An optical fiber has a core region that is doped with one or more viscosity-reducing dopants in respective amounts that are configured, such that, in a Raman spectrum with a frequency shift of approximately 600 cm.sup.1, the fiber has a nanoscale structure having an integrated D2 line defect intensity of less than 0.025. Alternatively, the core region is doped with one or more viscosity-reducing dopants in respective amounts that are configured such that the fiber has a residual axial compressive stress with a stress magnitude of more than 20 MPa and a stress radial extent between 2 and 7 times the core radius.

According to another aspect of the invention a majority of the optical propagation through the fiber is supported by an identified group of fiber regions comprising the core region and one or more adjacent cladding regions. The fiber regions are doped with one or more viscosity-reducing dopants in respective amounts and radial positions that are configured to achieve viscosity matching among the fiber regions in the identified group.

The present invention provides a process for fabrication of ytterbium (Yb) doped optical fiber through vapor phase doping technique. The method comprises deposition of Al2O3 and Yb2O3 in vapor phase simultaneously in combination with silica during formation of sintered core layer. This is followed by collapsing at a high temperature in stepwise manner to produce the preform and drawing of fibers of appropriate dimension. The process parameters have been optimized in such a way that Al and Yb-chelate compounds can be transported to the reaction zone without decomposition and condensation of precursor materials. Thus variations of dopants concentration along the length of the preform have been minimized to <1% and good repeatability of the process has also been achieved. The resulting fibers also have smooth core-clad boundary devoid of any star-like defect. The process can be reliably adopted for fabrication of large core Yb doped optical fibers. The fibers also show low loss, negligible center dip and good optical properties suitable for their application as fiber lasers.

A method of manufacturing including: (a) a first vapor deposition step comprising vapor depositing a first porous glass body of a glass former and a doping constituent onto a substrate; (b) a cleaning step after the first vapor deposition step, the cleaning step comprising exposing the first porous glass body to a cleaning gas at a cleaning temperature for a cleaning period of time, the cleaning gas (i) removing a metal or metal oxide from the first porous glass body, (ii) changing an oxidation state of a metal or metal oxide within the first porous glass body, or (iii) a combination of (i) and (ii); and (c) a second vapor deposition step after the cleaning step, the second vapor deposition step comprising vapor depositing a second porous glass body of the glass former onto the first porous glass body resulting in a porous preform for an optical fiber.

A method of manufacturing including: with a porous glass body having a surface and a density at the surface having been loaded into a furnace with heating elements disposed along a length of the porous glass body, a first heat treatment step comprising activating the heating elements until the porous glass body at an inner surface of the porous glass body facing a centerline of the porous glass body has a first temperature that is greater than or equal to 1250 C. for a first period of time greater than or equal to 1 hour; wherein, as a result of the first heat treatment step, the density of the porous glass body at the surface increases but is less than 85% of a closed pore density of a sintered glass preform made from the porous glass body.

An optical fiber has a core region that is doped with one or more viscosity-reducing dopants in respective amounts that are configured, such that, in a Raman spectrum with a frequency shift of approximately 600 cm.sup.1, the fiber has a nanoscale structure having an integrated D2 line defect intensity of less than 0.025. Alternatively, the core region is doped with one or more viscosity-reducing dopants in respective amounts that are configured such that the fiber has a residual axial compressive stress with a stress magnitude of more than 20 MPa and a stress radial extent between 2 and 7 times the core radius. According to another aspect of the invention a majority of the optical propagation through the fiber is supported by an identified group of fiber regions comprising the core region and one or more adjacent cladding regions. The fiber regions are doped with one or more viscosity-reducing dopants in respective amounts and radial positions that are configured to achieve viscosity matching among the fiber regions in the identified group.

An optical fiber package is described comprising a light transmitting core having a core diameter, a coating layer surrounding the core, and wherein the amount of chlorine in the light transmitting core region is homogeneous and comprises at least 3000 ppm. The fiber package is such that the optical fiber core exhibits a reduction in the hydrogen induced attenuation losses. A method for fabricating the optical fiber package is also disclosed.

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index .sub.1MAX, and a inner cladding region having refractive index .sub.2MIN surrounding the core, where .sub.1MAX>.sub.2MIN.

The core region of an optical fiber is doped with chlorine in a concentration that allows for the viscosity of the core region to be lowered, approaching the viscosity of the surrounding cladding. An annular interface region is disposed between the core and cladding and contains a concentration of fluorine dopant sufficient to match the viscosity of the core. By including this annular stress accommodation region, the cladding layer can be formed to include the relatively high concentration of fluorine required to provide the desired degree of optical signal confinement (i.e., forming a low loss optical fiber).

An optical fiber having a core comprising silica and greater than 1.5 wt % chlorine and less than 0.5 wt % F, said core having a refractive index .sub.1MAX, and a inner cladding region having refractive index .sub.2MIN surrounding the core, where .sub.1MAX>.sub.2MIN.

Described is a process for the production of synthetic fused silica in which the deposition surface is located for a period of at least 50% of the build-up time of the soot body at a burner distance in which the horizontally integrated luminous intensity of the flame of the burner used in the targetless state is still at least of the maximum horizontally integrated luminous intensity of the flame.