A polyurethane composition includes, based on the total weight of the composition, A) 20-35 wt % of polyurethane prepolymer PU-1 which is a reaction product of ethylene oxide (EO)-terminated polyether triol with an aromatic polyisocyanate, and B) 0.2-3 wt % of polyurethane prepolymer PU-2 which is a reaction product of polyester polyol with an aromatic polyisocyanate. The composition has a low TVOC content, has a good adhesion without the need of primer, can cure rapidly with a high initial bonding strength, while keeping good mechanical properties.

One embodiment of the present invention provides a curable composition, including a polyfunctional isocyanate compound, a compound selected from the group consisting of a multivalent alcohol and an epoxy compound, and a base amplifier.

Described herein is a 3D spacer fabric reinforced composite, a process for producing it, a method of using it in footwear, and a footwear including it.

A catalyst system useful in the production of polyurethane and/or polyisocyanurate foams using hydrohaloolefin blowing agents.

A foam-forming composition for producing a rigid polyurethane foam including: (a) at least one isocyanate component; and (b) at least one isocyanate-reactive composition including: (bi) a rigid polyol compound; and (bii) a flexible polyol compound; (c) a catalyst package including at least one latent gelling catalyst; and (d) at least one blowing agent.

Foam wall structures and methods for making them are described. The wall structures include a frame, a foam panel overlying a front surface of the frame, and a polyurethane foam layer disposed in a cavity of the wall structure. The polyurethane foam layer has a density, as determined by ASTM D1622-14, of at least 44 kg/m.sup.3 and exhibits ASTM E84-16 Class A flame spread and smoke development characteristics. The polyurethane foam layer is the cured reaction product of a polyurethane foam-forming composition that includes a polyisocyanate, an aromatic polyester polyol having a functionality of greater than 2.5 and an OH number of at least 300 mg KOH/g, which is present in an amount of at least 50% by weight, based on the total weight of the polyurethane foam-forming composition less the weight of the polyisocyanate, a catalyst, and a blowing agent composition. The blowing agent composition includes water and a hydrofluoroolefin.

Isocyanate-reactive compositions that include a hydrofluoroolefin blowing agent, polyurethane foam-forming compositions, as well as spray-applied polyurethane foams formed therefrom that can provide structural support to wall structures and can also exhibit ASTM E84-16 Class A flame spread and smoke development characteristics at a foam thickness of 4 inches.

A compound of formula (I) having advantageous properties when used as a latent curing agent for compositions containing isocyanate groups, and to compositions containing the compound of formula (I). The compound of formula (I) is odourless, is liquid and has comparatively low viscosity at room temperature and is stable in storage together with isocyanates. It makes possible odourless single-component polyurethane compositions which have good stability in storage, do not produce bubbles when cured in the presence of moisture, and cause no problematic odour emissions, giving a cured elastic material having good mechanical properties, good heat stability, a surprisingly non-adhesive surface and little tendency towards plasticizer migration.

A method for preparing a polyol comprises the following steps of: (1) dissolving 2,3 -epoxybutane and an acid catalyst in an inert solvent to obtain a solution A; dissolving triethylene glycol in an inert solvent to obtain a solution B; and dissolving epoxy vegetable oil in an inert solvent to obtain a solution C; (2) respectively and simultaneously pumping the solutions A and B into a first micromixer for mixing; (3) pumping the solution C and an effluent of the first microreactor into a second micromixer for mixing while carrying out step (2); and (4) dissolving the vegetable oil polyol in an inert solvent to obtain a solution D; dissolving epoxypropane and an alkaline catalyst in an inert solvent to obtain a solution E; and pumping the solution D and the solution E into a tank reactor for reaction, thereby obtaining the polyol.

Disclosed are HCFO-containing isocyanate-reactive compositions, polyurethane foam-forming compositions containing such isocyanate-reactive compositions, rigid polyurethane foams made using such polyurethane foam-forming compositions, and methods for producing such foams, including use of such foams as insulation in the construction of refrigerated storage devices. The isocyanate-reactive composition can exhibit a long shelf life, be shelf-stable, and produce a foam with good thermal insulation properties.