In some implementations, a substrate tube in a modified chemical vapor deposition process may rotate while glass precursors flow into the substrate tube at a fixed rate. Dopants may be delivered into the substrate tube while heat is applied to the substrate tube to deposit, on an inner wall of the substrate tube, a layer of material including the glass precursors and the dopants. A lateral position of an exit of an injection tube used to deliver the dopants may be adjusted while the substrate tube is rotated and heat is applied to the substrate tube such that the material deposited on the inner wall of the substrate tube has an azimuthally non-uniform doping concentration. Alternatively, a rotation of the substrate tube may be adjusted to create opposing temperature gradients within the substrate tube, causing non-uniform layer deposition to occur on different sides of the substrate tube in alternating passes.

Provided is an optical fiber containing an alkali metal element or the like having a smaller diffusion coefficient than K and having a low Rayleigh scattering loss. An optical fiber is composed of silica glass and includes a core and a cladding arranged to surround the core which has a lower refractive index than the core. The core includes a first core including a central axis and a second core arranged to surround the first core. The average concentration of an alkali metal element or alkaline-earth metal element in the first core is 10 mol ppm or less. The average concentration of chlorine in the first core is 2000 mol ppm or more. The average concentration of an alkali metal element or alkaline-earth metal element in the second core is 10 mol ppm or more. The average concentration of chlorine in the second core is 10 to 600 mol ppm.

An optical fiber preform of the present embodiment comprises a core portion and a cladding each comprised of silica glass. The core portion has a first dopant region including a central axis of the core portion and a second dopant region away from the central axis. The first dopant region contains a first dopant selected from among Na, K, and their compounds, and a concentration of the first dopant is 10 atomic ppm or more but 2,000 atomic ppm or less. The second dopant region contains a second dopant reducing viscosity of the silica glass. The second dopant has, as a characteristic at a temperature of 2,000 C. to 2,300 C., a diffusion coefficient of 110.sup.12 cm.sup.2/s or higher but lower than that of the first dopant, and a concentration of the second dopant region is 10 atomic ppm or more.

The present invention provides a process for fabrication of ytterbium (Yb) doped optical fiber through vapor phase doping technique. The method comprises deposition of Al2O3 and Yb2O3 in vapor phase simultaneously in combination with silica during formation of sintered core layer. This is followed by collapsing at a high temperature in stepwise manner to produce the preform and drawing of fibers of appropriate dimension. The process parameters have been optimized in such a way that Al and Yb-chelate compounds can be transported to the reaction zone without decomposition and condensation of precursor materials. Thus variations of dopants concentration along the length of the preform have been minimized to <1% and good repeatability of the process has also been achieved. The resulting fibers also have smooth core-clad boundary devoid of any star-like defect. The process can be reliably adopted for fabrication of large core Yb doped optical fibers. The fibers also show low loss, negligible center dip and good optical properties suitable for their application as fiber lasers.

A method for a defined deposition of a glass layer on an inner wall of a preform for an optical fiber and/or for setting a refractive index profile of the preform for a multi-mode fiber. The method includes providing the preform having a cavity and an inner wall which defines an inner diameter of the preform, and spreading a deposition gas at a flow speed (v) in the cavity of the preform so as to provide the defined deposition of the glass layer. The defined deposition is performed at a reduced change in the flow speed a*v, where a<1. Based on the defined deposition, a change in the flow speed (v):

[00001]$.Math..Math.v=\frac{4.Math..Math.Q}{}.Math.\left(\frac{1}{d_i^2}-\frac{1}{d_{i+1}^2}\right)$

forms at a volume flow (Q), a first diameter (d.sub.i), and a second diameter (d.sub.i+1).

A rotary feed-through for mounting a rotating substrate tube in a lathe and providing a flow of process gas into the tube, said feed-through including a process gas supply line for providing a process gas into said substrate tube, a rotatable holder arranged for receiving and holding said substrate tube for rotating said substrate tube with respect to said process gas supply line, a rotary union provided between said rotatable holder and said process gas supply line for rotatably connecting said rotatable holder to said process gas supply line, a stationary housing connected to said process gas supply line and to said rotatable holder, therewith forming a closed cavity surrounding said rotary union, wherein said stationary housing further includes an auxiliary gas supply line for providing said closed cavity with an auxiliary gas.

The present invention relates to a method of manufacturing an optical fiber preform for obtaining an optical fiber with low transmission loss. A core preform included in the optical fiber preform comprises three or more core portions, which are each produced by a rod-in-collapse method, and in which both their alkali metal element concentration and chlorine concentration are independently controlled. In two or more manufacturing steps of the manufacturing steps for each of the three or more core portions, an alkali metal element is added. As a result, the mean alkali metal element concentration in the whole core preform is controlled to 7 atomic ppm or more and 70 atomic ppm or less.

An optical fiber containing an alkali metal and capable of reducing Rayleigh scattering loss is provided. An optical fiber has a core and a cladding made of silica glass and enclosing the core. The cladding contains fluorine and has a refractive index lower than the refractive index of the core. The core contains first group dopants selected from the group of Na element, K element, or a compound thereof at an average concentration of 0.2 ppm or more and 10 ppm or less. The core also contains second group dopants for reducing the viscosity of silica glass and having a diffusion coefficient of 110.sup.12 cm.sup.2/s or more and smaller than the diffusion coefficient of the first group dopants, by an average concentration of 0.2 ppm or more at a temperature of 2000 C. to 2300 C.

A method for manufacturing an optical fiber preform made of silica-based glass, the method including: forming a core portion; and forming a cladding portion surrounding the core portion, the cladding portion having a refractive index lower than a refractive index of the core portion, wherein the forming the core portion includes: adding an alkali element group consisting of an alkali metal element and an alkaline earth metal element to an inner surface of a glass pipe made of silica-based glass; and integrating the glass pipe and a glass rod disposed inside the glass pipe to form an integrated rod after the adding.