coupled to respective ends of the housing, and an inlet cone. The separators may be configured to localize the electrodes and dimensioned to minimize a zone of reduced velocity occurring downstream from the separator. The end caps and inlet cone may be dimensioned to maintain fully developed flow and minimize pressure drop across the electrochemical cell.

A method and apparatus that can include an electrolytic cell and reactor chamber with an upstream ultrasonic cleaning system of the cell for the treatment contaminated water, which can include industrial wastewater containing high concentrations of inorganic compounds and elements. The contaminated water can optionally be effluent from open pit ponds and subterranean mining, produced water from oil and gas activities (upstream, midstream and downstream), ash ponds from the utilities industry, red mud ponds from aluminum production among many industries that produce industrial wastewater with heavy inorganic material concentration.

A water treatment device in which a treatment target water introduction portion is provided in an upper portion of a receptacle, and the water treatment device has a space in which conductive porous members are not disposed between the conductive porous members and the treatment target water introduction portion in the receptacle. When a backwashing fluid is introduced from a lower portion of the receptacle in a desorption, the conductive porous members flow and are agitated owing to the backwashing fluid, because of which a desorption of ions adsorbed to the conductive porous members is promoted. Grains of the agitated conductive porous members collide with other grains of the conductive porous members or with electrodes or a separator, whereby scale and a biofilm appearing on surfaces of the grains of the conductive porous members, the electrodes, or the separator can be removed, and desalination efficiency can be maintained.

In an electrochemical treatment of a liquid in a precipitation reactor, the liquid is brought into contact with an electrically conductive electrode and an electrically conductive counter-electrode. The electrically conductive electrode comprises a flexible area electrode essentially having a two-dimensional extension. An electric voltage is applied between the electrode and the counter-electrode. The flexible area electrode is repeatedly deformed perpendicularly to its two-dimensional extension to inhibit the accumulation of substances precipitated from the liquid on the electrode and to remove substances precipitated from the liquid and accumulated on the electrode from the electrode.

Systems and methods for sanitizing pool/spa water are provided. An electrolytic chlorinator is provided which includes a combined flow, temperature, and salt concentration sensor. The electrolytic chlorinator could include an acid tank for in-situ cleaning of the electrolytic chlorinator or acidification of pool/spa water where needed. A delayed polarity reversal technique is provided for de-scaling and managing passivation of the blades of an electrolytic chlorinator. The electrolytic chlorinator could include a sacrificial anode for protecting components of the chlorinator as well as other pool/spa components. The electrolytic chlorinator could include an integral, electrically-controlled acid generator, a brine tank for periodically superchlorinating and/or shocking pool/spa water, and/or a plurality of chemical tanks/feeds for periodically injecting chemicals into the chlorinator. A combined ultraviolet (UV)/Ozone and salt (electrolytic) chlorine generator is provided, as well as: filters having integral UV sanitizers; reflective linings for UV sanitization systems; means for injecting bubbles into pool/spa water.

Disclosed is a method of removal of an organic pollutant from an aqueous solution, comprising: a) contacting the solution with an anode and a cathode comprising a carbon material; b) applying electrical current to the anode, thereby generating reactive oxygen species; b) oxidizing the organic pollutant with the reactive oxygen species; and c) regenerating the carbon material. Also disclosed is a method of producing reactive oxygen species, comprising: a) flowing an aqeous solution through a reactor comprising at least one cathode and at least one anode; b) applying electrical current to the at least one anode; and c) collecting a product solution comprising reactive oxygen species.

A water treatment apparatus includes: a first granular electrode member and a second granular electrode member stored in a water treatment unit and provided so as to be separated from each other; a power supply unit which applies voltage between the first granular electrode member and the second granular electrode member so that ions contained in treatment target water supplied from one side of the water treatment unit are adsorbed to the first granular electrode member and the second granular electrode member; and a washing water supply pump which causes washing water to flow from the other side of the water treatment unit to the one side of the water treatment unit, thereby washing the first granular electrode member and the second granular electrode member, wherein the first granular electrode member and the second granular electrode member each include a plurality of flowable granular electrode members.

The present invention discloses a method and device for removing chloride ions in desulfurized wastewater by electrochemical coupling. In the device, an electrolyte tank is used as a separator in a separation process and as an electrode regenerator in an electrode regeneration process; two electrodes are a hydrogen evolution electrocatalysis function electrode and an electrochemically switched ion exchange (ESIX) function electrode respectively, and the electrodes are connected with each other by a wire; two DC circuits have opposite electric field directions and are alternately used in the separation process and the electrode regeneration process respectively; the bottom of the electrolyte tank is provided with a purified high-concentration chloride ion wastewater inlet and a flocculation product outlet, and the top is provided with a dechlorination treatment water outlet and a hydrogen collecting port; and in the electrode regeneration process, the electrolyte tank is connected to an electrode regeneration liquid storage tank through a pump and a pipeline. In the present invention, by utilizing the synergistic reinforcement of reactions of an anode and a cathode, the chloride ion removal efficiency and energy utilization efficiency can be improved, and finally the chloride ions in wastewater are present in flocculation products in a solid form, which facilitates recycling.