Patent classifications
C08G18/4854
AQUEOUS POLYURETHANE RESIN COMPOSITION AND COATING MATERIAL USING THE COMPOSITION
Provided is an aqueous polyurethane resin composition which is excellent in finished appearance as well as excellent in impact resistance, such as chipping resistance, and adhesion.
The aqueous polyurethane resin composition includes a polyurethane resin obtained from at least (a) at least two types of organic diisocyanate compounds and/or polyisocyanate compounds which are different from each other, (b) a polyol compound; (c) an acidic group-containing compounds comprising at least two types of compounds which are a compound containing a carboxyl group as the acid group (a carboxyl group-containing compound) and a compound containing a sulfo group as the acid group (a sulfo group-containing compound); and (d) a chain extender of a polyamine compound, a diamine compound, a polyol compound and/or an alkanolamine compound with a molecular weight of not more than 400, in which the aqueous polyurethane resin composition has a viscosity of not less than 500 Pa.Math.s and not more than 50,000 Pa.Math.s when the polyurethane resin is contained in an amount of 65% by weight.
PREPARATION METHOD OF ULTRAVIOLET (UV)-RESISTANT AND TRANSPARENT LIGNIN-BASED POLYURETHANE (PU) ELASTOMER
The present disclosure discloses a preparation method of an ultraviolet (UV)-resistant and transparent lignin-based polyurethane (PU) elastomer. During the synthesis process, natural lignin-based polyols are directly used as an end-capping agent, isophorone diisocyanate and 2,2-dimethylolbutyric acid are used as a hard segment and polyether chain polyols are used as a soft segment, to synthesize a PU elastomer with a transparent brown appearance, excellent high elasticity and elastic recovery performance, as well as excellent mechanical properties, excellent UV resistance and repeatable processability. The lignin-based PU elastomer has a simple preparation process, and has great potential values for use in the fields such as PU elastomer film, fabric coating, and elastic fiber and biomass polymer materials.
Cationic fluoropolymer composite polishing method
The invention provides a method for polishing or planarizing a substrate of at least one of semiconductor, optical and magnetic substrates. The method includes attaching a polymer-polymer composite polishing pad having a polishing layer to a polishing device. A hydrophilic polymeric matrix forms the polishing layer. Cationic fluoropolymer particles having nitrogen-containing end groups are embedded in the polymeric matrix. A slurry containing anionic particles is applied to the polymer-polymer composite polishing pad and rubbed against the substrate to polish or planarize the substrate with the fluoropolymer particles interacting with the anionic particles to increase polishing removal rate.
AMINATED PHOSPHORENE-BASED FLAME-RETARDANT WATERBORNE POLYURETHANE COATING AND PREPARATION METHOD THEREOF
This application relates to flame-retardant coatings, and more particularly to an aminated phosphorene-based flame-retardant waterborne polyurethane coating and a preparation method thereof. The aminated phosphorene-based flame-retardant waterborne polyurethane coating is prepared from a diisocyanate-terminated prepolymer, a neutralizer and an aminated phosphorene, where the diisocyanate-terminated prepolymer is prepared from polymeric diol with water-dispersible groups, aliphatic diisocyanate and carboxylic acid type hydrophilic diol under the catalysis of a catalyst for synthesizing waterborne polyurethane.
Rotaxane and polyurethane using the same
An object of the present invention is to provide a novel rotaxane and a polyurethane using the same. The present invention provides a rotaxane having a crown ether and a chain molecule piercing through the cyclic structure of the crown ether, wherein a hydroxyl group exists at one terminal of the chain molecule, and a hydroxyl group bonds to the cyclic structure of the crown ether. The present invention further provides a polyurethane using the rotaxane as a polyol component.
Dual cure method using Zerewitinoff-active H tin catalysts
The invention relates to a method for producing an object from a construction material, the construction material comprising radically crosslinkable groups, NCO groups and groups having Zerewitinoff active H atoms, and the object being a three-dimensional object and/or a layer. During and/or after the production of the object, the construction material is heated to a temperature of >50° C., and the construction material comprises one or more cyclic tin compounds of formula F-I, F-II and/or F-III.
Prepolymer of elastomer material for screw drilling tool and preparation method thereof
A prepolymer of elastomer material for screw drilling tools and a preparation method thereof are provided. The prepolymer includes component A and component B, wherein the component A includes hydroxyl-terminated liquid rubber, polytetrahydrofuran diol, and polyether polyol; the component B includes at least one of an isocyanate, a cyanate, and a cyano compound; the mass ratio of the hydroxyl-terminated liquid rubber, polytetrahydrofuran diol, and polyether polyol is (0.2-1.0): (0.2-1.0): (0.2-1.0). Different molecular segments of different proportions are introduced through structural design, such that the molecular structure of the prepolymer has both rigid and flexible segments, thus to achieve an adjustable and controllable structure of the prepolymer; and the introduction of active groups makes the prepolymer to show good reactivity and processability. Therefore, a reactive elastomer material having excellent properties such as hardness, tear strength, and tensile strength can be obtained used as an elastomer material for screw drilling tools.
Compressible non-reticulated polyurea polishing pad
The invention provides a polishing pad suitable for polishing at least one of semiconductor, optical, magnetic or electromechanical substrates. It includes a polyurea polishing layer and a polyurea matrix. The polyurea has a soft segment being a copolymer of aliphatic fluorine-free polymer groups and a fluorocarbon having a length of a least six carbons. The polyurea matrix being cured with a curative agent and including gas or liquid-filled polymeric microelements. The polyurea matrix has a bulk region and a transition region adjacent the bulk region that extends to the polishing layer. The polymeric microelements in the transition region decrease in thickness as they approach the polishing layer with thickness of the compressed microelements adjacent the polishing layer being less than fifty percent of a diameter of the polymeric microelements in the bulk region. The polishing layer remains hydrophilic during polishing in shear conditions.
EROSION RESISTANT COATINGS
An erosion resistant article such as rotor blades for helicopters and wind turbines having the leading edge surface protected from damage from high speed impingement of rain or sand with a protective coating formed from specific polyurethane or polyurea coating having a defined set of minimum physical properties where the protective coating can be applied as a liquid coating and cured in place or as a preformed complementary shaped covering to protect the leading edge against erosion damage in service.
Golf ball
An object of the present invention is to provide a novel golf ball having excellent spin performance on approach shots. The present invention provides a golf ball comprising a golf ball body, and a paint film formed on a surface of the golf ball body and composed of at least one layer, wherein a base resin constituting an outermost layer of the paint film includes a polyurethane, and the polyurethane has a loss elastic modulus (E″) of 0.2×10.sup.8 Pa or more at −50° C. and a loss tangent (tan δ) having a peak temperature of 0° C. or less, obtained by measuring dynamic viscoelasticity of the polyurethane under specific conditions.