Patent classifications
C07C2529/44
Preparation of a ZSM-5-based catalyst; use in ethylbenzene dealkylation process
A process of preparing a catalyst composition which process comprises the steps of (a) treating ZSM-5 zeolite with an alkaline solution having a pH of at least (8) followed by ion exchange to obtain a treated zeolite, (b) extruding a mixture of the treated zeolite and binder and contacting the zeolite with a fluorocompound containing solution, (c) increasing the temperature of the extrudates obtained in step (b) to at least 200 C., and (d) combining the extrudates obtained in step (c) with one or more metals selected from the group consisting of Group (10) and (11) of the IUPAC Periodic Table of Elements and a process for the conversion of an aromatic hydrocarbons containing feedstock using a catalyst composition prepared by such process.
Process for producing purified aromatic hydrocarbons from a mixed hydrocarbon feedstream
The present invention relates to a process for producing benzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide a benzene-rich aromatic stream and recovering the benzene from the benzene-rich aromatic stream.
Process for preparing hydrocracking catalyst
Disclosed herein is a process for preparing a hydrocracking catalyst, comprising (i) combining a zeolite, a binder, water and a hydrogenating metal compound which is a complex or a salt of a hydrogenating metal to obtain a mixture, wherein the zeolite has not been treated with a phosphorus-containing compound and the zeolite has a silica to alumina molar ratio of 5-200; (ii) forming the mixture into a shaped body; and (iii) calcining the shaped body to form the catalyst.
METHOD FOR AROMATIZATION OF LIGHT ALKANES
A method for aromatization of light alkanes, comprising: subjecting the light alkanes to dehydroaromatization reaction in the presence of aromatization catalysts including carriers and metal active components supported on the carriers, the metal active components include platinum, the carriers include zeolites and binders, and at least 80 wt. % of the metal active components are distributed on the zeolites. The method of the present disclosure may increase yield of the target productaromatic hydrocarbons, and the regenerated catalyst can still maintain high catalytic performance. In addition, the method of the present disclosure can meet the requirements of industrial applications.
Metal-loaded zeolite catalysts for the halogen-free conversion of dimethyl ether to methyl acetate
A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.
Synthesis of hierarchical zeolites by solid state crystallization of aluminosilicate nanogels
Hierarchically porous ZSM-5 zeolites, having macropores, mesopores, and micropores are formed using a solid-state crystallization process. An aluminosilicate nanogel prepared with precursors, solvent, and a structure-directing agent is provided. The solvent is evaporated from the aluminosilicate nanogel at room temperature. The dried aluminosilicate nanogel is then heated to promote crystallization. The crystallized zeolites are calcined to remove the structure-directing agent.
Small crystal ZSM-5, its synthesis and use
A molecular sieve having the framework structure of ZSM-5 is described comprising crystals having an external surface area in excess of 100 m.sup.2/g (as determined by the t-plot method for nitrogen physisorption) and a unique X-ray diffraction pattern.
SYSTEM AND METHOD FOR PREPARING AROMATICS BY USING SYNGAS
The present invention relates to a system and process for preparing aromatics from syngases, which has advantages of shortened flow process and reduced investment. The process comprises reforming the liquefied gas, separated dry gas with a water steam to produce carbon monoxide and hydrogen, which return, as raw materials, to the aromatization system, so that the problem of by-product utilization is solved, and the syngas unit consumption per ton of aromatic products is reduced. The problem of utilization of a dry gas as a by-product is also solved in the present invention from the perspective of recycling economy, which reduces the water consumption in the process, and conforms to the concept of green chemistry.
Process for producing alkylated aromatic hydrocarbons from a mixed hydrocarbon feedstream
The present invention relates to a process for producing alkylated aromatic hydrocarbons such as ethyl benzene or cumene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to hydrocracking to provide benzene and subjecting said benzene to alkylation.
Process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream
A process for producing cumene and/or ethylbenzene from a mixed hydrocarbon feedstream comprising subjecting C6 cut separated from said mixed hydrocarbon feedstream to aromatization to provide an aromatization product stream and subjecting the thus obtained aromatization product stream to alkylation to produce an alkylated aromatic stream.