A manufacturing method of a multilayer ceramic electronic device includes: forming each of stack units by forming each of internal electrode patterns on each of dielectric green sheets, the each of internal electrode patterns including Ni, Sn and Au; forming a multilayer structure by stacking the each of stack units; and firing the multilayer structure, whereby each internal electrode layer is formed from the each of internal electrode patterns and each dielectric layer is formed from the each of the dielectric green sheets wherein, in the each internal electrode layer, an Au concentration near each interface between the each internal electrode layer and the each dielectric layer is larger than an Au concentration in each center portion in a thickness direction.

The present disclosure is directed to using MXene compositions as templates for the deposition of oriented perovskite films, and compositions derived from such methods. Certain specific embodiments include methods preparing an oriented perovskite, perovskite-type, or perovskite-like film, the methods comprising: (a) depositing at least one perovskite, perovskite-type, or perovskite-like composition or precursor composition using chemical vapor deposition (CVD), physical vapor deposition (PVD), or atomic layer deposition (ALD) onto a film or layer of a MXene composition supported on a substrate to form a layered composition or precursor composition; and either (b) (1) heat treating or annealing the layered precursor composition to form a layered perovskite-type structure comprising at least one oriented perovskite, perovskite-type, or perovskite-like composition; or (2) annealing the layered composition; or (3) both (1) and (2).

A dielectric ceramic composition and a multilayer ceramic capacitor including the same are provided. The dielectric ceramic composition includes a BaTiO.sub.3-based base material main ingredient and an accessory ingredient, where the accessory ingredient includes dysprosium (Dy) and niobium (Nb) as first accessory ingredients. A total content of the Dy and Nb is greater than 0.2 mol and less than or equal to 1.5 mol based on 100 mol of titanium (Ti) of the base material main ingredient.

Provided is a multilayer ceramic capacitor having dielectric layers and internal electrode layers laminated alternately on one another. Each internal electrode layer comprises a common ceramic material containing 3 to 25% by weight of rare earth elements, and through the rare earth elements, high dielectric layers are formed on the interfaces between the dielectric layers and the internal electrode layers.

A multilayer ceramic capacitor includes a multilayer structure having a substantially rectangular parallelepiped shape and including dielectric layers and internal electrode layers that are alternately stacked, the dielectric layers being mainly composed of BaTiO.sub.3, the internal electrode layers being alternately exposed to two edge faces of the multilayer chip opposite to each other. A Zr/Ti ratio is 0.02 or more and 0.10 or less in a capacity section. A Ba/Ti ratio is more than 0.900 and less than 1.010 in the capacity section. A Eu/Ti ratio is 0.005 or more and 0.05 or less in the capacity section. A Mn/Ti ratio is 0.0005 or more and 0.05 or less in the capacity section. A total amount of a rare earth element or rare earth elements is less than the amount of Eu.

A manufacturing method of ceramic powder includes mixing a barium carbonate having a specific surface are of 15 m.sup.2/g or more, a titanium dioxide having a specific surface area of 20 m.sup.2/g or more, a first compound of a donor element having a larger valence than Ti, and a second compound of an acceptor element having a smaller valence than Ti and having a larger ion radium than Ti and the donor element, and synthesizing barium titanate powder by calcining the barium carbonate, the titanium dioxide, the first compound and the second compound until a specific surface area of the barium titanate powder becomes 4 m.sup.2/g or more and 25 m.sup.2/g or less.

The present invention is directed to a chromatic effect light reflective unit (1; 1a-1g). The unit (1; 1a-1g) comprises a reflective layer (10) having at least one reflective surface (11), and a chromatic diffusion layer (20) having a first surface (21) proximal to the reflective surface (11) and a second surface (23), opposite and substantially parallel to the first, configured to be illuminated by incident light, wherein the chromatic diffusion layer (20) comprises a nano-pillar (70) or nano-pore (30) structure in a first material having a first refractive index (n1), immersed in a second material having a second refractive index (n2) other than the first (n1), in which the first and second materials are substantially non-absorbing or transparent to electromagnetic radiations with wavelength included in the visible spectrum, wherein the ratio (n.sub.M/n.sub.m) between a higher refractive index (n.sub.M) and a lower refractive index (n.sub.M) chosen between the first (n1) and the second (n2) refractive indexes is comprised between 1.05 and 3, wherein the nano- pillars (71) or nano-pores (31) have a development along a main direction not parallel to the first surface (21) and the second surface (23) of the chromatic diffusion layer and the nano- pillars (70) or nano-pores (30) structure is characterized by a plurality of geometric parameters comprising a pillar diameter or pore diameter (d.sub.p), a pillar length or pore length (1.sub.p) along said main development direction, and a surface density of nano-pillars or nano-pores (D.sub.p) and/or a structure (30,70) porosity (P.sub.p) and wherein the pillar diameter or pore diameter (d.sub.p) is comprised between 40 nm and 300 nm, the length (l.sub.p) along the main development direction is comprised between 300 nm and 40 .Math.m (300 nm < l.sub.p < 40 .Math.m) and at least one between the surface density of nano-pillars or nano-pores (D.sub.p) and the structure (30,70) porosity (P.sub.p) is configured to provide a higher regular reflectance for wavelengths of incident light comprised in the range of red with respect to wavelengths of incident light comprised in the range of blue and a higher diffuse reflectance for wavelengths of incident light comprised in the range of blue than wavelengths of incident light comprised in the range of red.

A dielectric ceramic composition includes main component grains having a perovskite structure represented by a formula AMO.sub.3. “A” includes Ba. “M” includes Ti. The dielectric ceramic composition includes a 4A subcomponent. The 4A subcomponent includes Fe and Mn. A molar ratio of Mn to a total of Fe and Mn in terms of a metal element is 0.18 to 0.65.

A spark plug connecting element. The spark plug connecting element includes a first contact element and a second contact element. A resistor element is situated between the first contact element and the second contact element. The first contact element and the second contact element have a specific conductivity of 10.sup.2 S/m to 10.sup.8 S/m and the resistor element has a specific conductivity of 10.sup.−3 S/m to 10.sup.1 S/m.

A multilayer ceramic capacitor includes: a multilayer structure in which each of dielectric layers and each of internal electrode layers are stacked, wherein a relationship of 8.0≥I.sub.A/I.sub.B>1.40 is satisfied in a TSDC (Thermally Stimulated Depolarization Currents) of temperature elevation rate of 10 degrees C./min under a condition of 130 degrees C., 5 V/μm and a polarization of 30 min, when a peak current value on a lower temperature side in a temperature range of 130 degrees C. to 190 degrees C. is I.sub.A and a peak current value on a higher temperature side in a temperature range of 190 degrees C. to 280 degrees C. is I.sub.B.