The present invention provides a method for preparing a polyolefin having a broad molecular weight distribution. More specifically, the present invention provides a method for preparing a polyolefin having a broad molecular weight distribution and an ultra-high molecular weight in which an organometallic complex containing a specific TiAl complex structure is used as a molecular weight controller (i.e., molecular weight enhance) in the polymerization of an olefin monomer, thereby enabling both solution polymerization and slurry polymerization, particularly enabling the molecular weight distribution to be more readily and effectively controlled.

An ethylene/butadiene copolymer comprising statistically distributed ethylene units butadiene units, and trans-1,2-cyclohexane units is provided. The molar fraction of ethylene units in the copolymer is greater than or equal to 50%, relative to the total number of moles of ethylene, butadiene and trans-1,2-cyclohexane units. The microstructure of the copolymer is homogeneous. A process for preparing such a copolymer and also to the uses of this copolymer, in particular in rubber compositions for tires, is also provided.

An elastomeric article comprising an olefin-block copolymer comprising within a range from 4 to 40 mol % of C4 to C12 -olefin derived units, the remainder being ethylene-derived units, wherein the melting point temperature (T.sub.m2) is within a range from 92 C. to 120 C., and having an M.sub.w/M.sub.n value of less than 2.5. The olefin-block copolymer is desirably generated by combining ethylene, C4 to C12 -olefins, a single site catalyst, preferably a fluxional catalyst, and an activator. The elastomeric article may be an elastic hygiene garment, especially a garment comprising a waistband, stretch ear panels and/or belly bands.

An elastomeric article comprising an olefin-block copolymer comprising within a range from 4 to 40 mol % of C4 to C12 -olefin derived units, the remainder being ethylene-derived units, wherein the melting point temperature (T.sub.m2) is within a range from 92 C. to 120 C., and having an M.sub.w/M.sub.n value of less than 2.5. The olefin-block copolymer is desirably generated by combining ethylene, C4 to C12 -olefins, a single site catalyst, preferably a fluxional catalyst, and an activator. The elastomeric article may be an elastic hygiene garment, especially a garment comprising a waistband, stretch ear panels and/or belly bands.

A method for forming polar-functionalized polyolefins may comprise contacting an unsubstituted -olefin monomer and an amino-olefin monomer of formula H.sub.2CCH(CH.sub.2).sub.n(CHR).sub.mNR.sub.2, wherein R is H or an unsubstituted linear or branched alkyl group having from 1 to 10 carbons, each R is an independently selected unsubstituted linear or branched alkyl group having from 1 to 10 carbons, m is an integer from 1 to 11, and n is an integer from 1 to 11, in the presence of a rare earth catalyst and a cocatalyst under conditions to induce a heteropolymerization reaction between the unsubstituted oc-olefin and amino-olefin monomers to provide a polar-functionalized poly olefin.

A method for forming polar-functionalized polyolefins may comprise contacting an unsubstituted -olefin monomer and an amino-olefin monomer of formula H.sub.2CCH(CH.sub.2).sub.n(CHR).sub.mNR.sub.2, wherein R is H or an unsubstituted linear or branched alkyl group having from 1 to 10 carbons, each R is an independently selected unsubstituted linear or branched alkyl group having from 1 to 10 carbons, m is an integer from 1 to 11, and n is an integer from 1 to 11, in the presence of a rare earth catalyst and a cocatalyst under conditions to induce a heteropolymerization reaction between the unsubstituted oc-olefin and amino-olefin monomers to provide a polar-functionalized poly olefin.

A method for forming polar-functionalized polyolefins may comprise contacting an unsubstituted -olefin monomer and an amino-olefin monomer of formula H.sub.2CCH(CH.sub.2).sub.n(CHR).sub.mNR.sub.2, wherein R is H or an unsubstituted linear or branched alkyl group having from 1 to 10 carbons, each R is an independently selected unsubstituted linear or branched alkyl group having from 1 to 10 carbons, m is an integer from 1 to 11, and n is an integer from 1 to 11, in the presence of a rare earth catalyst and a cocatalyst under conditions to induce a heteropolymerization reaction between the unsubstituted oc-olefin and amino-olefin monomers to provide a polar-functionalized poly olefin.

A lubricant composition comprising a high-viscosity PAO lubricant base stock having a KV100 of at least 200 cSt and comprising multiple PAO molecules comprising at least 200 carbon atoms per molecule, wherein (i) each of the PAO molecules comprises multiple pendant groups; (i) the average pendant group length of all the pendant groups excluding one methyl on each of the PAO molecules among at least 90 mol % of all of the PAO molecules, if one or more methyl is present, is at least 6.0, and (iii) the concentration of the high-viscosity PAO base stock is no more than 75 wt % of the total weight of the lubricant composition. The lubricant composition exhibits provides a high degree of protection of gear surfaces as measured by ASTM D5182.

The present invention is directed to a heterophasic propylene copolymer (HECO), a polyolefin composition (PO) comprising the heterophasic propylene copolymer (HECO), an automotive article comprising the heterophasic propylene copolymer (HECO) and/or the polyolefin composition (PO) and a process for the preparation of the polyolefin composition (PO) as well as the use of the heterophasic propylene copolymer (HECO) for improving the mechanical properties of a polyolefin composition (PO).

Disclosed herein are ethylene-based polymers generally characterized by a density from 0.89 to 0.93 g/cm.sup.3, a ratio of Mw/Mn from 3 to 6.5, a Mz from 200,000 to 650,000 g/mol, a CY-a parameter at 190 C. from 0.2 to 0.4, and a reverse short chain branching distribution. The ATREF profile of these polymers can have a high temperature peak from 92 to 102 C., and a low temperature peak from 18 to 36 C. less than that of the high temperature peak. These polymers can have comparable physical properties to that of a metallocene-catalyzed LLDPE, but with improved processability, shear thinning, and melt strength, and can be used in blown film and other end-use applications.