A method of forming an optical element is provided. The method includes producing silica-based soot particles using chemical vapor deposition, the silica-based soot particles having an average particle size of between about 0.05 μm and about 0.25 μm. The method also includes forming a soot compact from the silica-based soot particles and doping the soot compact with a halogen in a closed system by contacting the silica-based soot compact with a halogencontaining gas in the closed system at a temperature of less than about 1200° C.

A method of making a multi-mode optical fiber that includes: depositing a porous germania-doped silica soot to form a germania-doped porous soot preform; depositing a porous silica layer over the porous soot preform; doping the porous soot preform and the porous silica layer with a fluorine dopant to form a co-doped soot preform having a core region and a fluorine-doped trench region; consolidating the co-doped soot preform to form a sintered glass, co-doped core preform having a refractive index alpha profile between 1.9 and 2.2 measured at 850 nm; depositing a cladding comprising silica over the sintered glass, co-doped preform to form a multi-mode optical fiber preform; drawing the optical fiber preform into a multi-mode optical fiber. Further, the step of doping the germania-doped soot preform and the porous silica layer is conducted according to a doping parameter (Φ) that is set between 20 and 300, and given by:

[00001]$\Phi =\frac{1\times {10}^{14}.Math.R_{\mathrm{prc}}^2.Math.\exp \left(-E/{\mathrm{RT}}_{\mathrm{dop}}\right).Math.T_{\mathrm{dop}}^{1/2}}{x^{3/4}}.$

A production method and others according to the present embodiment are provided with a structure for effectively preventing occurrence of accidental spiking during drawing of a preform. In order to control the residual He-concentration in the center part of the preform, a transparent glass rod that has a predetermined outer diameter and is already sintered but is not doped with an alkali metal yet is annealed in in the atmosphere not containing He gas for an annealing time determined by referring to result data in which the relationship between the annealing time and the residual He-concentration is previously recorded for each outer diameter. In the result data, actually measured data of the residual He-concentration in a produced optical fiber preform and the annealing time are accumulated as annealing treatment results.

An optical fiber includes a core region of silica glass doped with an alkali metal oxide. A depressed-index cladding region surrounds the core region and comprises silica glass doped with a first concentration of fluorine. The depressed-index cladding region has a minimum relative refractive index Δ.sub.3min in a range from −0.80% to −0.30%. An outer cladding region comprises silica glass doped with a second, lesser concentration. The outer cladding region has a relative refractive index Δ.sub.4, where Δ.sub.4−Δ.sub.3min>0.05%. The optical fiber has a time-to-peak hydrogen aging value at 23° C. of less than 100 hours upon exposure to an atmosphere having a total pressure of 1 atm and containing a partial pressure of 0.01 atm H.sub.2 and a partial pressure of 0.99 atm N.sub.2. The optical fiber exhibits an attenuation <0.16 dB/km.

Preparation of halogen-doped silica is described. The preparation includes doping silica with high halogen concentration, sintering halogen-doped silica to a closed-pore state, and subjecting the closed-pore silica body to a thermal treatment process and/or a pressure treatment process. The temperature of thermal treatment is sufficiently high to facilitate reaction of unreacted doping precursor trapped in voids or interstices of the glass structure, but is below temperatures conducive to foaming. Core canes or fibers drawn from halogen-doped silica subjected to the thermal treatment and/or pressure treatment show improved optical quality and possess fewer defects. The thermal treatment and/or pressure treatment is particularly advantageous when used for silica doped with high concentrations of halogen.

A co-doped optical fiber is provided having an attenuation of less than about 0.17 dB/km at a wavelength of 1550 nm. The fiber includes a core region in the fiber having a graded refractive index profile with an alpha of greater than 5. The fiber also includes a first cladding region in the fiber that surrounds the core region. Further, the core region has an relative refractive index of about −0.10% to about +0.05% compared to pure silica. In addition, the core region includes silica that is co-doped with chlorine at about 1.2% or greater by weight and fluorine between about 0.1% and about 1% by weight.

A method of producing a glass preform including: forming a porous glass soot configured by an inner deposition soot deposited on a start material and an outer deposition soot deposited outside the inner deposition soot; and sintering, after the forming, the porous glass soot while doping with fluorine to form a glass body including an inner glass portion and an outer glass layer. An amount of the fluorine, with which the inner deposition soot is doped at the sintering, is equal to or more than 0 g/cm.sup.3 and less than an amount of the fluorine with which the outer deposition soot is doped.

An optical fiber preform includes: a core formed of silica glass which does not contain Ge, wherein the core has at least one of characteristics in spectrometry of (1) an absorption peak is present at a wavelength of 240 nm to 255 nm, and (2) a wavelength at which an ultraviolet transmittance is 50% or lower is longer than 170 nm.

A method is provided that includes: forming a low-index trench region with a first density; forming an inner barrier layer comprising silica around the trench region at a second density greater than the first density; depositing silica-based soot around the first barrier layer to form an overclad region at a third density less than the second density; inserting a core cane into a trench-overclad structure; forming an outer barrier layer comprising silica in an outer portion of the overclad region at a fourth density greater than the third density; flowing a down dopant-containing gas through the trench-overclad structure to dope the trench region with the down dopant, and wherein the barrier layers mitigate diffusion of the down-dopant into the overclad region; and consolidating the trench-overclad and the core cane.

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index Δ.sub.1MAX, and an inner cladding region having refractive index Δ.sub.2MIN surrounding the core, where Δ.sub.1MAX>Δ.sub.2MIN.