Patent classifications
C08G18/4045
Method for improving fracture toughness of polyisocyanurate comprising reaction products
A curable composition for making polyisocyanurate comprising products obtained by combining and mixing at an isocyanate index of at least 100 at least a polyisocyanate composition, a polytetrahydrofuran polyol (P-THF) having average molecular weight in range 1000-5000 g/mol as toughening agent and diols having an average molecular weight <1000 g/mol.
Polyester prepolymers as impact modifiers in epoxy formulations
What is described is a polymer which is a polyurethane polymer having blocked isocyanate groups or a reaction product of said polyurethane polymer with at least one epoxy resin, where the polyurethane polymer having blocked isocyanate groups is an addition product formed from at least one polyisocyanate and at least one polyester polyol, wherein the isocyanate groups of the addition product have been blocked by reaction with at least one aromatic compound having at least one hydroxyl group. Such a polymer is suitable as an impact modifier in epoxy resin compositions, especially when they are used as adhesives or structural foams. The polymer improves the corrosion resistance and vertical expansion of the epoxy resin composition.
EPOXY RESIN COMPOSITION
Curable composition obtained by combining and mixing an epoxy resin composition comprising an epoxy resin, a monool and/or polyol and a compound comprising a carboxamide group, and a polyisocyanate composition comprising a polyisocyanate, a lithium halide and a urea compound, wherein the number of moles of lithium halide per isocyanate equivalent ranges of from 0.0001-0.04 and the number of urea+biuret equivalents per isocyanate equivalent of from 0.0001-0.4. The epoxy resin composition is claimed as well.
Cardanol modified epoxy polyol
A cardanol modified epoxy polyol may be used for forming a polyurethane resin system for use in applications such as coatings and composites formed by filament winding. The polyurethane resin system includes an isocyanate-reactive component that has a first cardanol component and the cardanol-modified epoxy polyol, and includes an isocyanate component that includes at least one polyisocyanate. The cardanol-modified epoxy polyol is a reaction product of an epoxy component and an epoxy-reactive component at a ratio of epoxy groups to epoxy reactive groups from 1:0.95 to 1:5, and the epoxy-reactive component includes a second cardanol component.
Hybrid matrix for fiber composite materials
A fiber composite material obtainable by (a) mixing the components of a multi-component agent immediately before use, wherein component A of the multi-component agent contains at least one compound having two or more isocyanate groups, component B of the multi-component agent contains at least one compound which has at least two reactive groups selected from hydroxyl groups, thiol groups, primary amino groups and secondary amino groups and is simultaneously free from epoxy groups, and at least one of the components of the multi-component agent contains at least one epoxide prepolymer, (b) introducing the resulting application preparation into a mold in which fibers and optionally further additives are present, the resulting mixture containing at least one latent hardener for epoxide prepolymers, (c) pre-curing the resulting mixture at a temperature from 5 C. to 90 C., and (d) then finally curing the pre-cured fiber composite material at temperatures from 100 C. to 240 C., wherein the fiber composite material being removed from the mold after step (c) or step (d).
The Method for Improving Fracture Toughness of Polyisocyanurate Comprising Reaction Products
A curable composition for making polyisocyanurate comprising products obtained by combining and mixing at an isocyanate index of at least 100 at least a polyisocyanate composition, a polytetrahydrofuran polyol (P-THF) having average molecular weight in range 1000-5000 g/mol as toughening agent and diols having an average molecular weight <1000 g/mol.
Cardanol modified epoxy polyol
A reaction system for forming polyurethane elastomers includes a cardanol modified epoxy polyol. In particular, the reaction system has an isocyanate-reactive component that includes the cardanol-modified epoxy polyol and an isocyanate component that includes at least one polyisocyanate. The cardanol-modified epoxy polyol is a reaction product of an epoxy component and an epoxy-reactive component at a ratio of epoxy groups to epoxy reactive groups from 1:1 to 1:5, and the epoxy-reactive component includes a cashew nutshell liquid having a cardanol content of at least 85 wt %, based on a total weight of the cashew nutshell liquid.
POLYURETHANE-POLYISOCYANURATE COMPOUND COMPRISING OUTSTANDING MECHANICAL PROPERTIES
Polyurethane-polyisocyanurate compounds and processes for preparing polyurethane-polyisocyanurate compounds are disclosed herein. A process includes mixing component (a) polyisocyanate with component (b) a mixture obtainable by introducing an alkali metal or alkaline earth metal salt into a compound RNHCOR containing urethane groups, where R is not hydrogen and is not COR, component (c) compounds containing one or more epoxide groups, component (d) one or more compounds having at least two isocyanate-reactive groups, comprising compounds having NH.sub.2 and/or primary OH groups, and component (e) optionally fillers and other additives, to form a reaction mixture, and reacting said reaction mixture to form the polyurethane-polyisocyanurate compound, wherein the molar amount of alkali metal and/or alkaline earth metal ions in the reaction mixture per mole of urethane group in component (b) is 0.0001 to 3.5 and the isocyanate index is greater than 150. Use of polyurethane-polyisocyanate compounds for producing vehicle parts is also disclosed.
Production of fibre composite component part based on steel and polyurethane
A method of producing a fiber composite component part, contains the following steps: a) providing two or more steel sheets; b) providing at least one textile fabric; c) providing an anhydrous mixture having one or more than one hardener containing a uretdione having an NCO functionality of not less than two, one or more than one binder having hydroxyl groups to an OH functionality of three to six, and one or more than one cobinder having oxirane groups; d) coating the textile fabric with the mixture; e) applying energy to the mixture-coated fabric for the purpose of performing a first crosslinking reaction to react hardener, binder and cobinder to form a thermoplastic polymer adhering to the textile fabric; f) hot pressing the steel sheets and the textile fabric together with the thermoplastic polymer adhering thereto into a sandwich such that the thermoplastic polymer joins the steel sheets together while enclosing the textile fabric; g) forming the sandwich into a shaped article; h) heat treating the shaped article to obtain the fiber composite component part, wherein the thermoplastic polymer undergoes a second crosslinking reaction to convert into a thermoset polymer.
Production of fibre composite component part based on aluminium and polyurethane
A method of producing a fiber composite component part has the following steps: a) providing two or more metal sheets each comprising an aluminum material; b) providing at least one textile fabric; c) providing an anhydrous mixture having one or more than one hardener having a uretdione having an NCO functionality of not less than two, one or more than one binder having hydroxyl groups to an OH functionality of three to six, and one or more than one cobinder having oxirane groups; d) coating the textile fabric with the anhydrous mixture, to obtain a mixture-coated fabric; e) applying energy to the mixture-coated fabric for the purpose of performing a first crosslinking reaction to react hardener, binder and cobinder to form a thermoplastic polymer adhering to the textile fabric; f) hot pressing the metal sheets and the textile fabric together with the thermoplastic polymer adhering thereto into a sandwich such that the thermoplastic polymer joins the metal sheets together while enclosing the textile fabric; g) forming the sandwich into a shaped article; and h) heat treating the shaped article to obtain the fiber composite component part, wherein the thermoplastic polymer undergoes a second crosslinking reaction to convert into a thermoset polymer.